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31.
Eugene P. Gross 《Journal of statistical physics》1989,54(1-2):405-427
A study is made of the ground-state energy of a spin-one-half particle in a fieldB and interacting with a phonon bath. The infrared-sensitive case of acoustic phonons with point coupling in three dimensions is characterized by two parameters, a coupling constant andB. Units are used where the high-momentum phonon cutoff is unity. There is a curve (B) separating a symmetry-breaking region with a long-range phonon field from a normal region. Two simple, well-known, approximations are compared. The source theory yields discontinuities in the first derivatives of the energy with respect toB and whenB>e
–1 and an infinite-order transition whenB<e
–1, but is trivial in the large- region. The classical theory yields discontinuities in the second derivatives but is trivial in the small- region. An improved variationally fixed ground-state wave function is analyzed. It gives a new (B) curve with an infinite-order transition with continuous energy derivatives whenB<e/(e
2–1/4) and with discontinuous derivatives whenB is larger than this value. It is nontrivial in the entire (B) plane. The crossover to classical behavior occurs near =1/2 forB1. But the wave function does not describe quantum fluctuations in the large- phase. A second way of combining source and classical effects is described. It yields a second-order transition (near =1/2 forB1) everywhere. These theories are special cases of a symmetry-breaking transformation together with a one-mode treatment of quantum fluctuations. The transition is viewed in terms of a single mode with a variable length, coupled dynamically to the spin. 相似文献
32.
Ab initio calculations of the orbital and the ground state energies of some open- and closed-shell atoms over Slater type orbitals with quantum numbers integer and Slater type orbitals with quantum numbers noninteger have been performed. In order to increase the efficiency of these calculations the atomic two-electron integrals were expressed in terms of incomplete beta function. Results were observed to be in good agreement with the literature. 相似文献
33.
34.
Filip Fratev Gottfried Olbrich Oskar E. Polansky 《Monatshefte für Chemie / Chemical Monthly》1979,110(3):505-515
UsingGleason's theorem the pars orbital concept is developed for excited states of conjugated systems described by CI-methods. A significance index is introduced to evaluate different patterns of fragmentation. The usefulness of this approach is illustrated for butadiene, biphenyl, naphthalene, and azulene.
11. Mitt.:H. Karpf, O. E. Polansky undM. Zander, Tetrahedron Lett.1978, 2069. 相似文献
35.
Grimme S 《Journal of computational chemistry》2003,24(13):1529-1537
Based on a partitioning of the total correlation energy into contributions from parallel‐ and antiparallel‐spin pairs of electrons, a modified third‐order Møller–Plesset (MP) perturbation theory is developed. The method, termed SCS–MP3 (SCS for spin‐component‐scaled) continues previous work on an improved version of MP2 (S. Grimme, J Chem Phys 2003, 118, 9095). A benchmark set of 32 isogyric reaction energies, 11 atomization energies, and 11 stretched geometries is used to assess to performance of the model in comparison to the standard quantum chemical approaches MP2, MP3, and QCISD(T). It is found, that the new method performs significantly better than usual MP2/MP3 and even outperforms the more costly QCISD method. Opposite to the usual MP series, the SCS third‐order correction uniformly improves the results. Dramatic enhancements are especially observed for the more difficult atomization energies, some of the stretched geometries, and reaction and ionization energies involving transition metal compounds where the method seems to be competitive or even superior to the widely used density functional approaches. Further tests performed for other complex systems (biradicals, C20 isomers, transition states) demonstrate that the SCS–MP3 model yields often results of QCISD(T) accuracy. The uniformity with which the new approach improves for very different correlation problems indicates significant robustness, and suggests it as a valuable quantum chemical method of general use. © 2003 Wiley Periodicals, Inc. J Comput Chem 24: 1529–1537, 2003 相似文献
36.
C. E. I. Carneiro M. J. de Oliveira W. F. Wreszinski 《Journal of statistical physics》1995,79(1-2):347-376
We show rigorously that the ground state of a quantum chain with competing ferromagnetic nearest and antiferromagnetic next nearest interactions undergoes a transition from ferromagnetic to helical type, in the isotropic case, for a certain value of the relevant ratio of coupling constants. Boundaries of the phase diagram are also determined in the anisotropic case. The stability of a special quantum state (corresponding to a classical modulated phase of =/3) is analyzed by an extension of Holstein-Primakoff arguments, along a line of constant ratio of couplings, showing in particular a sequence of (instability) gaps. Finally, a natural adaptation of a variational wave function due to Huse and Elser is used to study several portions of the phase diagram, with very good agreement with previous theoretical results. 相似文献
37.
