轨道角动量光束非线性转换研究进展北大核心CSCD

轨道角动量(OAM)是光的一个重要的自由度。由于携带OAM的光束具有特殊的强度相位分布以及力学效应,使得此类光束在高速光通信、测量、成像、光镊和量子信息中具有广泛的应用。关于OAM光束在准相位匹配晶体(QPM)中的频率变换研究,一方面可以研究OAM光束参与非线性相互作用时与高斯光束不同的物理机制;另一方面,非线性过程提供了多种有效的光场调控手段,可以实现携带OAM光场不同自由度的精细调控,为满足不同的光学应用奠定基础。综述了近十年来OAM光束在QPM晶体中的非线性转换研究主要进展,具体包括:非线性过程中OAM光束的守恒、传输、演化和干涉行为研究,高效率的OAM激光和单光子态频率转换研究,OAM频率转换效率模式非依赖性研究,矢量光束的频率转换研究,以及无后向选择的高维OAM纠缠态的制备研究。最后讨论和展望了OAM在QPM晶体中频率转换方面的未来研究趋势。     

基于多尺度圆周频率滤波与卷积神经网络的遥感图像飞机目标检测方法研究

针对遥感图像飞机目标检测因目标尺度不一存在漏警、虚警等问题,该文基于遥感图像中飞机目标形状特征和灰度变化特点提出了一种多尺度圆周频率滤波(MSCFF)与卷积神经网络(CNN)相结合的MSCFF+CNN飞机目标自动检测算法.该算法首先采用多尺度圆周频率滤波器滤除遥感图像复杂背景,实现不同尺度飞机目标候选区域提取;然后,通过构建卷积神经网络(CNN)模型实现候选区域有效分类,最终精确确定飞机目标位置.最后,基于获取的真实遥感图像进行目标检测算法实验验证,经统计该算法的飞机目标检测率为94.38%,虚警率为3.76%,实验结果充分验证了该文算法的有效性,该算法可为机场监管、军事侦察等应用提供重要的技术支持.     

短波通信频率的选择技术研究与实现

短波通信技术具有传输距离远、灵活性强、机动性高、应用成本低等优势,在诸多领域都有着广泛的应用。短波通信主要时利用电离层与地面之间的反射实现通信功能,受到太阳辐射等多方面因素的影响,电离层具有不稳定性和变化的不规则性,短波通信的稳定性、可靠性和持久性也会受到较大的影,保证短波通信的质量,要结合通信需求和电离层变化的规律,选择合适的通信信道和通信频率。     

Flow injection analysis of potassium using an all-solid-state potassium-selective electrode as a detector

The concentration of potassium was determined by a combination of flow injection analysis (FIA) with an all-solid-state potassium sensor detection. The all-solid-state potassium-selective electrode possessing long-term potential stability was fabricated by coating an electroactive polypyrrole/poly(4-styrenesulfonate) film electrode with a plasticized poly(vinyl chloride) membrane containing valinomycin. The simple FIA system developed in this laboratory demonstrated sensitivity identical to that in the batch system and achieved considerably rapid assay (150 samples h⁻¹). Analyses of soy sauce and control serum samples by this FIA system yielded results in good agreement with those obtained by conventional measurements.     

The frequency-domain method reveals the dimeric structure of Na,K-ATPase

Lucifer yellow and lissamine rhodamine sulfonyl hydrazine were used as the donor and the receptor, respectively, for Förster energy transfer measurements to determine the location of the subunit in the native Na,K-ATPase from pig kidney. It was found that (1) the subunits are located in one functional complex, i.e., the dimer ()₂ appears to be the functional complex of Na,K-ATPase, and (2) the subunits in the functional enzyme complex in the membrane are not located next to each other but are rather well separated. The distance between fluorophores covalently attached to the subunits was found to be 5.3 nm.     

