贵金属对钴基催化剂上肉桂醛选择加氢反应的影响

 研究了贵金属改性的Co／γ－Al2O3催化剂上的肉桂醛选择加氢反应．结果表明，通过Pt，Pd和Ru贵金属改性，提高了催化剂的活性，但只有Pt改性的催化剂具有较高的选择性．w（Pt）＜0．5％时，催化剂的活性随着Pt含量的增加呈直线升高，当w（Pt）＝0．5％时，催化剂活性可提高近5倍，但催化剂的选择性变化很小．XRD结果表明，催化剂经还原后，γ－Al2O3上的钴主要为α－Co0．TPR结果表明，Pt的加入提高了Co3O4的还原性能，且Pt含量越高，Co3O4的还原温度越低．XPS结果表明，Pt改性的催化剂样品，其Co3O4大部分被还原为Co0．由于Pt与Co具有协同效应，故Pt改性的Co／γ－Al2O3催化剂既具有较高的活性，又具有很高的选择性．     

Dispersion state and catalytic properties of vanadia species on the surface of V_2O_5/TiO_2 catalysts

The dispersion state and catalytic properties of anatase-supported vanadia species are studied by means of X-ray diffraction (XRD), laser Raman spectroscopy (LRS), H2 temperature-programmed reduction (TPR) and the selective oxidation of o-xylene to phthalic anhydride. The almost identical values of the experimental dispersion capacity of V2O5 on anatase and the surface vacant sites available on the preferentially exposed (001) plane of anatase suggest that the highly dispersed vanadium cations are bonded to the vacant sites on the surface of anatase as derived by the incorporation model. When the loading amount of V2O5 is far below its dispersion capacity, the dispersed vanadia species might mainly consist of isolated VOx species bridging to the surface through V-O-Ti bonds. With the increase of V2O5 loading the isolated vanadia species interact with their nearest neighbors (either isolated or polymerized vanadia) through bridging V-O-V at the expenses of V-O-Ti bonds, resulting in the increase of the ra     

双臂套索冠醚PVC膜碘离子选择电极

研究了两种新型双臂套索冠醚1，10－二（5－氯－8－羟基喹啉－7－亚甲基）－1，10－二氮杂－4，7，16－三氧杂－13，19－二硫杂环二十一烷（Ⅰ）和1，13－二（5－甲基－8－羟基喹啉－7－亚甲基）－1，13－二氮杂－4，7，10－三氧杂－16，19－二硫杂环二十一烷（Ⅱ）为载体的PVC膜电极的响应行为；实验结果表明，两电极均显示阴离子响 应，其中对碘离子具有优良的能斯特电位响应性能，线性范围为10^－5－10^-1mol/L，斜率分别为－59．1mV/pcI-和－57．6mV/pcI-；电极具有读数稳定，重复性好，PH值范围宽等优点；将该电极用于药品中碘含量的测定，其结果与药典法一致。     

实现金相图象彩色化的一种新方法

本文提出一种简便的方法,仅利用一彩色滤波器便可以从金相显微镜实时地观察到假彩色编码图象。图象棱角分明、色彩鲜艳丰富,并能显示黑白显微放大图象所看不到的细节。 我们使用的方法是使黑白图象假彩色化,它利用改造物的空间频谱(即在不同频谱处仅让“某种颜色的光”通过)而实现的。 作者给出理论解析、实验装置和实验结果,并指出这种方法的优点及其在冶金,机械等领域的潜在实用前景。     

可调谐钛宝石双波长激光在β－BaB2O4晶体中和频

本文用矩阵光学推导出了相位共轭腔的热稳条件。     

4G载波向5G重耕之前的5G业务覆盖能力研究

为了满足低成本建设5G广覆盖网络的需求,需要提前研究低频3G、4G网络向5G重耕的最佳方案。在没有进行重耕,因而没有理想的低频5G测试环境的情况下,采用理论分析的手段进行重耕后的覆盖能力估算。以未来L900重耕用于5G广覆盖为例,探讨了链路预算的关键设定、模型选择等问题,并通过多个本地网实际测试数据间接验证估算结果的合理性。所得结论已实际应用于某大运营商对全国900 MHz网络的规划方案,对于指导网络重耕具有重要的借鉴意义,也为面向覆盖和感知的6G网络演进及重耕提供了参考模型。     

