Multiple Function Synchronous Optimization by PbS Quantum Dots for Highly Stable Planar Perovskite Solar Cells with Efficiency Exceeding 23%

Colloidal lead sulfide (PbS) quantum dots (QDs), which possess quantum confinement effect and processing compatibility with perovskite, are regarded as an excellent material for optimizing perovskite solar cells (PSCs). However, the existing PSCs optimized by PbS QDs are still facing the challenges of poor performance of the charge transport layers, low utilization in the near-infrared (NIR) region, and unsuitable energy level alignment, which limit the improvement of power conversion efficiency (PCE). Herein, a synchronous optimization strategy is realized via simultaneously introducing PbS QDs into SnO₂ electron transport layer and employing rare-earth-doped PbS QDs (Eu:PbS QDs) film with hydrophobic chain ligands as the NIR light-absorping layer and hole transport layer (HTL) of devices. PbS QDs effectively decrease the density of trap states by passivating defects. Eu:PbS QDs film with adjustable bandgap is employed as an absorption layer to broaden the NIR spectral absorption. The well-matched energy level between Eu:PbS QDs layer and perovskite layer implies efficient hole transfer at the interface. The successful synchronous optimization greatly elevates all photovoltaic parameters, reaching a maximum PCE of 23.27%. This PCE is the highest for PSCs utilizing PbS QDs material in recent years. The optimized PSCs retain long-term moisture and light stability.     

Solid Solvation Assisted Electrical Doping Conserves High-Performance in 500 nm Active Layer Organic Solar Cells

Organic solar cells (OSCs) process fascinating solution-printing capability to achieve low-cost and large-scale manufacture. However, the rapid power conversion efficiency (PCE) decay with active layer thickness enlargement inhibits the implement of OSCs’ potential advantages. To overcome the bottlenecks of PCE decay in thick active layer OSCs, the electrical doping with componential selectivity in bulk heterojunction (BHJ) film is achieved by introducing a solid solvation additive. Benefiting from the higher exciton splitting efficiency together with the longer drift (L_dr) and diffusion (L_diff) lengths, an OSC with 100 nm BHJ film demonstrates a PCE increment from 16.44% to 18.24% with prolonged dark and illuminated storage stabilities. Applying the solid solvation assisted (SSA) doping method in the OSCs with 500 nm active layer, the PCE significantly increases by 31.9%, from the original value of 11.79% to 15.55%. It further improves to 15.84% in a ternary blend thick-film device, which is the record value to the best of our knowledge. Besides, the SSA doping narrows the PCE gap between the 0.04 and 1 cm² devices. All improvements demonstrate the great potential of SSA doping for OSC commercial manufacture, since it optimizes the photovoltaic performance under all practical conditions of long-term, thick-film, and large-area.     

In Situ Electrical Network Activation and Deactivation in Short Carbon Fiber Composites via 3D Printing

Prior studies on carbon-filler based, conductive polymer composites have mainly investigated how conductive filler morphology and concentration can tailor a material's electrical conductivity and overlooks the effects of filler alignment due to the difficulty to control and quickly quantify the filler alignment. Here, direct ink write 3D printing's unique ability is utilized to control carbon fiber alignment with a single process parameter, velocity ratio, to instantaneously activate or deactivate the electrical network in composites. Maximum electrical conductivity is achieved by randomly aligning carbon fibers that enhances the chance of direct fiber-to-fiber contact and, thus, activating the electrical network. However, aligning the fibers by increasing the velocity ratio disrupts the electrical network by minimizing fiber-to-fiber contact that resulted in a drastic decrease in electrical conductivity by as much as five orders of magnitude in both short and long carbon fiber composites. With this study, this study demonstrates that electrically conductive or insulative composites can be fabricated sequentially with a single ink. This novel ability to instantaneously control the electrical conductivity of carbon fiber reinforced composites allow to directly embed conductive pathways into designs to 3D print multifunctional composites that are capable of localized heating and self-sensing.     

Three Potential Elements of Developing Nerve Guidance Conduit for Peripheral Nerve Regeneration

Autograft replaced by a nerve guidance conduit (NGC) is challenging in peripheral nerve injury because current NGC is still limited by precise conductivity and excellent biocompatibility in vivo, which influences the peripheral nerve repair even for a long lesion gap repair. Several particular elements have the potential function for nerve conductivity acceleration based on the traditional three factors of neural tissue engineering. The review aims to address three questions: 1) What is the superior factor for nerve conduction in the application? 2) How can a more conductive regenerative scaffold be constructed in vivo? 3) What is the next step in nerve regeneration for NGC? The bibliometrics analysis of NGC-related references is adopted to acquire that the conductive material, manufacturing technology of neural scaffold, and electrical stimulation (ES) play essential roles in the acceleration of nerve conduction. This review visually analyses the research status and summarizes the main types of conductive materials, the manufacturing technologies of neural scaffolds, and the characteristics of ES. The viewpoints and outlook of developing NGC are also discussed in this review. The proposed three elements are expected to improve the nerve conduction of NGC in vivo and even address the dilemma of long-distance peripheral nerve injury.     

