Determination of fungicides in sediments using a dispersive liquid–liquid microextraction procedure based on solidification of floating organic drop

A dispersive liquid–liquid microextraction procedure based on solidification of floating organic droplet has been investigated for the determination of fungicides (cyprodinil, difenoconazole, myclobutanil, and spiroxamine) in sediments by HPLC with diode array detection. In the overall extraction process, the extraction solvents can be separated easily from the sample solution, and the experiment time was shortened. Moreover, several parameters such as the type and volume of the extraction solvent and dispersive solvent, centrifugal speed, extraction time, and salt effect that affect the extraction efficiencies of the target fungicides were studied and optimized. Under the optimized conditions, the LOD for the target analytes were in the range of 0.1–0.5 μg/g. Satisfactory recoveries of the target analytes in the sediment samples were 81.00–99.00%, with RSDs (n = 5) that ranged from 1.8 to 6.5%. Finally, the simple, sensitive, and environmentally friendly method was successfully applied to determine the target fungicides in actual sediment samples.     

The frequency of CFVD speed report for highway traffic

The control signals of cellular networks have been used to infer the traffic conditions of the road network. In particular, consecutive handover events are being used to estimate the traffic speed. During traffic congestion, consecutive handover events may be rare because vehicles move slowly, and thus very few or no speed reports would be generated from the congested area.However, the traffic speed report rate during traffic congestion has not been investigated in the literature. In this paper, we present an analytic model to estimate the speed report rate from cellular network signaling in steady traffic conditions, that is, the traffic speed and flow are assumed constant. Real field trial data were used to validate our analytic model. In addition, computer simulations were conducted to study how speed reports are generated in dynamic traffic conditions when traffic speed and flow change rapidly. Our study indicates that in a typical cell of length 1.5 km with a typical expected call holding time of 1 min, no speed report was generated from a congested three‐lane highway. Our study demonstrates that the lack of speed reports from consecutive handover events during rush hours indicates severe traffic congestion, and new methods that can estimate traffic speed from cellular network data during severe traffic congestion need to be developed. Copyright © 2013 John Wiley & Sons, Ltd.     

运载火箭试验数据管理及可视化系统设计

针对现有运载火箭试验数据管理及可视化系统依赖于第三方功能插件,未实现纯浏览器端三维模型渲染及交互,系统对运行环境依赖性强、部署和维护成本高等问题,设计了基于JavaScript框架ExtJS和WebGL框架three.js的运载火箭试验数据管理及可视化系统。首先基于B/S架构设计了系统总体框架,然后针对二维图形数据传输延迟问题设计了基于Web Worker的数据读取方案,最后针对浏览器端三维模型渲染需求提出了基于VTK模型的转换算法,设计了三维模型渲染及交互方案。试验结果显示,本系统不依赖于运行环境和功能插件,能实现浏览器端二维图形和三维模型渲染及流畅交互,为兼容国产化操作系统、降低部署和维护成本创造了条件。     

悬浮固化-分散液液微萃取-液相色谱-串联质谱测定纺织废水中磷系阻燃剂

建立了悬浮固化-分散液液微萃取结合液相色谱-串联质谱测定纺织废水中5种痕量磷系阻燃剂的方法。通过对萃取过程中萃取剂、分散剂的种类与体积、盐浓度、溶液pH值等对萃取效率的影响因素优化,确立了最佳萃取条件。采用了密度小于水的十一烷醇（400 μL）为萃取剂,甲醇（300 μL）为分散剂,控制溶液pH值在6~9之间,NaCl添加量为2 g,萃取时间为涡旋2 min。在优化的萃取条件下,该方法在2~100 μg/L均有良好的线性关系,相关系数大于0.995,除二（2,3-二溴丙基）磷酸酯（BIS）的检出限为5 μg/L外,三（2-氯乙基）磷酸酯（TCEP）、三（1,3-二氯-异丙基）磷酸酯（TDCP）、三（1-氮丙啶基）氧化膦（TEPA）和三（2,3-二溴丙基）磷酸酯（TRIS）的检出限均为2 μg/L。后整理、染色和印花等实际废水样品加标试验表明,方法的平均回收率为71.6%~114.5%,RSD为2.7%~11.2%（n=6）。对11个样品进行检测,其中3个废水样品检出TCEP与TDCP化合物,含量为2.6~3.4 μg/L。本方法简单,快速,灵敏度好且环保绿色,能够对纺织废水中的5种痕量磷系阻燃剂进行准确的定性与定量检测。     

