含吩噻嗪金属配合物的合成及非线性光学性质研究

本文报道了一种新的配体:10-乙基-3-甲酰吩噻嗪缩肼基二硫代甲酸甲酯(HL)及其金属配合物的合成。采用了元素分析、质谱、核磁共振、红外光谱对配体及其金属配合物进行了表征。此外,并应用紫外、荧光和Z-扫描技术,测定了配体及其金属配合物的荧光最佳发射波长(λ_max^em)、荧光量子产率(Φ_f)、寿命(τ)和非线性光学性质。结果表明它们在DMF溶液中都能发射出较强的橄榄色荧光,配体及其金属配合物都有双光子吸收,并且金属配合物的非线性光学效应比配体明显增强。用半经验量子化学方法(RHF/PM3)计算结果与实验值较为吻合。     

拓扑指数法研究显色剂结构与反应性能关系

本文讨论了２９个不对称色酸双偶氮膦酸型显色剂的分子联接性指数，并将其与结构选择性因子相结合，用于偶氮类剂结构与铈显色反应灵敏度的相关性研究，讨论了显色剂结构对显色反应灵敏度的影响。     

雷尼镍催化剂的吸附量热研究

雷尼镍催化剂的吸附量热研究王益沈俭一（南京大学化学系，南京２１００９３）ＨａｎｓＷａｒｌｉｍｏｎｔ（ＩｎｓｔｉｔｕｔｅｆｏｒＳｏｌｉｄＳｔａｔｅａｎｄＭａｔｅｒｉａｌｓＲｅｓｅａｒｃｈ，ＤｒｅｓｄｅｎＤ０１０６９，Ｇｅｒｍａｎｙ）关键词雷尼镍...     

SA耐火材料多晶结构与性能的研究

本实验采用磨具废砂和炉皮SiC废砂生产SA耐火材料，通过XRD分析和计算机处理确定各试样中的晶相（4H－SiC，33R－SiC，3C－SiC，α－Al2O3，β-石英和Al6Si2O13）及其各相的含量。通过材料性能与结构综合分析，确定较好的配方，其含量：磨具废砂50％，炉皮砂45％，结合剂5％，外加矿化剂2％。     

Networks and chain coverings in partial orders and their products

For an arbitrary poset P, subposets {P _i : 1ik} form a transitive basis of P if P is the transitive closure of their union. Let u be the minimum size of a covering of P by chains within posets of the basis, s the maximum size of a family of elements with no pair comparable in any basis poset, and a the maximum size of an antichain in P. Define a dense covering to be a collection D of chains within basis posets such that each element belongs to a chain in D within each basis poset and is the top of at least k-1 chains and the bottom of at least k-1 chains in D. Dense coverings generalize ordinary chain coverings of poset. Let d=min {|D|–(k–1)|P|}. For an arbitrary poset and transitive basis, a convenient network model for dense coverings yields the following: Theorem 1: da, with equality iff P has a minimum chain decomposition in which every pair of consecutive elements on each chain are comparable in some basis poset. Theorem 2: usda. Theorem 3: s=d iff s=a. The most interesting special case is where the transitive basis expresses P as the product of two posets, in which case u and s measure the minimum and maximum sizes of unichain coverings and semiantichains.     

meso-四(对烷氧苯基)卟啉金属配合物的合成和性能研究(IV)

合成了系列卟啉乙酸合锰配合物9个,其中6个为未见文献报道的新化合物.用UV,1HNMR,IR,MS,元素分析等表征确证了配合物的结构,总结了锰与卟啉类配体配合的IR,UV,1HNMR判据.采用差示扫描量热法(DSC)和偏光显微镜(PM)研究了该系列配合物的液晶性能,发现8个配合物具有液晶性.考察了烷氧基链长、配位金属离子和分子空间结构对液晶性能的影响.     

Synthesis, crystal structure and spectroscopic properties of an unsymmetrical compound with carbazole and benzothiadiazole units

An unsymmetrical organic compound with carbazole (Cz) as donor and benzothiadiazole (BTD) as acceptor (D-π-A-π∗-D∗) was designed and synthesized via simple Heck reaction. The unique crystal structure of Cz-BTD-Cz∗ shows a ladder-like packing mode. A two molecule pair stacks parallelly with each other in each packing unit. In each cell, one Cz moiety is connected with BTD by vinylene bond in same plane. However, the other Cz group is connected to BTD by a one-end vinyl bond in almost perpendicular position to the coplanar part of the molecule. The shortest intermolecular plane distance is 3.48 ± 0.1 Å. The photophysical properties of Cz-BTD-Cz∗ in solution and in bulky crystalline powder state were studied. In bulk crystalline powder state, it has a red-shifted emission band peaked at 609 nm relative to that in solution, and the FWHM was reduced to only 58 nm. Electrochemical properties were also investigated.     

球形SiO2-Al2O3的制备、结构和性能

将Na2SiO3·9H2O 溶液通过强酸性阳离子树脂进行离子交换得到酸性硅溶胶,再将硅溶胶与铝溶胶及六次甲基四胺混合后采用油柱成型法制备了球形SiO2-Al2O3复合氧化物. 通过XRD、BET 及TPD等手段对样品进行测试和表征, 结果表明, 600 ℃焙烧得到的SiO2-Al2O3中SiO2以无定型形式存在, 其比表面、孔容与表面酸性随SiO2含量的增加而提高, 孔径、堆密度随SiO2含量的提高而减小, 压碎强度基本保持不变.     

纳米稀土谷氨酸咪唑三元配合物的合成、表征及抗菌活性研究

合成了6种新型纳米稀土三元配合物。通过元素分析、摩尔电导、红外光谱、紫外光谱、氢谱、碳谱、热重-差热等表征,确定了该类配合物的化学组成为：RE（Glu）3ImCl3·3H2O（RE=La^3＋,Nd^3＋,Er^3＋,Eu^3＋,Y^3＋,Gd^3＋;Glu=L-谷氨酸;Im=咪唑）,TEM电镜测试表明其有一定规则形貌,粒径在30-60 nm。通过抗菌实验对其抑菌效果进行研究,结果表明：6种纳米稀土三元配合物对大肠杆菌、金黄色葡萄球菌和白色念珠菌均有较强的抑制作用（最小抑菌浓度MIC分别约为140,100,250μg·ml^-1）,属于广谱抗菌剂;抗菌效果明显优于非纳米稀土三元配合物、稀土氯化物、L-谷氨酸或咪唑。     

聚酰胺酸及其接枝衍生物的三阶非线性光学性能研究

设计合成了苯代三聚氰胺与均苯四酸二酐缩聚物, 及不同侧链的p-π共轭缩聚物, 并以量子化学PM3/CIS方法为基础, 利用完全态求和(SOS)公式, 对不同侧链取代的聚酰胺酸的分子进行了几何构型优化, 并计算了其三阶非线性光学系数γ. 研究了不同侧链对聚合物三阶非线性性能的影响. 这些结果对合成具有优良加工性能的三阶非线性光学材料是有一定的指导作用.