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41.
Ogbonnaya Ofor 《Journal of colloid and interface science》1996,180(2):323
Using “pure” natural hematite selected from a high silica Nigerian hematitic ore, oleate adsorption densities at the hematite–water interface were determined in the presence of various inorganic ions (anions and cations) of different charges and at varying concentrations. Adsorption density was determined using electrical conductivity measurements. The specific surface area of the hematite particles was determined using the method of adsorption of paranitrophenol in aqueous solution. Inorganic ions in solution depressed oleate adsorption at the aqueous hematite surface. The charge of the ion proved to be the dominant factor determining the depression of oleate adsorption. Ionic strength also was an influence, up to a limiting value at which monolayer oleate coverage of the hematite surface occurred. The inorganic ions in solution are considered to function through nonspecific adsorption in the diffuse region of the electric double layer. 相似文献
42.
The oxidative polycondensation of 4-[(pyridin-3-ylimino)methyl]phenol (4-PIMP) with O2, H2O2, and NaOCl was studied in an aqueous alkaline medium between 50°C and 90°C. Oligo-4-[(pyridin-3-ylimino)methyl]phenol (O-4-PIMP)
prepared was characterized by 1H-NMR, 13C-NMR, FT-IR, UV-VIS, size-exclusion chromatography, and elemental and thermal analyses techniques. At the optimum reaction
conditions, the yield of O-4-PIMP was 18.9%, 39.4%, and 46.8% using H2O2, O2, and NaOCl oxidant, respectively. According to the TG analysis, the initial degradation temperature of O-4-PIMP was 218°C,
which was by 50°C higher than that of 4-PIMP. Thermal analyses of 4-PIMP and O-4-PIMP were carried out in N2 atmosphere at 15–1000°C. The highest occupied molecular orbital, the lowest unoccupied molecular orbital, and electrochemical
energy gaps of 4-PIMP and O-4-PIMP were determined from the onset potentials for n-doping and p-doping, respectively. Also, optical band gaps of 4-PIMP and O-4-PIMP were determined according to UV-VIS measurements. 相似文献
43.
R.-L. Yun Y.-M. Chang C.-H. Lin K.-H. Hu C.-M. Shu 《Journal of Thermal Analysis and Calorimetry》2006,85(1):107-113
In industrial processes, information
on the safety property of chemicals is essentially crucial for safe handling
during unit operations. Ensuring the safe use of combustible or flammable
substances in processes is unlikely without detailed investigations of their
flammability characteristics and related hazards. We studied 3-methyl pyridine
(3-picoline), e.g., flammability limits (LFL/UFL), maximum explosion pressure
(P
max), maximum
explosion pressure rise (dP/dt)max, minimum oxygen concentration
(MOC), vapor deflagration index (K
g),
and characterized the influence of inert steam (H2O)
on critical parameters for 3-picoline/water mixtures at 270°C, 1 atm,
various oxygen concentrations, and vapor mixing ratios (100/0, 30/70, 10/90
and 5/95 vol.%) with a 20-L-Apparatus in simulated conditions, respectively.
The results showed that the flammability characteristics
of 3-picoline(aq) all increased with the oxygen concentration.
However, as the composition of inert steam increased, the flammability parameters
and the degree of fire and explosion hazards were significantly reduced, instead.
This study elucidated the flammability properties of 3-picoline mixed with
inert steam. The conclusions could be applied to proactively prevent the relevant
processes from incurring fire and explosion accidents. 相似文献
44.
镓是第一个根据化学元素周期律预言并在自然界中证实的元素,是室温下电导率和热导率均为最大的液态物质,镓在电子工业中得到了广泛应用,被誉为电子工业“脊梁”。近十几年来,镓的更多应用潜力被发掘出来,在电子工业、散热、增材制造、柔性机器、生物医学等领域均有重要的应用前景。 相似文献
45.
C. DurioA. Daidouh N. ChouaibiC. Pico M.L. Veiga 《Journal of solid state chemistry》2002,168(1):208-216
New sodium orthophosphates of general formula Na2M3(PO4)3 belonging to the alluaudite-type structure have been synthesized and characterized by neutron and X-ray powder diffraction. The nature of the M3 elements (M3=GaMn2, GaCd2, InMn2 and FeMnCd) was chosen in order to analyze their influence on electrical and magnetic properties. The conductivity of these materials was measured by the complex impedance method and the transport mechanism was studied from complex permittivities and modulus formalism. Electrical results including charge/discharge experiments showed two main behaviors: GaCd2 and FeMnCd behave as purely ionic conductors whereas GaMn2 and InMn2 are mixed ionic-electronic conductors. The magnetic susceptibility data reveal the antiferromagnetic behavior of FeMnCd, InMn2 and GaMn2, with a weak ferromagnetic transition at low temperatures. 相似文献
46.
