Synthesis and characteristics of photopolymerized benzophenone

Photopolymerization is extensively used in today's industrial field due to its advantages of rapid reaction, environmental friendly, energy saving and economical. Benzophenone is a most common photoinitiator (PI) using in photopolymerization because of its superior ability to initiate acrylate monomers. However, the intrinsic nature of initiator molecules is that they migrate out of polymer network, which limits its application, especially in the domain of food packaging materials. A polymerizable PI 4‐methylbenzophenone acrylate (MBPAc) was synthesized by a facile procedure and characterized by ¹H NMR, ¹³C NMR, and MS analyses. A systematic study of the photopolymerization kinetics of MBPAc was explored by the Real‐Time Fourier Transform Infrared Spectrometer. The results show that the final conversion and photopolymerization rate of acrylate monomers are closely related to the factors of their chemical structure, viscosity, functionality and light intensity, which means MBPAc is an efficient PI. Ultraviolet‐visible Spectrophotometer and vitro cytotoxicity measurement results indicate that the noncytotoxic MBPAc shows significantly lower migration than its analogue. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 313–320     

糖基亚苄基NaBH_3 CN-HCl选择性开环过程中乙酰基迁移现象的研究

用NaBH3CN HCl/Et2 O对 3 O 乙酰基 4,6 O 亚苄基 β D 吡喃半乳糖乙硫苷 (2 )进行还原开环 ,发现有乙酰基迁移至 2 位的产物生成 ;进一步的实验表明 ,室温条件下 ,NaBH3CN与 2的作用导致乙酰基的迁移     

Initiation of Light Pulses by a Coaxial H‐Compressed Discharge

An optimum configuration of the discharge channel of a coaxial Hcompressed discharge is determined to exclude the screening influence of an envelope on discharge radiation in the UV region of a spectrum. It is shown that the use of an Hcompressed discharge of coaxial shape makes it possible to increase the radiation yield in the UV spectrum as compared to a plane shape at the same parameters of electric power supply.     

Łukasiewicz Tribes are Absolutely Sequentially Closed Bold Algebras

We show that each sequentially continuous (with respect to the pointwise convergence) normed measure on a bold algebra of fuzzy sets (Archimedean MV-algebra) can be uniquely extended to a sequentially continuous measure on the generated ukasiewicz tribe and, in a natural way, the extension is maximal. We prove that for normed measures on ukasiewicz tribes monotone (sequential) continuity implies sequential continuity, hence the assumption of sequential continuity is not restrictive. This yields a characterization of the ukasiewicz tribes as bold algebras absolutely sequentially closed with respect to the extension of probabilities. The result generalizes the relationship between fields of sets and the generated -fields discovered by J. Novák. We introduce the category of bold algebras and sequentially continuous homomorphisms and prove that ukasiewicz tribes form an epireflective subcategory. The restriction to fields of sets yields the epireflective subcategory of -fields of sets.     

使用遗传算法进行微波非线性电路包络仿真

介绍用于分析任意调制信号激励的微波非线性电路包络仿真技术,相应给出了线性器件的伴随模型,并将该方法发展为分析多载波调制信号激励的强非线性电路。此外,本文给出了一种求解非线性谐波平衡方程组或交调波平衡方程组的非数值方法———基于十进制编码的混沌遗传算法(DCGA),融合设计了相应的交叉和变异操作,并将混沌过程引入其中以避免陷入早熟状态,可有效地产生更优解,并加速种群的收敛。最后,给出了运用这种方法的两个计算实例。     

Migration Effects in Reversible System [Fe(CN)6]3–/4– on a Microelectrode

Migration factors Y are determined for an [Fe(CN)₆]^3–/4– reversible system at a platinum microelectrode 10 m in radius by measuring anodic and cathodic limiting currents at different concentrations of the redox forms in solution, from which Y _a and Y _c are calculated. The obtained results agree with theory. The experimental error for the Y _a/Y _c ratio is smaller than for each factor taken separately.     

Diffusion Along Migrating Grain Boundaries

The paper summarizes recent experiments on diffusion at migrating grain boundaries (GBs) occurring during discontinuous reactions, like discontinuous precipitation (DP) and diffusion induced grain boundary migration. Analytical electron microscopy was used for measurements of the solute concentration across individual solute-depleted lamellae. These data combined with information on the growth velocity and the thickness of an individual lamella allowed the determination of the local values of the diffusivities of the moving reaction front of the DP cell in Al–Zn, Ni–Sn, Cu–In and Co–Al alloys. The obtained diffusivities and activation energies are very similar to the relevant parameters of stationary GBs. This allows us to conclude that there is no significant difference in the rates of diffusion along migrating and stationary GBs in the systems investigated. It is therefore believed that the diffusivity values of the moving reaction front of the DP reaction can be a source of reliable information on interfacial diffusion characteristics, especially in systems and/or at temperatures where radiotracer data are not readily available.     

Steady-State and Time-Resolved Spectroscopic Characteristics of Novel Silicon-Containing Organopolymers

The spectroscopic characteristics of novel -conjugated polymers containing four-coordinated silicon, acetylene groups and either 1,4-biphenylene or 2,7-fluorene in the main chain were investigated by steady-state and picosecond laser spectroscopy. The spectral features of absorption, fluorescence excitation spectra, fluorescence lifetime, and fluorescence polarization were explained by the existence of two kinds of inhomogeneously broadened electronic states formed in the disordered polymeric chain. The dynamics of photoinduced absorption was measured in the 400–900 nm spectral range with picosecond time resolution. The long-wavelength band with _max 710 nm was ascribed to excited-state absorption from higher-lying electronic states created in short polymeric segments with essential conformational distortion of the subunits. The short-wavelength band with _max 580 nm and a shoulder at 500 nm was interpreted as photoinduced absorption from a lower-lying state arisen in more planar, longer -conjugated segments populated via direct excitation and energy migration between disordered segments of the polymeric chain. For the fluorene-containing polymer, the smaller Stokes shift and the greater degree of fluorescence polarization are consistent with more extensive electron delocalization along the backbone.     

ISAR机动目标的平动补偿和瞬时成像研究

机动目标成像近年来受到广泛注意.本文首先讨论平动补偿,它通常可以分解为两步进行──包络对齐和自聚焦,分析表明,针对平稳目标的包络对齐方法仍然适用于机动目标,而根据相干积累原理,已有的自聚焦方法从理论上和实际上都不是最优的,我们提出适用于机动目标和平稳目标的迭代相干积累自聚焦(ICSA)算法,PGA(相位梯度算法)是ICSA算法的一个特例; 然后,本文讨论机动目标的瞬时成像,它实际上是一个瞬时谱估计问题,已有的一些瞬时成像方法只适用于散射点子回波为线性调频信号(多普勒分布为直线).针对时频分布为非直线的情况,我们提出用自适应窗短时chirplet分解方法估计信号的瞬时频率和瞬时幅度,并结合"洁净"技术,提出了快速自适应窗短时chirplet分解成像(ACDI)算法.实测数据的处理表明本文提出ICSA算法和ACDI算法是有效的.