To what extent can an uncertainty calculation be general?

 It is argued that results of uncertainty calculations in chemical analysis should be taken into consideration with some caution owing to their limited generality. The issue of the uncertainty in uncertainty estimation is discussed in two aspects. The first is due to the differences between procedure-oriented and result-oriented uncertainty assessments, and the second is due to the differences between the theoretical calculation of uncertainty and its quantication using the validation (experimental) data. It is shown that the uncertainty calculation for instrumental analytical methods using a regression calibration curve is result-oriented and meaningful only until the next calibration. A scheme for evaluation of the uncertainty in uncertainty calculation by statistical analysis of experimental data is given and illustrated with examples from the author's practice. Some recommendations for the design of corresponding experiments are formulated.     

PVC DISULFIDE AS CATHODE MATERIALS FOR SECONDARY LITHIUM BATTERIES

PVC disulfide (2SPVC) was synthesized by solution crosslink and its molecular structure was confirmed by infrared spectrum. 2SPVC's specific area is 36.1 m2·g-1 tested by stand BET method, and granularity experiment gives out the particle size of d0.5= 11.3μm. With SEM (Scanning Electron Microscope) experiment the surface morphology and particle shape of 2SPVC were observed. Cyclic voltammetry (scan rate: 0.5 mV·s-1) shows that 2SPVC experience an obvious S-S redox reaction in charge-discharge process. When 2SPVC was used as cathode material for secondary lithium battery in a 1 mol·L-1 solution of lithium bis(trifluoromethylsulfonyl) imide (Li(CF3SO2)2N) in a 5:45:50 volume ratio mixture of o-xylene (oxy), diglyme (DG) and dimethoxymethane (DME) at 30℃, the first discharge capacity of 2SPVC is about 400.3 mAh·g-1 which is very close to its theoretical value (410.5 mAh·g-1) at a constant discharge current of 15 mA·g-1. It can retain at about 346.1 mAh·g-1 of discharge capacity after 30 charge-discharge cycles. So 2SPVC is a very promising cathode candidate for rechargeable lithium batteries.     

热敏电阻温度计的设计与制作

本文介绍了设计性实验“热敏电阻的设计与制作”的实施情况。说明了只要选题合适、要求恰当,设计性实验不仅可行,而且对物理实验训练的总结提高十分有效。     

融合课程思政的“自动化综合实验”教学探索

为将思政教育融入课程教学中,培养德能兼备的自动化专业优秀人才。在《自动化综合实验》课程中,首先明确提出了教学的专业目标和思政目标,然后将教学环节分为课程介绍、选题汇报、学生实践以及项目展示和答辩环节,挖掘出丰富的思政元素并融入到课程教学的每个环节,并选取典型案例,通过思维导图法剖析了课程思政的融入策略,最后介绍了课程思政考核模式和取得的初步成效。该课程思政教学模式可以为“专业实验课程-思政教育体系”的打造提供参考。     

“虚实结合”的EDA课程设计实验教学案例

为提高学生的工程实践能力,我校EDA课程设计结合自研在线教学平台,采用案例式教学方式,锻炼和培养学生对EDA开发工具综合运用的能力和动手实践能力。EDA课程案例包括Matlab设计仿真、Modelsim仿真及D/A电路设计调试等EDA完整工程设计流程,线上实验平台提供远程硬件调试功能,学生可以随时随地通过线上实验平台对设计进行验证并与教师进行在线交流。该案例的成功实施有助于虚实结合的实践教学方法探索。     

基于工业传感器示教平台的课堂教学改革

以学生发展为中心的教学理念逐渐深入人心,目前的传感课程存在一个实际问题——学生在课堂上学到的理论知识很难转变成实践能力。为了解决这个问题,自主开发了具有知识产权的工业传感器示教平台,在课堂上创设工业教学环境,现场演示或远程直播工业级传感器的测量实验,让同学们能把理论知识用得好。通过以上创新,解决了课堂教学的真实问题,提升了学生实践能力,建设为省一流本科课程。     

纳秒脉冲激光清洗石化设备对清洗表面的影响

采用纳秒脉冲激光对石化设备普遍使用的20钢表面锈蚀层以及油污进行了激光清洗试验,通过正交实验法得到优化后的激光清洗工艺参数,在激光功率18 W,激光脉冲重复频率75kHz,扫描速度3 000mm/s的清洗工艺参数下可有效去除20钢表面的锈蚀层;在激光功率20 W,激光脉冲重复频率75 kHz,扫描速度2 250 mm/s的清洗工艺参数下可有效去除20钢表面附着的油污。分析了激光清洗前后材料表面形貌的变化,研究了激光清洗前后表面的显微硬度以及耐腐蚀性,结果表明：激光清洗可以在不改变材料的耐腐蚀性能的同时提升材料表面的显微硬度,从而达到理想的激光清洗效果。     

Tailoring of Photoluminescence Properties in All-Vacuum Deposited Perovskite via Ruddlesden–Popper Faults

Ruddlesden–Popper (RP) faults are well known in oxide perovskites, and are also observed in promising metal halide perovskites. However, the effect of RP faults on optical properties of perovskite has not been systematically investigated. In this study, it is found that RP faults are common planar faults in all-vacuum deposited CsPbBr₃-based perovskite polycrystal thin films, and the density of RP planar faults can be greatly increased by non-stoichiometric composition (Cs-rich) as well as reduced dimensionality (quasi-2D) strategies. The photoluminescence (PL) measurement reveals monotonically increasing peak intensities with higher densities of RP planar faults from Cs-rich, quasi-2D to Cs-rich & quasi-2D samples. The corresponding atomic-scale differential phase contrast maps indicate strongly confined charges within the RP planar fault network, which explains well the relationship between PL enhancement and the density of RP planar faults, and offers an alternative pathway for tailoring the optoelectronic properties of perovskite.     

提升配电自动化课程内涵的实验平台建设

配电自动化作为新工科智能电网的主要内容,在实验教学上还不满足新工科内涵要求。为加强学生在配电网方面的实践能力,提出配电自动化实验教学体系及课程教学的改革方案,基于贵州大学自主研发的实时仿真器UREP、嵌入式开发系统及PC端搭建配电网模块化半实物通用实时仿真实验平台。以馈线自动化为例,阐述平台的使用方法及步骤。提升学生理论与实践相结合的能力,达到新工科人才培养目的。     

基于组态虚拟仿真技术的水箱液位实验

为节约自动化实验设备成本,提出了基于组态虚拟仿真技术的水箱液位实验方案。采用OPC通信技术实现 Matlab与组态王的数据交换,由Matlab实现算法的分析和计算,在组态王中进行可视化的画面实时监控、操作等,并以双容水箱液位实验进行物理实物和虚拟仿真的实验对比验证。实验比较结果表明,组态虚拟仿真实验技术既能体现出控制算法的分析与计算,又能较好地监控实验对象的实时运行状态,实现了与实物物理实验的同质等效。