PLC-RF无线传输网络中的能效最优设计方法

针对电力线通信（PLC）和射频（RF）无线通信混合传输的室内通信场景,提出了一种基于角度信息的信道状态信息（AI-CSI）的能效优先传输方案。首先,Wi-Fi无线网络和PLC网络分别作为主网络和次级网络,并且采用认知无线电技术来提高频谱效率的情况下,建立次级网络总能效最大化为目标函数的优化问题。其次,为了求解该问题,通过基于AI-CSI的迫零波束成形方法,获得波束成形权矢量,并进一步提出Dinkelbach与拉格朗日乘子法相结合的优化方法,进行最优的功率分配。最后,计算机仿真结果不仅验证了所提方案的有效性和优越性,而且分析了中继天线数和用户个数等典型参数对系统能效带来的影响,从而为实际系统设计提供了参考和依据。     

集中式MIMO雷达研究进展：正交波形设计与信号处理

集中式多输入多输出（Multiple Input Multiple Output,MIMO）雷达通常利用正交波形增加发射波形自由度,采用数字阵列拓展空间收发自由度,使得雷达接收机的天线孔径获得明显扩展,最终带来空间分辨率、测角精确度、杂波抑制能力等大幅度提升。但是,这些性能提升的前提是发射波形具有正交特性。事实上,在实际应用中,在不牺牲时域/频域资源情况下,受限于时宽带宽积,无法获得完全正交的波形集合,从而限制了MIMO雷达系统性能。本文对集中式MIMO雷达正交波形复用的技术原理进行了系统回顾,分别归纳了三种快时间发射波形设计方法：时分复用（Time Division Multiplexing, TDM）、码分复用（Code Division Multiplexing,CDM）和频分复用 （Frequency Division Multiplexing, FDM）,以及两种慢时间发射波形设计方法：多普勒分复用（Doppler Division Multiplexing,DDM）和随机相位编码波形,并对其优缺点进行对比。同时,对快时间MIMO和慢时间MIMO的信号处理流程进行归纳综合,给出基于匹配滤波的集中式MIMO雷达统一信号处理框架。为了展示不同波形对成像性能的影响,本文给出了基于三维匹配滤波的MIMO雷达成像结果。最后,结合实际应用问题,指出当前MIMO雷达面临的技术难点和发展趋势。     

Circularly polarized patch antenna with simultaneously wide frequency tuning range and high gain performance

A tunable circularly polarized square patch antenna with parasitic elements is designed for a wide frequency tuning range and high gain characteristics. The proposed antenna is constructed by one main patch and four semi-elliptic parasitic units. By loading four varactor diodes and adjusting their capacitance values, the tunable feature is performed to reallocate the corresponding working frequency. Moreover, the diagonal corners of the antenna are cut and loaded with varactor diodes, which provide the appropriate perturbation between the two orthogonality modes of the antenna, so as to ensure the circular polarization characteristic in the entire operating tuning band. The experimental results demonstrate that the reflection coefficient and axial ratio are less than −13 dB and 3 dB, respectively. The proposed antenna features a relatively wide continuously tuning range of 24% within 1.9-2.3 GHz and a stable gain of over 7 dBi with a radiation efficiency of above 85%.     

Least squares decoding in binomial frequency division multiplexing

This paper proposes a method that can reduce the complexity of a system matrix by analyzing the characteristics of a pseudoinverse matrix to receive a binomial frequency division multiplexing (BFDM) signal and decode it using the least squares (LS) method. The system matrix of BFDM can be expressed as a band matrix, and as this matrix contains many zeros, its amount of calculation when generating a transmission signal is quite small. The LS solution can be obtained by multiplying the received signal by the pseudoinverse matrix of the system matrix. The singular value decomposition of the system matrix indicates that the pseudoinverse matrix is a band matrix. The signal-to-interference ratio is obtained from their eigenvalues. Meanwhile, entries that do not contribute to signal generation are erased to enhance calculation efficiency. We decode the received signal using the pseudoinverse matrix and the removed pseudoinverse matrix to obtain the bit error rate performance and to analyze the difference.