校企协同研究生创新人才培养模式探索

在国家新基建战略以及双碳目标背景下,契合新工科理念,本文提出电气类硕士研究生创新人才培养三大新要求：立德树人、学科交叉、科研服务产业。文章阐述了通过充分发挥协同育人机制,优化课程体系,强化工程实践,科研服务产业发展, 形成了“521”研究生创新人才培养模式(5个培养阶段; 2类教育贯穿始终;1套管理制度),构建了校企无缝对接研究生实践创新能力培养有效机制,取得了持续有效的人才培养效果。     

基于无人机影像的电网绝缘子自爆识别

电网因其在电能传输方面的关键性作用,在我国民生项目建设领域一直扮演着至关重要的角色。电网杆塔上的绝缘子一旦发生自爆(也称“缺陷”),绝缘子会自动剥落,输电线路就会产生安全隐患,严重时会降低输电线路的运行寿命,甚至会引发供电中断,发生大范围的停电事故,造成巨大的财产损失。目前,主流的巡检方法为人工巡检,该方法不仅耗时耗力,而且也存在一定主观出错率,已不适用于目前电路巡检的实际情况。本设计采用YOLO V5网络模型,对无人机航拍影像中绝缘子串及绝缘子自爆进行自动识别。首先通过平移、翻转、裁剪等,对航拍绝缘子影像数据集进行数据增广,并对增广后的数据集在LabelImg中进行标注,然后利用YOLO V5网络模型对绝缘子串及绝缘子自爆进行识别,最后采用PyQt5框架在PyCharm中设计了绝缘子自爆识别的系统界面,对模型进行调用,实现了绝缘子串及绝缘子自爆识别。本设计采用从网络上下载、国家电网提供、数据增广所得到的500张无人机航拍影像作为数据集,对所得数据集进行人工标注,再使用YOLO V5网络模型进行训练和测试,结果表明YOLO V5网络模型对绝缘子串具有较高的识别精度,最高识别精度为90.2%,对绝缘子自爆的最高检测精度为80.8%。这说明了YOLO V5网络模型在绝缘子串识别方面有较好的表现,但是由于训练集中绝缘子自爆的样本影像数量有限,所以该网络模型对绝缘子的自爆识别存在一定局限性,本实验能够部分代替人力实现电网绝缘子智能巡检,提高了检测效率。     

白藜芦醇分子的转动惯量和电偶极矩

通过分子轨道理论和杂化轨道理论推断出较稳定的白藜芦醇分子是平面型分子,然后根据白藜芦醇分子结构特点计算了该化合物的一种稳定异构体的转动惯量,用矢量合成法计算了其电偶极矩,为微波辅助白藜芦醇萃取理论研究提供转动惯量和电偶极矩的数据.     

Accounting for the Adsorption of Anions When Interpreting the Mechanism of Electrodeposition of Metals from Complex Electrolytes: The Reaction Order by the Electrochemically Active Ion

The relationship between the current and the bulk concentration of complex ions during concurrent specific adsorption of an electrochemically active complex ion and a complexing ligand is considered. The effect of parameters that characterize adsorption of such ions and the structure of the electrical double layer on this relationship is analyzed.__________Translated from Elektrokhimiya, Vol. 41, No. 7, 2005, pp. 817–822.Original Russian Text Copyright © 2005 by Rogozhnikov.     

单一稀土Ce, La和混合稀土在工业纯铝中的作用

通过对比实验的方法，研究了稀土Ce，La和混合稀土对工业纯铝组织、电性能和机械性能的影响。结果表明：单一稀土La，Ce可降低工业纯铝的电阻率，提高工业纯铝的导电性，其中La的效果优于Ce．而混合稀土对电阻率几乎无影响；La，Ce和混合稀土均能减小工业纯铝的晶粒度，在其加入量为0．1％后细化效果明显，当其含量大于0．5％后细化效果趋于平缓，其中Ce的效果最佳，La次之，混合稀土最弱；单一稀土La，Ce在一定含量时可提高工业纯铝的σb6和δ，Ce的作用强于La，混合稀土对σb和δ的影响不明显。     

Effect of adsorption of vapours on the electrical conductivity of some polyene semiconductors: adsorption and desorption kinetics

The change in semiconductive properties of β-apo-8′-carotenal, astacene and methyl bixin on adsorption of various vapours on the crystallite surfaces has been studied at a constant sample temperature. The adsorption of vapours enhances the semiconductivity of the polyenes appreciably. This enhancement depends on the chemical nature and also on the pressure of the adsorbed vapour. The adsorption and desorption kinetics follow the modified Roginsky-Zeldovich relation. A two stage desorption process, the first stage of which gives a Lennard-Jones potential energy curve and is followed by a rate-determining transition over a potential energy barrier to the second stage of adsorption forming weakly bound complexes between the vapour molecules and the polyene crystallites, can explain satisfactorily the experimentally observed kinetic data.