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151.
The design and performance of an electron spin resonance spectrometer operating at 3 and 9 GHz microwave frequencies combined with a 9-T superconducting magnet are described. The probehead contains a compact two-loop, one gap resonator, and is inside the variable temperature insert of the magnet enabling measurements in the 0-9T magnetic field and 1.5-400 K temperature range. The spectrometer allows studies on systems where resonance occurs at fields far above the g approximately 2 paramagnetic condition such as in antiferromagnets. The low quality factor of the resonator allows time resolved experiments such as, e.g., longitudinally detected ESR. We demonstrate the performance of the spectrometer on the NaNiO2 antiferromagnet, the MgB2 superconductor, and the RbC60 conducting alkaline fulleride polymer. 相似文献
152.
Feng-Yu Wang 《Proceedings of the American Mathematical Society》2004,132(9):2629-2638
Let be a probability space, and a symmetric linear contraction operator on with and . We prove that is the optimal sufficient condition for to have a spectral gap. Moreover, the optimal sufficient conditions are obtained, respectively, for the defective log-Sobolev and for the defective Poincaré inequality to imply the existence of a spectral gap. Finally, we construct a symmetric, hyperbounded, ergodic contraction -semigroup without a spectral gap.
153.
采用分子束外延的方法在BaF2(111)衬底上制备出了高质量的Pb1-xMnxSe(0≤x≤0.0681)薄膜.X射线衍射结果表明,Pb1-xMnxSe薄膜为立方相NaCl型结构,没有观察到MnSe相分离现象,薄膜的取向为平行于衬底(111)晶面.晶格常数随着Mn含量的增加逐渐减小,Mn含量由Vegard公式得到.通
关键词:
1-xMnxSe外延薄膜')" href="#">Pb1-xMnxSe外延薄膜
透射光谱
带隙
折射率 相似文献
154.
设计了一种棋盘格子复式晶格的二维光子晶体:在二维正方形格子中,把截面为正方形的柱子旋转45°,同时在每个原胞中心引入一个圆形截面的柱子构成的光子晶体结构. 用平面波展开计算棋盘格子复式晶格的完全光子带隙,结果表明:棋盘格子复式晶格的完全光子带隙的Δω/ω比值几乎是普通棋盘格子的5倍,完全光子带隙的个数也增加. 与其他复式结构相比较,发现其最佳的Δω/ω比值是一类粗锐复合结构光子晶体的2.1倍.
关键词:
二维光子晶体
复式晶格
完全光子带隙 相似文献
155.
First-principles study on the electronic structure and optical properties of T12Cd2(SO4)3 and Rb2Cd2(SO4)3
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With the help of ab initio full-potential linearized augmented plane wave (FPLAPW) method, calculating the electronic structure and linear optical properties is carried out for XCd2(SO4)3 (X =Tl, Rb). The results show that Tl2Cd2(SO4)3 (TlCdS) has a larger band gap than Rb2Cd2(SO4)3 (RbCdS) and the energy bands for RbCdS are more dispersive than those of TlCdS. From their partial densities of states (PDOS), we have observed that the hybridization between S ionic 2p and O atomic 2p orbitals forms SO4 ionic groups. The remarkable difference between RbCdS and TlCdS is, however, the degree of hybridization between cation (Tl and Rb) and its surrounding oxygen atoms. In the view of quantum chemistry, the strong p-d hybridization indicates the existence of their cation ionic bonds (Cd-O, Rb-O, and Tl-O). The calculations of TlCdS and RbCdS show their optical properties to be less anisotropic. Their anisotropies in the optical properties mainly occur in a low photon energy region of 5-16 eV. 相似文献
156.
一维光子晶体缺陷模的偏振特性研究 总被引:2,自引:3,他引:2
利用周期结构的布洛赫定理推导了一维无限光子晶体缺陷模方程,研究了缺陷模的偏振特性,以及在不同入射角和缺陷层厚度下缺陷模位置的变化.利用传输矩阵方法对有限周期数光子晶体也进行了研究,分别对应一维无限光子晶体和有限周期数光子晶体给出了数值计算结果.通过比较这两者的数值结果得出了缺陷模随入射角和缺陷层厚度变化的一般规律. 相似文献
157.