大气环境下的钢筋混凝土桥梁时变可靠度分析

为了探究钢筋混凝土桥梁抗力退化对桥梁可靠性能的影响,综合考虑一般大气环境下混凝土强度、钢筋强度、混凝土与钢筋黏结性能的降低,建立普通钢筋混凝土桥梁的抗力退化时变模型,分析规范车辆荷载作用的桥梁时变可靠度。研究结果表明,(1)一般大气环境下,桥梁抗力随着服役时间的增加而减小,其中钢筋强度退化对桥梁抗力的影响最大,其次是钢筋与混凝土黏结性能降低,而混凝土强度退化对桥梁抗力的影响相对较小; (2)桥梁可靠指标随着服役时间的增加而减小,密集行车占比越大,桥梁承载能力失效的概率就越大;非平稳车载作用下的桥梁可靠指标小于平稳车载,桥梁需要维修补强的时间比平稳车载提前; (3)多梁式简支梁桥在建造时应该提高边梁的安全储备,在管养时可以采取限载措施进行干预。     

绝缘体上硅动态阈值nMOSFETs特性研究

基于绝缘体上硅技术,提出并研制动态阈值nMOSFETs结构.阐述了动态阈值nMOSFETs的工作原理.动态阈值nMOSFETs的阈值电压从VBS=0 V时的580 mV动态变化到VBS=0.6 V时的220 mV,但是这种优势并没有以增加漏电流为代价.因此动态阈值nMOSFETs的驱动能力较之浮体nMOSFETs在低压情况下,更具有优势.工作电压为0.6 V时,动态阈值nMOSFETs的驱动能力是浮体的25.5倍,0.7 V时为12倍.而且浮体nMOSFETs中的浮体效应,诸如Kink效应,反常亚阈值斜率和击穿电压降低等,均被动态阈值nMOSFETs结构有效抑制.     

基于雷达的嵌入式车载辅助驾驶系统的设计

提高车辆驾驶的安全性和舒适性是智能交通系统(ITS)的主要研究内容之一.介绍了自行研制的车载辅助驾驶系统,论述了其基本设计思想和总体方案.对系统的硬件实现、基于模糊推理的辅助驾驶系统的控制算法和雷达信号的Kalman滤波等技术进行了研究.经过现场试验证明该系统是切实可行的,在汽车行进过程中具有安全距离保持的功能,并且较好地体现了驾驶员的驾驶特征.     

海上舰船(群)三线防御技术研究

介绍了海上舰船目标(群)进行三线防御的特点和使用时机,分析了不同发射方式下运载物的飞行轨迹及投弃点的确定程序,针对新一代反舰船导弹末制导雷达体制,重点阐述了海上舰船目标第三线防御的基本技术措施.     

GB 18655—2002中车载零部件发射测量骚扰限值的选择方法

通过实际的两个测试案例,分析讨论了在运用GB18655—2002对车载零部件进行发射测试时,选用适当的骚扰限值的方法。认为以标准中的辐射/传导骚扰的符合性判断流程图为主,宽带骚扰举例及窄带骚扰源的定义为辅,综合考虑,才能选择出适当的骚扰限值,得到正确的测试结果。     

PIV水下流场测试系统试验研究

基于粒子图像测速技术,设计研制了一套适用于水洞洞体内高速、封闭试验条件的流场测量与显示设备.该系统由光源、成像、图像处理与分析、控制和粒子投放等分系统组成,具有复杂环境下全流场的无接触、无扰动、高准确度测量和显示能力,流场测试误差小于2%,可为水下航行器外形设计及其改进提供相关的实测数据.