Determination of Iron in Calf Serum Using Bathophenanthroline and Thermal Lens Spectrometry

ABSTRACT

Thermal lens spectrometry has been used for the determination of iron in calf serum. The method is based on dissociation of Fe³⁺ from proteins, reduction of Fe³⁺ to Fe²⁺ and formation of a coloured complex between Fe²⁺ and bathophenanthroline. Contrary to the spectrophotometric method, it is shown that thermal lens spectrometry is less sensitive to scattering caused by the presence of small particles remaining in the test solution after the deproteinization step. The background signal is very small and the response is only slightly dependent on the amount of scattering particles. The method is reliable, sensitive and reproducible. The limit of detection for iron is 4 ppb and the relative standard deviation is around 2%. It is expected that the volume of serum sample necessary for an analysis can be reduced to less than 100 μl.     

相位波带片型时间透镜研究

基于Opti-System软件,对相位波带片型时间透镜进行了深入研究。明确了中心波长对相位波带片型时间透镜焦距色散补偿量的影响机理,建立了中心波长、色散补偿量与输出光脉冲消光比及脉冲宽度间的关系。研究结果表明,相位波带片型时间透镜的焦距色散补偿量,在1 310~1 550 nm波长范围与光信号中心波长呈近似线性关系。通过线性拟合,得出焦距色散补偿量与中心波长的线性关系公式。对于不同波长的输入光波,可通过公式确定最佳焦距色散补偿量,实现最窄脉宽和最优消光比的光脉冲输出。研究结果可为优化相位波带片型时间透镜设计提供理论指导,进而拓宽相位波带片型时间透镜的应用范围。     

2-（5-溴-2-吡啶偶氮）-5-二甲氨基苯胺激光热透镜光谱法测定痕量铑的研究

基于铑(Ⅲ)与2-(5-溴-2-吡啶偶氮)-5-二甲氨基苯胺(5-Br-PADMA)的高灵敏显色反应,建立了激光热透镜光谱法测定痕量铑的新方法。实验表明,在pH 3.6～6.0的HAc-NaAc缓冲介质中,Rh(Ⅲ)与5-Br-PADMA显色形成紫红色铑络合物;继续以1.2 mol/L HClO4酸化后,可转变为另一种具有较高吸收特性的绿蓝色质子化型体,其最大吸收波长位于612 nm处,与所用He-Ne激光器的输出激光波长(632.8 nm)能较好匹配。铑的质量浓度在5～140μg/L范围内与热透镜信号强度呈良好的线性关系,检出限(S/N=3)为1.1μg/L。该方法灵敏度高、选择性好,用于铑炭催化剂中痕量铑的测定,结果满意。     

Ultrabroadband superoscillatory lens composed by plasmonic metasurfaces for subdiffraction light focusing

Conventional optics is diffraction limited due to the cutoff of spatial frequency components, and evanescent waves allow subdiffraction optics at the cost of complex near‐field manipulation. Recently, optical superoscillatory phenomena were employed to realize superresolution lenses in the far field, but suffering from very narrow working wavelength band due to the fragility of the superoscillatory light field. Here, an ultrabroadband superoscillatory lens (UBSOL) is proposed and realized by utilizing the metasurface‐assisted law of refraction and reflection in arrayed nanorectangular apertures with variant orientations. The ultrabroadband feature mainly arises from the nearly dispersionless phase profile of transmitted light through the UBSOL for opposite circulation polarization with respect to the incident light. It is demonstrated in experiments that subdiffraction light focusing behavior holds well with nearly unchanged focal patterns for wavelengths spanning across visible and near‐infrared light. This method is believed to find promising applications in superresolution microscopes or telescopes, high‐density optical data storage, etc.