针对民航空地通信数据丢失率高、吞吐量低问题,提出了一种基于丢包感知负载均衡(Packet Loss-Aware Load Balancing)的分配算法。在空地多链路通信中,每条链路的数据损失率随着链路状态与传输环境等情况实时变化。该算法通过控制每次空地通信中数据流的分割比率,动态分配给每条链路不同大小的数据流,使每条链路的传输损失率趋于相近,提高了空地通信系统吞吐量并减少了数据传输损失,以应对空地通信中丢包率高与吞吐量低等问题。仿真结果表明,所提算法在数据传输损失率和吞吐量上都优于现有的多链路子流分配算法。 相似文献
38.
为了节省基站天线所占空间资源,降低其运营成本,现代移动通信需要将多个天线阵列紧密地排列在一起,构成多频共口径基站天线。多天线的紧密排列势必造成天线间强烈的耦合,不仅使得天线阻抗失配、隔离度变差,同时也造成辐射方向图的严重变形。因此,近年来多频共口径基站天线的去耦成为工业界和学术界研究的热点,早期的去耦技术主要是面向改善天线的阻抗匹配和隔离度,而对面向方向图保形的去耦技术研究相对较少。文章在简要介绍面向方向图保形的基站天线去耦技术的研究现状的基础上,重点阐述了褚庆昕教授天线射频团队基于感应电流抵消、耦合场抵消和辐射阻断等原理,提出的几种新型的去耦技术。这些技术不仅可以有效地改善基站天线的阻抗匹配和隔离,更重要的是很好地实现了天线方向图保形。仿真和测试结果验证了原理的正确性和设计的可行性。一些技术已被用于5G基站天线产品。 相似文献
39.
Yawar Abbas Bangash Waseem Iqbal Saddaf Rubab Abdul Waheed Khan Waqas Aman 《International Journal of Communication Systems》2023,36(17):e5601
Base station's location privacy in a wireless sensor network (WSN) is critical for information security and operational availability of the network. A key part of securing the base station from potential compromise is to secure the information about its physical location. This paper proposes a technique called base station location privacy via software-defined networking (SDN) in wireless sensor networks (BSLPSDN). The inspiration comes from the architecture of SDN, where the control plane is separated from the data plane, and where control plane decides the policy for the data plane. BSLPSDN uses three categories of nodes, namely, a main controller to instruct the overall operations, a dedicated node to buffer and forward data, and lastly, a common node to sense and forward the packet. We employ three kinds of nodes to collaborate and achieve stealth for the base station and thus protecting it against the traffic-analysis attacks. Different traits of the WSN including energy status and traffic density can actively be monitored by BSLPSDN, which positively affects the energy goals, expected life of the network, load on common nodes, and the possibility of creating diversion in the wake of an attack on the base station. We incorporated multiple experiments to analyze and evaluate the performance of our proposed algorithm. We use single controller with multiple sensor nodes and multiple controllers with multiple sensor nodes to show the level of anonymity of BS. Experiments show that providing BS anonymity via multiple controllers is the best method both in terms of energy and privacy. 相似文献
40.
Jangwon Moon Junwoo Kim Hoon Lee Youngjin Moon Yongsu Lee Youngjo Bang Kyungyeol Sohn Jungsook Bae Kwangseon Kim Seungjae Bahng Heesoo Lee 《ETRI Journal》2023,45(5):781-794
Uncrewed aerial vehicles (UAVs) have become a vital element in nonterrestrial networks, especially with respect to 5G communication systems and beyond. The use of UAVs in support of 4G/5G base station (uncrewed aerial vehicle base station [UAV-BS]) has proven to be a practical solution for extending cellular network services to areas where conventional infrastructures are unavailable. In this study, we introduce a UAV-BS system that utilizes a high-capacity wireless backhaul operating in millimeter-wave frequency bands. This system can achieve a maximum throughput of 1.3 Gbps while delivering data at a rate of 300 Mbps, even at distances of 10 km. We also present the details of our testbed implementation alongside the performance results obtained from field tests. 相似文献