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For the first time, intensification of monooleoyl glycerol (MOG) synthesis has been investigated in an ultrasonic-infrared-wave (USIRW) promoted batch reactor. Esterification of octadecanoic acid (ODA) with glycerol (Gl) has been conducted [using Amberlyst 36 wet catalyst] in three different reactors, namely traditional batch reactor (TBR), infrared wave promoted batch reactor (IRWPBR), and USIRW-promoted batch reactor (USIRWPBR) to assess the relative efficacy. The energy-efficient USIRWPBR remarkably intensifies the ODA-Gl esterification as manifested through superior ODA conversion (92.5 ± 1.25%) compared to that achieved in IRWPBR (79.8 ± 1.2%) and TBR (36.39 ± 1.25%). The most favorable reaction condition for optimum ODA conversion and maximum MOG yield was identified through statistical optimization over a selected parametric range, namely 3-5 Gl/ODA mole ratio, 0.004-0.006 g/mL Amberlyst 36 catalyst concentration, 300-700 rpm impeller speed, and 333-353 K reaction temperature. The present study also reports the formulation and validation of an innovative reaction kinetics, that is, concurrent noncatalytic and heterogeneously catalyzed (CNCHC) reaction mechanism in addition to the conventional heterogeneous kinetic models (LH and Eley-Rideal mechanisms). Under combined USIRW, the CNCHC esterification mechanism could best describe ODA-Gl esterification (R2 = 0.98) compared to LH (R2 = 0.97) and Eley-Rideal (R2 = 0.88) mechanisms. The optimal product (MOG) was characterized by differential scanning calorimetry and thermogravimetric analysis to assess its crystallization property and thermal stability for possible application as plasticizer/fuel additives. 相似文献
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大规模MIMO OFDMA下行系统能效资源分配算法 总被引:4,自引:0,他引:4
针对大规模多输入多输出(MIMO)正交频分多址(OFDMA)下行移动通信系统,提出了一种基于能效最优的资源分配算法。所提算法在采用迫零(ZF)预编码的情况下,以最大化系统能效的下界为准则,同时考虑每个用户的最低速率要求,通过调整带宽分配、功率分配和基站天线数分配来优化能效函数。首先根据优化条件提出了一种迭代算法确定每个用户的带宽分配,然后利用分数规划的性质并采用凸优化方法,通过联合调整基站端的发射天线数和用户的发射功率来优化能效函数。仿真结果表明,所提算法在较少迭代次数的同时能够取得较好的系统能效性能和吞吐量性能。 相似文献
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提出了一种分布式高效节能的无线传感器网络数据收集和路由协议HEEDC.此协议中传感器节点根据自身状态(综合考虑剩余能量、节点密度等因素计算得出的代价因子)自主的竞争簇首,同时为减少簇首节点的能量开销,簇首之间通过多跳方式将各个簇内收集到的数据发送给特定簇首节点,并由此簇首节点将整个网络收集的数据发送给汇聚节点.仿真实验表明,HEEDC协议比起现有的几种重要路由协议(如LEACH、PEGASIS等),能提供更加有效的能量使用效率,延长无线传感器网络的生存周期.因此,使用HEEDC协议的无线传感器网络具有更好的使用性,其监测结果具有更高的可靠性. 相似文献
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针对IP over WDM网络,基于多跳光旁路和流量疏导,以减少能耗为目标对网络链路配置进行设计;考虑多跳光旁路会增大业务传输距离的问题,分析了光路建立顺序对业务传输距离的影响;通过优先路由短距离业务和限制最大传输跳数来减少业务的平均传输跳数。仿真结果表明,优先建立短距离光路的启发式算法与Dijkstra算法相比可以减少25%~55%的能耗,业务平均物理跳数与Dijkstra算法相差在1跳之内。 相似文献
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Ramalingam Vinodha Sundarraj Durairaj Sakkarai Padmavathi 《International Journal of Communication Systems》2022,35(1):e5019
Due to low cost, ease of implementation and flexibility of wireless sensor networks (WSNs), WSNs are considered to be an essential technology to support the smart grid (SG) application. The prime concern is to increase the lifetime in order to find the active sensor node and thereby to find once the sensor node (SN) dies in any region. For this reason, an energy-efficient Dynamic Source Routing (DSR) protocol needs to provide the right stability region with a prolonged network lifetime. This work is an effort to extend the network's existence by finding and correcting the considerable energy leveraging behaviors of WSN. We build a comprehensive model based on real measures of SG path loss for different conditions by using the characteristics of WSN nodes and channel characteristics. This method also establishes a hierarchical network structure of balanced clusters and an energy-harvesting SN. The cluster heads (CHs) are chosen by these SN using a low overhead passive clustering strategy. The cluster formation method is focused on the use of passive clustering of the particle swarm optimization (PSO). For the sake of eliminating delayed output in the WSN, energy competent dynamic source routing protocol (EC-DSR) is used. Chicken swarm optimization (CSO) in which optimum cluster path calculation shall be done where distance and residual energy should be regarded as limitation. Finally, the results are carried out with regard to the packet distribution ratio, throughput, overhead management, and average end-to-end delay to demonstrate the efficiency of the proposed system. 相似文献