Enhancing the enzymatic hydrolysis of cellulosic materials using simultaneous ball milling 总被引:1,自引:0,他引:1
Mais Ursula Esteghlalian Ali R. Saddler John N. Mansfield Shawn D. 《Applied biochemistry and biotechnology》2002,98(1-9):815-832
One of the limiting factors restricting the effective and efficient bioconversion of softwood-derived lignocellulosic residues
is the recalcitrance of the substrate following pretreatment. Consequently, the ensuing enzymatic process requires relatively
high enzyme loadings to produce monomeric carbohydrates that are readily fermentable by ethanologenic microorganisms. In an
attempt to circumvent the need for larger enzyme loadings, a simultaneous physical and enzymatic hydrolysis treatment was
evaluated. A ball-mill reactor was used as the digestion vessel, and the extent and rate of hydrolysis were monitored. Concurrently,
enzyme adsorption profiles and the rate of conversion during the course of hydrolysis were monitored. α-Cellulose, employed
as a model substrate, and SO2-impregnated steam-exploded Douglas-fir wood chips were assessed as the cellulosic substrates. The softwood-derived substrate
was further posttreated with water and hot alkaline hydrogen peroxide to remove >90% of the original lignin. Experiments at
different reaction conditions were evaluated, including substrate concentration, enzyme loading, reaction volumes, and number
of ball beads employed during mechanical milling. It was apparent that the best conditions for the enzymatic hydrolysis of
α-cellulose were attained using a higher number of beads, while the presence of air-liquid interface did not seem to affect
the rate of saccharification. Similarly, when employing the lignocellulosic substrate, up to 100% hydrolysis could be achieved
with a minimum enzyme loading (10 filter paper units/g of cellulose), at lower substrate concentrations and with a greater
number of reaction beads during milling. It was apparent that the combined strategy of simultaneous ball milling and enzymatic
hydrolysis could improve the rate of saccharification and/or reduce the enzyme loading required to attain total hydrolysis
of the carbohydrate moieties. 相似文献
47.
48.
49.
Zixin Chang Mengsu Zhu Yong Sun Feng He Yang Li Chunhui Ye Yigang Jin Ze Li Wei Xu 《Advanced functional materials》2023,33(32):2301513
Herein, a novel D4 symmetrical redox-active ligand tetrathia[8]circulene-2,3,5,6,8,9,11,12-octaol (8OH-TTC) is designed and synthesized, which coordinates with Ni2+ ions to construct a 2D conductive metal-organic framework (2D c-MOF) named Ni-TTC. Ni-TTC exhibits typical semiconducting properties with electrical conductivity up to ≈1.0 S m−1 at 298 K. Furthermore, magnetism measurements show the paramagnetic property of Ni-TTC with strong antiferromagnetic coupling due to the presence of semiquinone ligand radicals and Ni2+ sites. In virtue of its decent electrical conductivity and good redox activity, the gravimetric capacitance of Ni-TTC is up to 249 F g−1 at a discharge rate of 0.2 A g−1, which demonstrates the potential of tetrathia[8]circulene-based redox-active 2D c-MOFs in energy storage applications. 相似文献
50.
Jianfeng Li Min Liu Kun Yang Yimei Wang Junwei Wang Zhicai Chen Kui Feng Dong Wang Jianqi Zhang Yongchun Li Han Guo Zhixiang Wei Xugang Guo 《Advanced functional materials》2023,33(23):2213911
Designing n-type polymers with high electrical conductivity remains a major challenge for organic thermoelectrics (OTEs). Herein, by devising a novel selenophene-based electron-deficient building block, the pronounced advantages of selenium substitution in simultaneously enabling advanced n-type polymers is demonstrated with high mobility (≈2 orders of magnitude higher versus their sulfur-based analogues due to both intensified intra- and inter-chain interactions) and much improved n-doping efficiency (enabled by the largely lowered LUMO level with a ≈0.2 eV margin) of the resulting polymers. Via side chain optimization and donor engineering, the selenium-substituted polymer, f-BSeI2TEG-FT, achieves a highest conductivity of 103.5 S cm−1 and power factor of 70.1 µW m−1 K−2, which are among the highest values reported in literature for n-type polymers, and f-BSeI2TEG-FT greatly outperformed the sulfur-based analogue polymer by 40% conductivity increase. These results demonstrate that selenium substitution is a very effective strategy for improving n-type performance and provide important structure-property correlations for developing high-performing n-type OTE materials. 相似文献