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31.
Linear and nonlinear optical properties of racemic (±)2-(α-methylbenzylamino)-5-nitropyridine ((±)MBANP) single crystals have been comprehensively investigated and compared with those of the enantiomorph (–)2-(α-methylbenzylamino)-5-nitropyridine ((–)MBANP) crystals. (±)MBANP crystal exhibits very high chemical and physical stability, but relatively small nonlinear optical coefficients (d31 = 6.8 pm/V, d32 = 4.7 pm/V, d33 = 0.84 pm/V). A comparison between the nonlinear optical coefficients of (±)MBANP and (–)MBANP demonstrates the validity of the oriented-gas model in molecular crystals that neglects all the contributions from intermolecular interaction. 相似文献
32.
A. L. Ivanovskii 《Theoretical and Experimental Chemistry》2007,43(1):1-27
The present state of research on the production and modeling of nanostructures based on titanium carbide-a typical representative
of an extensive class of carbides of d-and f-metals-is reviewed. Methods for the synthesis of various Ti-C nanostructures
(molecular clusters, nanocrystallites, nanospheres, nanofibers, nanowires) are examined, and their morphology, atomic structure,
and known physicochemical characteristics are described. Theoretical models of the atomic structure and properties of new
types of nanostructures in the titanium-carbon system (endo-and exohedral titanofullerenes, “hybrid” structures based on carbon
nanotubes, the so-called peapods, nanocables, and a number of others) and the prospects for their application as components
of nanoceramics, hydrogen accumulators, materials for spintronics, etc. are discussed.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 1, pp. 1–23, January–February, 2007. 相似文献
33.
34.
Daria E. Lonsdale Geoffrey Johnston‐Hall Amanda Fawcett Craig A. Bell Carl N. Urbani Michael R. Whittaker Michael J. Monteiro 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3620-3625
In this work, we propose that retardation in vinyl acetate polymerization rate in the presence of toluene is due to degradative chain transfer. The transfer constant to toluene (Ctrs) determined using the Mayo method is equal to 3.8 × 10?3, which is remarkably similar to the value calculated from the rate data, assuming degradative chain transfer (2.7 × 10?3). Simulations, including chain‐length‐dependent termination, were carried out to compare our degradative chain transfer model with experimental results. The conversion–time profiles showed excellent agreement between experiment and simulation. Good agreement was found for the Mn data as a function of conversion. The experimental and simulation data strongly support the postulate that degradative chain transfer is the dominant kinetic mechanism. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3620–3625, 2007 相似文献
35.
抓好数学建模竞赛 推动数学教学改革 总被引:5,自引:0,他引:5
本文通过近几年组织数学建模教学和指导学生参加竞赛的实践 ,探索抓好数学建模竞赛 ,促进数学教学改革 ,推动数学素质教育 ,提高人才培养质量的途径、措施和方法 相似文献
36.
The Rio de la Plata is a large and shallow water body that discharges onto the Atlantic Ocean. The main driving forces for the river flow are the bathymetry, tides, the outflow from the Paraná and Uruguay rivers and the winds. A numerical model covering the entire river was set up with the objective of increasing our understanding of the hydrographical features and morphological dynamics in the Estuary. The simulations revealed a counter-clockwise residual circulation in the Samborombón Bay and an eastward net flow near the Uruguayan coast. The residual flow is forced by both the tides and the bathymetry. The residence time for the entire river ranges from 40 to 80 days. However, residence times above 120 days was found in the Samborombón Bay. Three corridors of flow have been identified. 相似文献
37.
Stability and bifurcation in a delayed predator-prey system with Beddington-DeAngelis functional response 总被引:1,自引:0,他引:1
Zhihua Liu 《Journal of Mathematical Analysis and Applications》2004,296(2):521-537
We consider a delayed predator-prey system with Beddington-DeAngelis functional response. The stability of the interior equilibrium will be studied by analyzing the associated characteristic transcendental equation. By choosing the delay τ as a bifurcation parameter, we show that Hopf bifurcation can occur as the delay τ crosses some critical values. The direction and stability of the Hopf bifurcation are investigated by following the procedure of deriving normal form given by Faria and Magalhães. An example is given and numerical simulations are performed to illustrate the obtained results. 相似文献
38.
Gabriela Jeronimo Teresa Krick Juan Sabia Martín Sombra 《Foundations of Computational Mathematics》2004,4(1):41-117
We present a bounded probability algorithm for the computation of the
Chowforms of the equidimensional components of an algebraic variety. In particular,
this gives an alternative procedure for the effective equidimensional decomposition
of the variety, since each equidimensional component is characterized by its Chow
form.
The expected complexity of the algorithm is polynomial in the size and the geometric
degree of the input equation system defining the variety. Hence it improves (or
meets in some special cases) the complexity of all previous algorithms for computing Chow forms. In addition to this, we clarify the probability and uniformity aspects,
which constitutes a further contribution of the paper.
The algorithm is based on elimination theory techniques, in line with the geometric
resolution algorithm due to M. Giusti, J. Heintz, L. M. Pardo, and their collaborators.
In fact, ours can be considered as an extension of their algorithm for zero-dimensional
systems to the case of positive-dimensional varieties. The key element for dealing
with positive-dimensional varieties is a new Poisson-type product formula. This
formula allows us to compute the Chow form of an equidimensional variety from a
suitable zero-dimensional fiber.
As an application, we obtain an algorithm to compute a subclass of sparse resultants,
whose complexity is polynomial in the dimension and the volume of the input
set of exponents. As another application, we derive an algorithm for the computation
of the (unique) solution of a generic overdetermined polynomial equation system. 相似文献
39.
T. Beda 《Journal of Polymer Science.Polymer Physics》2007,45(13):1713-1732
A constitutive phenomenological model completing the Gent‐Thomas concept is carried out to formulate laws governing the hyperelastic behavior of incompressible rubber materials. It is shown that the phenomenological Gent‐Thomas model (1958) and the constrained chain model (1992) give similar precise results at small to moderate deformation. On the other hand, comparisons of the outcome of the proposed model with that of the molecular model from the combined concepts of Flory‐Erman and Boyce‐Arruda (2000), and with those of the phenomenological models of Ogden (1982), Yeoh‐Fleming (1997), Pucci‐Saccomandi (2002) and Beda (2005) are made. Residual inconveniences raised by attractive continuum models in rubber elasticity literature have been successfully overcome. Results from both the statistical and phenomenological mechanics concepts are compared with the data of some useful classical materials (rubbers of Treloar, Rivlin‐Saunders, Pak‐Flory and Yeoh‐Fleming). The results permit one to see salient equivalence of the two theories for a more reliable prediction of stress‐stretch response for all states of any mode of deformation. A complete and exhaustive analysis of the Mooney plot that combines small and very large extension‐compression has been quite essential in assessing the validity of models. A method of identification of material parameters is presented and data of the simple tension suffice for the determination of the parameter values. It is shown that the ordinary identification procedures, such as the usual least squares, a very much used numerical method in materials investigation, can be unsuitable in some cases of hyperelastic modeling. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1713–1732, 2007 相似文献
40.
Regularity of Harmonic Functions in Cheeger-Type Sobolev Spaces 总被引:3,自引:0,他引:3
We give a geometric approach to the study of the regularity of harmonic functions in Cheeger-type Sobolev spaces, and prove the Hölder continuity of such functions. In the proof, we give a definition of an upper curvature bound of the unit sphere of a Banach space, which seems to be of independent interest. 相似文献