     

基于大功率LED扩展光源的均匀光斑光辐射模拟器设计

基于边缘光线原理和光学扩展量守恒思想,结合复合抛物面聚光器和轴对称自由曲面透镜,设计并研制了大功率发光二极管扩展光源的反射/折射准直器.运用Tracepro软件对系统进行光束追迹模拟仿真和实验,研制出均匀光斑的光辐射模拟器.模拟器输出发散角为±12°光束,测量距离出射面50cm处光屏的光斑,在尺寸为14cm×14cm的光照范围内,测得光斑水平方向中心线上的光度均匀度优于4.1%,竖直方向中心线上的光度均匀度优于3.8%.     

可调焦胶囊内窥镜光学系统设计

为解决胶囊内窥镜分辨率与景深相互制约的问题,将一种单液体、电控、可变焦液体透镜应用到内窥镜光学系统中进行光学设计,在保证分辨率的同时,扩大了系统景深.采用CODE V软件进行设计,建立系统初始结构,构造液体透镜模型,基于液体透镜中液体的体积不变,曲率、孔径和厚度可变的结构约束特点,在MATLAB中计算出不同物距下透镜的曲率、孔径和厚度数据,将其导入CODE V的系统模型中,并提出了相应的优化流程.设计并优化带有液体透镜的胶囊内窥镜系统,实现了系统在3~100mm景深范围内的清晰成像,视场角大于110°,全视场范围内调制传递函数在40lp/mm频率下均大于0.3.     

镜面偏心测量光学系统设计及其杂光分析

为了解决现有镜面偏心测量设备存在的问题,本文研究了一种采用切换镜头和调焦相结合的方法来设计的镜面偏心测量光学系统,使用这个光学系统,既能使被测镜面的曲率半径扩展到-∞~+∞范围,又能保证测量精度。通过Lighttools软件对这个光学系统进行光线追迹,分析其杂光分布,结果表明:准直镜头内部多次反射产生的杂光强度很低,可以忽略。而当被测镜头中存在相邻球心像距的镜面时,产生的杂光强度比较大,在后续的图像处理过程中,必须增强目标图像的对比度。利用研制的镜面偏心测量设备进行测量实验,结果进一步验证了杂光分析的正确性。     

Adaptive nematic liquid crystal lens array with resistive layer

ABSTRACT

We propose an adaptive nematic liquid crystal (LC) lens array using a dielectric layer with low dielectric constant as resistive layer. With the resistive layer and periodic-arranged iridium tin oxide (ITO) electrodes, the vertical electric field across the LC layer varies linearly over the lens aperture is obtained in the voltage-on state. As a result, a centrosymmetric gradient refractive index profile within the LC layer is generated, which causes the focusing behaviour. As a result of the optimisation, a thin cell gap which greatly reduces the switching time of the LC lens array can be achieved in our design. The main advantages of the proposed LC lens array are in the comparatively low operating voltage, the flat substrate surface, the simple electrodes, and the uniform LC cell gap. The simulation results show that the focal length of the LC lens array can be tuned continuously from infinity to 3.99 mm by changing the applied voltage.     

转换屏发光光谱对闪光照相成像质量影响研究

转换屏的X射线激发发光光谱与透镜系统的匹配偏差会对闪光照相光电接收系统的成像质量造成影响.提出了一种一维线阵全分辨的模拟计算方法,对在理想光源照射下系统成像视觉全分辨能力进行了模拟计算.用白光光源加滤波片照明分辨率板的实验方法,对不同光源照射下系统的成像质量进行了评估.分析表明,转换屏发光宽光谱及其中心波长与透镜系统不匹配均对成像分辨率造成一定影响,而对图像对比度造成较大影响.只有在透镜系统针对的消像差波段540～550 nm附近窄带发光的转换屏,其成像质量才能基本不受匹配影响,近似于模拟计算的结果.     

关于左手性介质几何光学的研究(一)

根据几何光学中的费马原理和完善成像原理研究了光线经过正负折射率界面时的传播特性,推导了单负折射率完善成像的曲面方程,讨论了单块负折射率透镜成像特性的一些缺陷及改进方案,依此指出了最短时间原理的适用范围的局限性和利用左手性介质制作光学器件的优越性,为进一步研究左手性介质的光学特性和相关光学器件设计提供了理论基础.