掺杂对碳纳米管拉曼光谱及场发射性能的影响

采用高温热解法在860℃分别制备出了镓、氮以及硼和氮掺杂的碳纳米管,提纯后利用丝网印刷工艺分别将它们制备成薄膜,并测试了它们的拉曼光谱与场发射性能。测试结果表明,掺杂纳米管的缺陷密集度比纯碳纳米管明显增大,而它们的场致电子发射性能则与掺杂元素的性质密切相关。镓和氮掺杂的纳米管均具有非常优异的场发射性能,而硼和氮共掺杂的纳米管的场发射性能很差。掺杂引起碳纳米管费米能级附近能态密度的变化及功函数的降低是其具有优异场致电子发射性能的主要原因。     

纳米晶ZrO2:Er3+-Yb3+的制备及其室温上转换发射

用化学共沉淀法制备了ZrO₂:Er³⁺-Yb³⁺纳米晶粉体，所制备的纳米晶粉体具有较强的室温上转换发射和红外发射.研究了样品的晶体结构和上转换发光性质随着Yb³⁺掺杂浓度和煅烧温度的变化关系.通过X射线衍射谱分析发现，经800℃煅烧2h后得到的ZrO₂:Er³⁺-Yb³⁺纳米晶是四方相和单斜相的混合结构，经950℃煅烧2h后得到的样品以单斜相为主，随着Y     

掺杂Er^3＋的TiO2的发射光谱研究

用无水乙醇、冰醋酸、钛酸丁酯凝胶法制备了掺杂Er^3＋的TiO2粉末，测量了其在488m激发下的Stokes发射光谱和980nm激发下的上转换发光光谱。在可见光范围内，观察到了绿光和红光，绿光从500-570nm，对应Er^3＋的^2H11/2,^4S3／2→^4I15/2，红光从650～690m，对应Er^3＋的^4F9／2→^4I15／2的跃迁。由ln Ivis-In Iin曲线可知，绿光和红光均为双光子过程，光强正比于泵浦功率的二次方，即Iout ∝Iin。初步研究了此材料的上转换过程。     

彩色等离子体显示器的新进展

扼要地介绍了近年来世界上各大公司对彩色PDP的结构和驱动方法的改进 ,将现今彩色PDP的亮度、对比度和色纯度等主要性能与过去相比 ,得到明显的改善 ,达到了与高清晰度CRT相当的性能。     

低速高电荷态离子40Ar16+与云母表面作用中的电子发射研究

报道了由兰州ECR源提供的低速高电荷离子40Ar16 入射到云母表面产生的电子发射的实验测量结果.结果发现,电子发射产额Y与离子入射角ψ有近似1/tanψ的关系.基于经典过垒模型,我们对这一关系进行了理论分析.实验结果和理论结果相当符合,这就间接说明势能电子发射是低速高电荷态离子作用于表面发射电子的一个主要途径.     

迅速发展的有机电致发光(OEL)显示器件

有机电致发光显示器件以其全固体、自发光、宽视角、高对比、快响应、低功耗、更轻薄等比液晶显示器件更为优越的特性 ,在小尺寸平板显示市场上正开始向 LCD挑战     

掺染料激光介质的研究

以PMMA为基质，在助溶剂的作用下掺杂激光染料Rh6G制备出了塑料激光介质样品，采用YAG激光器作为泵浦源测试了塑料激光介质的发射光谱，讨论了其激光发射机理。     

二维光子晶体中极化原子自发辐射的开关效应

利用二维光子晶体的各向异性，结合原子的偶极辐射能量分布特点，提出通过改变原子的极化方向，可以使其自发辐射寿命显著地缩短或者延长，实现开关控制．发现在某些空间位置上，极化原子寿命的改变可高达33倍．     

Holographic interferometry as electrochemical emission spectroscopy of a carbon steel in 5–20 ppm TROS C-70 inhibited seawater

In the present investigation, holographic interferometry was utilized for the first time to determine the rate change of the number of the fringe evolutions during the corrosion test of a carbon steel in blank seawater and seawater with different concentrations of a corrosion inhibitor. In other words, the anodic dissolution behaviors (corrosion) of the carbon steel were determined simultaneously by holographic interferometry, as an electromagnetic method, and by the electrochemical impedance (EI) spectroscopy, as an electronic method. So, the abrupt rate change of the number of the fringe evolutions during corrosion tests, EI spectroscopy, of the carbon steel is called electrochemical emission spectroscopy. The corrosion process of the steel samples was carried out in blank seawater and seawater with different concentrations, 5–20 ppm, of TROS C-70 corrosion inhibitor using the EI spectroscopy method, at room temperature. The electrochemical-emission spectra of the carbon steel in different solutions represent a detailed picture of the rate change of the anodic dissolution of the steel throughout the corrosion processes. Furthermore, the optical interferometry data of the carbon steel were compared to the data, which was obtained from the EI. spectroscopy. Consequently, holographic interferometry is found very useful for monitoring the anodic dissolution behaviors of metals, in which the number of the fringe evolutions of the steel samples can be determined in situ.     

Spectroscopy of the regenerative soot

The mechanisms and processes of the formation of the regenerative soot in a graphite hollow cathode discharge that produces and emits carbon clusters are presented. Mass spectrometry with a specially designed E×B velocity filter analyzes the entire range of the charged clusters from C ₁ to ∼C ₄₃₀₀. The state of the carbon vapour within the source is evaluated by using the characteristic line emissions from the carbonaceous discharge whose formative mechanisms depend upon the kinetic and potential sputtering of the sooted cathode. The carbonaceous discharge generates atomic and ionic C and its clusters C _m (m≥ 2), noble gas metastable atoms and ions, energetic electrons and photons in the cavity of the graphite hollow cathode. The parameters of soot formation and its recycling depend critically on the discharge parameters, the geometry of the hollow cathode and 3D profile of the cusp magnetic field contours. Received 2nd July 2001 and Received in final form 10 September 2001