A status report on rapidly advancing femtosecond laser technology, three-dimensional (3D) microstructuring by multiphoton illumination technique, is given. Taking its origin from multiphoton microscopy, this technique is now becoming an important microfabrication tool. In our work we apply near-infrared Ti:sapphire femtosecond laser pulses (at 800/780 nm) for 3D material processing. When tightly focused into the volume of a photosensitive material (or photoresist), they initiate 2PP process by, for example, transferring liquid into the solid state. This allows the fabrication of any computer generated 3D structure by direct laser “recording” into the volume of photosensitive material. 2PP of photosensitive materials irradiated by femtosecond laser pulses is now considered as enabling technology for the fabrication of 3D photonic crystals and photonic crystal templates. In particular, 2PP allows one to introduce defects at any desired locations, which is crucial for the practical applications. Recently, we studied possible applications of 2PP technique in biomedicine. 2PP is a very interesting technique for the fabrication of drug delivery systems, scaffolds for tissue engineering, and medical implants. These and other biomedical applications of 2PP will be reviewed. 相似文献
158.
Yanping Liu 《Applied Surface Science》2007,253(21):8571-8574
Three-dimensional (3D) composite colloidal photonic crystals with SiO2 core and ZnO shell were fabricated on borosilicate glass (BSG) substrate by a two-stage deposition method. Scanning electron microscopy (SEM) measurements show that both the pre-deposited SiO2 and SiO2/ZnO core-shell structures are oriented with their (1 1 1) axes parallel to the substrates. Optical measurement reveals that the periodic arrays exhibit a photonic band gap in the (1 1 1) direction. The optical properties of SiO2/ZnO core-shell structures strongly depend on the size dispersions of colloidal spheres and the intrinsic defects in the sample. 相似文献
159.
Clusters of high aspect ratio, high surface area anatase-TiO2 nanotubes with a typical nanotube outer diameter of about 18 nm, wall thickness of approximately 5 nm and length of 5-10 μm were synthesized, in powder form, by breakdown anodization of Ti foils in 0.1 M perchloric acid, at 10 V (299 K) and 20 V (∼275 and 299 K). The surface area, morphology, structure and band gap were determined from Brunauer Emmet Teller method, field emmission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman, photoluminescence and diffuse reflectance spectroscopic studies. The tubular morphology and anatase phase were found to be stable up to 773 K and above 773 K anatase phase gradually transformed to rutile phase with disintegration of tubular morphology. At 973 K, complete transformation to rutile phase and disintegration of tubular morphology were observed. The band gap of the as prepared and the annealed samples varied from 3.07 to 2.95 eV with increase in annealing temperature as inferred from photoluminescence and diffuse reflectance studies. 相似文献
160.
Jaehong Kim Sung Heum Park Jinwoo Kim Shinuk Cho Youngeup Jin Joo Young Shim Hyunmin Shin Sooncheol Kwon Il Kim Kwanghee Lee Alan J. Heeger Hongsuk Suh 《Journal of polymer science. Part A, Polymer chemistry》2011,49(2):369-380
Newly designed 2H‐benzimidazole derivatives which have solubility groups at 2‐position have been synthesized and incorporated into two highly soluble carbazole based alternating copolymers, poly[2,7‐(9‐(1′‐octylnonyl)‐9H‐carbazole)‐alt‐5,5‐(4′,7′‐di(thien‐2‐yl)‐2H‐benzimidazole‐2′‐spirocyclohexane)] (PCDTCHBI) and poly[2,7‐(9‐(1′‐octylnonyl)‐9H‐carbazole)‐alt‐5,5‐(4′,7′‐di(thien‐2‐yl)‐2H‐benzimidazole‐2′‐spiro‐4′′‐((2′′′‐ethylhexyl)oxy)‐cyclohexane)] (PCDTEHOCHBI) for photovoltaic application. These alternating copolymers show low‐band gap properties caused by internal charge transfer from an electron‐rich unit to an electron‐deficient moiety. HOMO and LUMO levels are –5.53 and –3.86 eV for PCDTCHBI, and –5.49 and –3.84 eV for PCDTEHOCHBI, respectively. Optical band gaps of PCDTCHBI and PCDTEHOCHBI are 1.67 and 1.65 eV, respectively. The new carbazole based the 2H‐benzimidazole polymers show 0.11–0.13 eV lower values of band gaps as compared to that of carbazole based benzothiadiazole polymer, poly[N‐9′‐heptadecanyl‐2,7‐carbazole‐alt‐5,5‐(4′,7′‐di‐2‐thienyl‐2′,1′,3′‐benzothiadiazole)] (PCDTBT), while keeping nearly the same deep HOMO levels. The power conversion efficiencies of PCDTCHBI and PCDTEHOCHBI blended with [6,6]phenyl‐C71‐butyric acid methyl ester (PC71BM) are 1.03 and 1.15%, respectively. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献