EFFECTS OF SOURCE PROPERTIES ON CUTOFF FREQUENCY f_(max)

The cutoff frequency f_(max) of radiation from earthquakes is one of the important parameters for studying the source process. By theoretical analysis and numerical experiments on acceleration Fourier spectrum it is suggested that f_(max) mainly depends on the lower values of slip rise time. This result can be used to explain the observational fact that the greater the earthquake magnitude, the smaller the value of f_(max).     

Multicomponent electrolyte systems: Dependence of ionic mobilities on aqueous organic solvent structure

Ionic mobility data for multicomponent electrolyte systems at low concentrations are scarce due to experimental difficulties and are actually restricted to aqueous solutions of alkali chlorides. Some new results are presented which have been obtained by using a radiotracer method valid even if one of the ionic species is present at very low concentrations (tracer ion). The following electrolyte systems (two electrolytes with a common ion in a solvent) have been investigated at a 0.5N total ionic strength: NaNO₃–AgNO₃, KNO₃–AgNO₃, LiNO₃–AgNO₃ either in pure water or in water-rich (acetonitrile or dimethylsulfoxide) mixed solvents. Since ionic conductivity data processing by an extended law generalized to mixtures, such as that proposed by Quint and Viallard, has proved to be delicate to handle, our experimental results have been compared with the qualitative predictions of the classical Onsager-Fuoss limiting law. The main conclusion of this work is to give clear experimental evidence of the inability of any continuum theory to predict the ionic mobilities when solvent structural effect have to be taken into account. Consequently, the ionic behavior, particularly that of the Ag⁺ ion, has been interpreted in terms of preferential solvation and solvent microscopic structure. The trace mobility measurements reflect the maximum structural effect on the ionic transport properties.     

N－N－二甲基甲酰胺缩二甲醇对喋呤的甲基化反应

用N，N-二甲基甲酰胺缩二甲醇[（CH3）2NCH(OCH3)2，1]和蝶呤（2-氨基-4- 羟基蝶啶）衍生物在极性有机溶剂中反应一般得到脒化产物：N^2-(N，N-二甲基氨 基亚甲基)-蝶呤衍生物，但是在1，4-二氧六环中进行以上反应时发现，N，N-二甲 基酰胺缩二甲醇（1）不仅是脒化试剂，而且也是蝶呤化合物的甲基化试剂，并且 也依据蝶呤的N^2-位的不同取代基进行选择性的N(3)-或O^4-甲基化反应。     

New far infrared laser lines obtained by optically pumping13CD3OD

We have obtained laser action on 34 far infrared lines for the first time in fully deuterated methyl alcohol with the¹³C isotope (¹³CD₃OD), and we have measured the frequency of 13 lines. The molecule was pumped by a cw CO₂ laser. We have measured the wavelength, the relative polarization, the relative intensity of most lines, the frequency, and the CO₂ pump frequency offset of the strongest lines. The new lines are distributed in the wavelength region from 75.27 m to 464.7 m.Supported in part by a joint grant with the U.S. National Science Foundation grant # INT 80-19014 and the Brazilian Conselho Nacional de Pesquisas (CNPq).     

Propane/propylene separation by selective olefin adsorption on Cu/SBA-15 mesoporous silica

Samples of mesoporous silica, SBA-15, were prepared under hydrothermal conditions and Cu cations were incorporated into the framework by two different impregnation techniques. The corresponding adsorption/desorption isotherms of propylene, propane, and N₂ were measured to evaluate the material's effectiveness in the separation of propane/propylene mixtures. Adsorption uptake of propylene increased and that of propane decreased in Cu containing samples as compared to the uptakes observed in undoped SBA-15 samples. It was demonstrated that the presence of Cu atoms in the adsorbent lattice led to a greater selectivity towards propylene. Furthermore, the highest level of Cu(I) were obtained in samples prepared by equilibrium impregnation, which in turn improved the olefin/paraffin uptake ratio. Under some working conditions, the amount of propylene adsorbed in selected samples is totally reversible while propane uptake was negligible.