用MnO_2离子筛吸附剂从溶液中提取锂(英文)

研究了MnO2离子筛的制备、表征及其提锂性能。通过控制低温水热合成反应条件制备了4种不同晶相的一维纳米MnO2,进一步用浸渍法制备了Li-Mn-O三元氧化物前驱体,并经酸处理后得到对Li+具有特殊选择性的离子筛。用XRD、吸附等温线、吸附动力学及pH滴定等手段对产物的晶相结构和Li+吸附性能进行了研究。结果表明,SMO-b和SMO-d离子筛的Li+平衡吸附量符合Freundlich吸附等温方程。反应物浓度对MnO2不同晶面的生长速率有不同的影响,但(NH4)2SO4对吸附容量并无提高。吸附速率方程符合一级动力学Lagergren方程。MnO2离子筛Li+的吸附量远远高于Na+。     

Ring‐opening metathesis polymerization of fatty acid derived monomers

The ring‐opening metathesis polymerization (ROMP) of fatty acid functionalized norbornenes was explored in the presence of dichloro[1,3‐bis(2,4,6‐trimethylphenyl)‐2‐imidazolidinylidene](benzylidene)bis(3‐bromopyridine)ruthenium(II) ( C3 ) at room temperature. The investigated monomers were derived from fatty acids with different chain lengths (C₆, C₈, C₁₀, C₁₂, C₁₄, C₁₆, and C₁₈) and can therefore contribute to the development of more sustainable, bio‐based polymeric materials. The polymerizations initiated by C3 proceeded in a living fashion with good initiation efficiency, and thus the synthesis of well‐defined polymers with narrow polydispersities was accomplished. All prepared polymers were fully characterized (GPC, DSC, TGA, NMR) and the results of these investigations are discussed within this contribution. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010     

基础设施共建共享与我国电信产业的发展变革

基于企业竞争理论,对电信企业竞争优势的主要来源进行分析,并指出：共建共享政策改变了传统的电信企业竞争机制和电信行业的竞争关系;随着国家电信基础设施共建共享工作的逐步推进,电信企业之间的竞争将由以通信网络建设为主的资源竞争,向以企业竞争力培育为主的核心能力竞争转变,这是我国通信行业由外延性发展向内涵型发展转变的重要标志,对我国通信行业发展具有重要的理论和实践意义。     

On stabilizing volatile product returns

As input flows of secondary raw materials show high volatility and tend to behave in a chaotic way, the identification of the main drivers of the dynamic behavior of returns plays a crucial role. Based on a stylized production-recycling system consisting of a set of nonlinear difference equations, we explicitly derive parameter constellations where the system will or will not converge to its equilibrium. Using a constant elasticity of substitution production function, the model is then extended to enable coverage of real world situations. Using waste paper as a reference raw material, we empirically estimate the parameters of the system. By using these regression results, we are able to show that the equilibrium solution is a Lyapunov unstable saddle point. This implies that the system is sensitive on initial conditions that will hence impede the predictability of product returns. Small variations of production input proportions could however stabilize the whole system.     

物联网与UHF RFID频谱资源

本文从物联网的概念出发,谈到物联网对RFID的关联,介绍了各国UHFRFID频谱资源安排情况,指出现实可供频谱资源与物联网发展需求的矛盾。分析了现行RFID空中接口频谱资源不足与频谱资源浪费的现实的矛盾,提出出路在于研究新的技术体制。     

接入型服务资源配置研究

从电信业务分类出发,提出了自己的分类方法,并基于此方法详细论述了接入型服务的定义和资源配置的过程,提出了接入型服务与资源的关系模型,也具体阐述了笔者对接入方式和资源覆盖的一些思考和观点.     

N‐glycosylation approach to glucose‐functionalized diamine and its use for protection‐free synthesis of polyurea bearing glucoside pendant

A glucose‐functionalized diamine was prepared and used as a new monomer for polyurea synthesis. The diamine was prepared by N‐glycosylation of 1,6‐hexamethylenediamine with D ‐glucose. Upon adding diisocyanates to the diamine, isocyanate reacted selectively with the amino groups, not with the hydroxyl groups of the glucose‐derived structure, to give the corresponding polyureas. The polyureas exhibited highly hydrophilic nature due to the presence of the glucose‐derived side chain. A ternary system consisting of the glucose‐functionalized diamine, piperazine, and diisocyanate gave the corresponding polyureas, where content of the glucose‐derived moiety was tunable by feed ratio between the diamine and piperazine. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

Tuning the frontier molecular orbital energy levels of n‐type conjugated copolymers by using angular‐shaped naphthalene tetracarboxylic diimides,and their use in all‐polymer solar cells with high open‐circuit voltages

An angular‐shaped naphthalene tetracarboxylic diimide (NDI) was designed and synthesized as a new building block for n‐type conjugated polymers to tune their energy levels. Three n‐type copolymers incorporating this angular‐shaped NDI as the acceptor moiety were obtained by Stille coupling reactions and had number average molecular weights of 18.7–73.0 kDa. All‐polymer bulk‐heterojunction solar cells made from blends of these polymers with poly(3‐hexylthiophene) gave a power conversion efficiency up to 0.32% and exhibited an open‐circuit voltage (V_oc) up to 0.94 V due to their relative high‐lying lowest unoccupied molecular orbital energy levels. The high V_oc of 0.94 V is higher than that of solar cells based on linear‐shaped NDI‐containing polymers (<0.6 V). The results indicate that the angular‐shaped NDI is a promising building block for constructing nonfullerene polymer acceptors for solar cells with high open‐circuit voltages. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013