粉末材料爆炸压实数值模拟

本文对粉末爆炸压实数值模拟作了系统评述。首先叙述了流体弹塑性体的模型、方程和计算方法;然后对一些典型的程序编码作了介绍;总结了粉末爆炸压实数值模拟最新进展,最后,对未来发展方向提出了我们的看法．      

溴化银晶体光谱敏化光电流的研究和染料增感性能的判据

本文以AgBr晶体和菁染料为对象,对AgBr晶体的光电流进行了研究。实验发现,AgBr晶体经其本征吸收波长的光辐照后,可产生新的诱导吸收带。用诱导吸收带波长范围内的光辐照AgBr晶体,在非本征吸收区可测量到自敏化光电流。若染料吸附在AgBr晶体片上,则其敏化光电流将叠加在自敏化光电流上。增感染料对AgBr晶体的阳极和阴极光电导均有不同程度的敏化作用。本文在实验研究的基础上,提出了对染料增(减)感性能的判据S_D,比现有的一些判据更具有综合性。利用S_D—λ曲线可以较直观地对染料的增(减)感性能做出预测。本文利用S_D判据对一些实用增感染料及其组合作了分析。     

染料黑白片XP1 400的粒度研究

本文测定了依尔福染料黑白片XP1 400在XPI套药中冲洗的染料影像及中间银影像的均方根粒度,同时又测定了在同样曝光条件下的涂层在普通黑白显影液中冲洗的黑白银影像的均方根粒度。结果表明,三种影像粒度随密度变化的规律完全不同。本文又用selwyn公式计算了中间银影像及黑白银影像的单位面积显出颗粒数,测试和计算结果表明,与黑白银影像比较,中间银影像具有均方根粒度明显低和单位面积显出颗粒数高的特点。这与光学显微镜下现察到的中间银影像及黑白银影像的形态是一致的。本文还根据实验及计算结果讨论了DIR成色剂在影像形成过程中的作用。     

某些有机物在溴化银重结晶过程中的作用

卤化银晶体的习性对乳剂的照相性能起决定性作用。因此多年来人们对影响卤化银晶体物理成熟过程的各种因素进行了研究。     

Phase Diagram of RbI-SmI_2 Binary System and Structural Investigation of RbSm_2I_5 and RbSmI_3

The RbI-SmI2 , binary system was studied with DTA and X-ray powder diffraction. Its phase diagram shows that it has a congruently melting compound,RbSm2I5 , with a melting point 524℃; an incongru-ently melting compound, Rb2SmI4 , with an inconsruently point 467℃ and two compounds, RbSmI3, and Rb3SmI5, being decomposed at 433℃ and 460℃, respectively. The measured structure of RbSm2I5 shows that it is isomorphous with NH4 Pb2 Cl5 space group P21/c, a=10 . 063(3)A, b=9.003(3)A. c =14 . 242(5)A°,β=90.23(3)°;z = 4, MVx= 1 94 . 3cm3/mol;D=5.255g/cm3 and Do =5. 334g/cm3 (25. 0℃).The structural, investigation ofRbSmI3 shows that it belongs to the orthorhombic system with a = 15.914(6)A, b=8.898(3)A c =12.193(5)A; Z=8, MVx =130.0cm3/mol, Dx =4 . 743g/cm3,Do = 4.597g/cm3(25.0℃).     

镓一镁二元相图研究

本文用两种差热分析方法即“一步法”和“二步法”以及多晶X-射线衍射法对镓-镁二元系相图进行了研究.修正了前人的工作. 为了考察该二元体系的金属间化合物是否以镓原子多面体簇状结构存在,作者对富镓部分相图(镓原子百分含量大于71.4％)进行了较为细致的研究.在三种不同比例下(含镓量分别为85at.％、90at.％、95at.％)合成,分离得到了颗粒状晶体.对这些晶体进行了差热分析和多晶X-射线研究.分析结果表明:从这三种不同比例的合金中分离得到的晶体为同一金属间化合物Mg_2Ga_5,也是该二元系镓含量最高的金属间化合物.考察Ga-Mg体系中存在的五种金属间化合物的结构,未能发现镓原子以多面体簇状结构存在的现象.     

铝硅钛合金表面激光合金化研究

在锅硅钛合金表面,用G312铁基合金粉进行了激光合金比实验,用金相显微镜和显微硬度计对试样进行了观察和测试,对一种异常的实验现象进行了讨论。     

送粉式激光熔覆获得最佳熔覆层的必要条件及其影响因素

在分析自动送粉式激光熔覆过程中熔覆材料颗粒加入方式及其在激光束中的行为的基础上,建立热平衡方程,推导出反映熔覆过程实际情况的参数：熔覆材料颗粒尺寸、在激光束中运动距离、加热温度、激光功率密度之间的相互关系式等。指出在自动送粉式激光熔覆中能够获得最佳熔覆层的必要条件是：熔覆材料颗粒进入激光束后直到其落到基体材料表面之前,必须始终在激光束中。激光束沿着扫描方向必须有足够的宽度是满足上述条件的关键,同时提出其计算方法及公式,并阐明获得最佳熔覆层的工艺参数之间的匹配原则     

Exploring the Antibacterial and Antibiofilm Efficacy of Silver Nanoparticles Biosynthesized Using Punica granatum Leaves

The current research work illustrates an economical and rapid approach towards the biogenic synthesis of silver nanoparticles using aqueous Punica granatum leaves extract (PGL-AgNPs). The optimization of major parameters involved in the biosynthesis process was done using Box-Behnken Design (BBD). The effects of different independent variables (parameters), namely concentration of AgNO₃, temperature and ratio of extract to AgNO_3, on response viz. particle size and polydispersity index were analyzed. As a result of experiment designing, 17 reactions were generated, which were further validated experimentally. The statistical and mathematical approaches were employed on these reactions in order to interpret the relationship between the factors and responses. The biosynthesized nanoparticles were initially characterized by UV-vis spectrophotometry followed by physicochemical analysis for determination of particle size, polydispersity index and zeta potential via dynamic light scattering (DLS), SEM and EDX studies. Moreover, the determination of the functional group present in the leaves extract and PGL-AgNPs was done by FTIR. Antibacterial and antibiofilm efficacies of PGL-AgNPs against Gram-positive and Gram-negative bacteria were further determined. The physicochemical studies suggested that PGL-AgNPs were round in shape and of ~37.5 nm in size with uniform distribution. Our studies suggested that PGL-AgNPs exhibit potent antibacterial and antibiofilm properties.     

茂基稀土配合物催化纳米镁粉的加氢反应

Organo lanthanide complex (C 5Me 5)NdCl 2·LiCl has been found to be an efficient catalyst for the hydrogenation of nanometric magnesium powder. This magnesium powder was generated by the thermal decomposition of magnesium anthracene in THF at 90～150 ℃ under vacuum. Suitable temperatures for the catalytic hydrogenation of nanometric magnesium powder are between 150～185 ℃ which are much lower than that of the nanometric magnesium powder without catalyst.