管理学科案例教学——实验视角

对管理学科案例教学和管理学科实验教学的现状及其发展进行了详细分析，创新地从能力培养、实务操作、综合知识的实验视角讨论了基于实验平台的管理学科案例教学，指出了管理学科案例教学与实验教学均会因此得到进一步发展。     

Assignment of phycocyanobilin in HMPT using triple resonance experiments

A complete assignment of all resonances of a small organic molecule is a prerequisite for a structure determination using NMR spectroscopy. This is conventionally obtained using a well‐established strategy based on COSY, HMQC and HMBC spectra. In case of phycocyanobilin (PCB) in HMPT this strategy was unsuccessful due to the symmetry of the molecule and extreme signal overlap. Since ¹³C and ¹⁵N labeled material was available, an alternative strategy for resonance assignment was used. Triple resonance experiments derived from experiments conventionally performed for proteins are sensitive and easy to analyze. Their application led to a complete and unambiguous assignment using three types of experiments. Copyright © 2011 John Wiley & Sons, Ltd.     

13C shielding scale for MAS NMR spectroscopy

We have performed the direct measurements of ¹³C magnetic shielding for pure liquid TMS, solution of 1% TMS in CDCl₃ and solid fullerene. The measurements were carried out in spherical ampoules exploring the relation between the resonance frequencies, shielding constants and magnetic moments of ¹³C and ³He nuclei. Next the ¹³C shielding constants of glycine, hexamethylbenzene and adamantane were established on the basis of appropriate chemical shifts measured in the solid state. All the new results are free from susceptibility effects and can be recommended as the reference standards of ¹³C shielding scale in the magic angle spinning NMR experiments. Copyright © 2011 John Wiley & Sons, Ltd.     

Research Note: Mobility of Herbicide Microcapsules in Saturated Granular Media

The mobility of the microcapsules in saturated granular media was estimated on the basis of conventional breakthrough experiments in vertical columns packed with sands for various physical and chemical conditions. Four types of microcapsules have been tested, all of them were found to have reasonable mobility in clean quartz sand, but not in sandy soil. The immobility in the sandy soil was attributed to some production deficiencies in terms of shape, size and quality of the coating surface. The size of the microcapsules should be considerably smaller than those produced with an order of magnitude of a few micrometers. They should also be more spherical and with a smoother surface. The addition of a proper dispersant had stabilized the microcapsules suspension, and facilitated their transport in the sand. A major flow factor affecting microcapsules mobility is the water flux. The microcapsules should be applied at a high irrigation rate, which also implies a high water content in the soil profile. Considering solely the mobility aspect, it seems that the prospect for successful application of the new method for weed control is limited to granular soils with a high hydraulic conductivity at/or near saturation. However, for the time being the most limiting problem is the production of quality microcapsules with good physical and chemical properties.     

均匀设计抽样的一、二阶矩

（７）中给出并研究了均匀设计抽样（ＵＤＳ）及随机化均匀设计（ＲＵＤ）的一些优良性质，作者给出该设计和抽样的一、二阶矩。     

Effect of the rare earth in the perovskite-type mixed oxides AMnO3 (A=Y, La, Pr, Sm, Dy) as catalysts in methanol oxidation

The effect of the rare earth in the perovskite-type mixed oxides AMnO₃ (A=Y, La, Pr, Sm, Dy) on catalytic properties in methanol oxidation was investigated in this work. The perovskites were prepared by reactive grinding in order to enhance the specific surface area in comparison with other classical synthesis procedures. These catalysts were characterized by N₂ adsorption, X-ray diffraction, H₂ temperature-programmed reduction (TPR-H₂), O₂-, CH₃OH- and CO₂-temperature-programmed desorption (TPD). The activity of the five catalysts under study in the methanol oxidation reaction was evaluated. The behaviour of the α-O₂ from the surface of the perovskite was strongly related to the nature of the A-site cation and particularly to its electronegativity but also to its density. Concerning the β-O₂ from the bulk, the rare earth only induces an indirect effect notably due to structural modifications. As suggested in a previous study, the activity in methanol oxidation was directly linked with the surface oxygen density. Under an excess of α-oxygen, the reaction intermediate was found to be a monodentate carbonate that decomposes into CO₂. The stability of monodentate carbonates was also found to be related to the electronegativity of the rare earth during both CH₃OH- and CO₂-temperature-programmed desorption. However, as soon as a lack of α-oxygen was observed in the structure, the dominant reaction intermediate was a bidentate carbonate that induces a consumption of anion vacancies in spite of the production of CO₂. Nevertheless, the accumulation of these carbonates leads to a decrease in the oxidation rate since their desorption requires high temperatures.     

Mortar element methods for parabolic problems

In this article a standard mortar finite element method and a mortar element method with Lagrange multiplier are used for spatial discretization of a class of parabolic initial‐boundary value problems. Optimal error estimates in L^∞(L²) and L^∞(H¹)‐norms for semidiscrete methods for both the cases are established. The key feature that we have adopted here is to introduce a modified elliptic projection. In the standard mortar element method, a completely discrete scheme using backward Euler scheme is discussed and optimal error estimates are derived. The results of numerical experiments support the theoretical results obtained in this article. © 2008 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2008     

Induced-fit recognition by p-carboxylatocalix[4]arene hosts

Calix[4]arene derivatives bearing anionic carboxylato groups at the upper rim (p-carboxylatocalix[4]arenes) are able to ‘grab’ paraquat dicationic guest through an induced-fit mechanism, which originates from the conformational mobility of calixarene skeleton.