无铅焊膏用助焊剂的制备与研究

无铅焊膏用助焊剂需要一定的黏性,选择有机酸和有机胺混合作为活性物质,配合一定量的松香配制出一种助焊剂。通过控制助焊剂中松香的含量,降低不挥发物的含量,减少残留物对元器件的腐蚀。依据标准对所配制的助焊剂进行了性能测试,并与一种松香含量较高的助焊剂比较。结果表明:助焊剂的松香含量降低约10%,在260℃焊接后不挥发物含量降低了近6%,黏度较好,无卤化物,无毒,环保,符合焊膏用助焊剂的要求。     

无铅焊膏用助焊剂活性物质的研究

选择几种常用活性剂进行铺展面积和润湿力性能测试,对效果较好的活性剂进行复合处理;采用铺展试验优化,模拟实际回流焊工艺进行性能测试,得到了一种较好的助焊剂。结果表明:当A酸、B酸和C酸的复合质量比为2:4:1,加入质量分数约0.56%的三乙醇胺时,溶液的pH值约为3.80,钎料焊后的扩展率可接近80%。由此配制的焊膏焊接性能良好,腐蚀性小,焊后残留量低,存储寿命较长。     

探针移动速度对等离子体射流热流密度测量结果的影响

采用自行研制的中心嵌有铜柱感应件的小尺寸杆状热流探针,在低扰动条件下,对射入大气环境的纯氩层流等热离子体射流传向铜探头表面的热流密度进行了动态测量.结果表明,在射流最高温度16500 K、最大轴向速度850 m/s、探针垂直于射流流动方向的移动速度130～260 mm/s的实验参数范围内,随着探针移动速度的提高,测得的热流密度值减小;射流温度和速度越高,探针移动速度对热流密度测量值的影响越大.     

ThSi2 Type Ytterbium Disilicide and its Analogues YbTxSi2–x (T = Cr,Fe, Co)

YbSi₂ and the derivatives YbT_xSi_2–x (T = Cr, Fe, Co) crystallizing in the α‐ThSi₂ structure type were obtained as single crystals from reactions run in liquid indium. All silicides were investigated by single‐crystal X‐ray diffraction, I4₁/amd space group and the lattice constants are: a = 3.9868(6) Å and c = 13.541(3) Å for YbSi₂, a = 4.0123(6) Å and c = 13.542(3) Å for YbCr_0.27Si_1.73, a = 4.0142(6) Å and c = 13.830(3) Å for YbCr_0.71Si_1.29, a = 4.0080(6) Å and c = 13.751(3) Å for YbFe_0.34Si_1.66, and a = 4.0036(6) Å, c = 13.707(3) Å for YbCo_0.21Si_1.79. YbSi₂ and YbT_xSi_2–x compounds are polar intermetallics with three‐dimensional Si and M (T+Si) polyanion sub‐networks, respectively, filled with ytterbium atoms. The degree of substitution of transition metal at the silicon site is signficant and leads to changes in the average bond lengths and bond angles substantially.     

Study of a dipping method for flip-chip flux coating

A dipping method for flux coating is proposed in the paper. Flow process of the flux transferred into the groove is investigated by using an optical detection means. Flow process influenced by gluing speed and viscosity is analyzed by using two indicators including reflective area ratio and flow velocity. Experimental result shows that stably reflective area ratio of glue is associated with gluing speed instead of viscosity; and it decreases with the increase of gluing speed in a same viscosity. The reason is that different gluing speed changes the amount of the glue transferred to the groove. Flow velocity of glue is related with gluing speed, a greater gluing speed leads to greater maximum flow velocity at the same viscosity, which may be due to larger gluing speed gives greater inertial force to the glue. Real chip experiments verified the feasibility of this method.     

Application of the photon's intrinsic flux to the 1s‐2p and 2p‐3d excitonic transitions in nanostructures

We have applied our two recent results [depending on its helicity photon carries a quantum flux of ± Φ ₀ = ± hc/e and the quantized magnetic fluxes through the electronic orbits of the Dirac hydrogen atom are given by: Φ (n,l,m_j) = (n‐l‐m_j)Φ₀) ] to the 1s‐2p and 2p‐3d excitonic transitions in nanostructures. It is shown that the flux changes for the non‐zero matrix elements in the 1s‐2p and 2p‐3d excitonic transitions is either ± Φ₀ or zero. The present result supports the previous results stated above. It is also shown that spin flip is possible in the 1s‐2p and 2p‐3d excitonic transitions.     

A well‐balanced upstream flux‐splitting finite‐volume scheme for shallow‐water flow simulations with irregular bed topography

This study extends the upstream flux‐splitting finite‐volume (UFF) scheme to shallow water equations with source terms. Coupling the hydrostatic reconstruction method (HRM) with the UFF scheme achieves a resultant numerical scheme that adequately balances flux gradients and source terms. The proposed scheme is validated in three benchmark problems and applied to flood flows in the natural/irregular river with bridge pier obstructions. The results of the simulations are in satisfactory agreement with the available analytical solutions, experimental data and field measurements. Comparisons of the present results with those obtained by the surface gradient method (SGM) demonstrate the superior stability and higher accuracy of the HRM. The stability test results also show that the HRM requires less CPU time (up to 60%) than the SGM. The proposed well‐balanced UFF scheme is accurate, stable and efficient to solve flow problems involving irregular bed topography. Copyright © 2009 John Wiley & Sons, Ltd.     

An Experimental Study of a Flux Modulated Solid State Metathesis Reaction

A solid state metathesis (SSM) reaction was investigated with respect to the formation of rare‐earth carbodiimides, the role of the co‐produced salt (LiCl), and the eutectic flux medium (LiCl/KCl). A SSM reaction is characterized by an exothermic reaction in which a salt (often LiCl) is coproduced. When the salt melts, it can serve as a useful medium for the crystallization of a desired product. An improved crystal growth can be observed by using an eutectic flux. However, the composition of an eutectic LiCl/KCl flux is altered when LiCl is produced during the reaction. The thermal effects concerning the endothermic melting of the flux and the exothermic ingnition of the SSM reaction may compensate each other, which is not necessarily a drawback for the reaction to proceed.     

Comparison of adjustable permanent magnetic field sources

A permanent magnet assembly in which the flux density can be altered by a mechanical operation is often significantly smaller than comparable electromagnets and also requires no electrical power to operate. In this paper five permanent magnet designs in which the magnetic flux density can be altered are analyzed using numerical simulations, and compared based on the generated magnetic flux density in a sample volume and the amount of magnet material used. The designs are the concentric Halbach cylinder, the two half Halbach cylinders, the two linear Halbach arrays and the four and six rod mangle. The concentric Halbach cylinder design is found to be the best performing design, i.e. the design that provides the most magnetic flux density using the least amount of magnet material. A concentric Halbach cylinder has been constructed and the magnetic flux density, the homogeneity and the direction of the magnetic field are measured and compared with numerical simulation and a good agrement is found.