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61.
62.
《合成通讯》2012,42(24):3536-3545
AbstractA novel two-step amine persulfonylation method described here results in significantly higher yields of sulfonimide-based dendrimers as compared with formerly available procedures. This allowed the preparation of the fifth-generation sulfonimide-based dendrimer for the first time, on a 2?g scale. Dendrimers of fourth and fifth generations decorated with naphthyl groups after being spin-coated on a glass substrate were shown to form stable hydrophobic films as revealed by contact angle measurements. 相似文献
63.
毫米波雷达的安装角度校准是雷达正常使用并与摄像头进行数据融合的重要前提,雷达安装角度偏
转过大会导致雷达数据与摄像头数据融合失败,影响高级驾驶辅助系统(Advanced Driving Assistance System,ADAS)
的正常使用。文中提出一种基于曲线拟合的毫米波雷达安装角度校准方法,当车辆在道路上行驶时辅以车辆输入
的车速和偏航角信息,通过2000 个静止点进行曲线拟合得到雷达需要补偿的角度。相较于选择有护栏的道路进行
绕行和在标定场地部署角反射器进行安装角度校准的方法,这种方法适用的场景种类更多并且校准时间从15 分钟
以上缩短为5 分钟以下。经过实验验证,在花费更短时间完成校准后,校准精度与其它自校准方法相同为±5°。 相似文献
64.
65.
Kamil Wojciechowski Anna Brzozowska Sebastien Cap Witold Rzodkiewicz Thomas Gutberlet 《Applied Surface Science》2009,256(1):274-279
Adsorption of two alkylated N,N′-diaza-18-crown-6 ethers (decyl- and hexadecyl-derivatives, ACE-10 and ACE-16, respectively) on solid surfaces was studied by using contact angle and neutron reflectivity measurements. The solid substrates used were (a) Si covered with a native oxide layer (Si/SiO2) and (b) Si with sputtered Pt layer (Si/Pt). The sensitivity of neutron reflectivity was drastically improved by applying the intermediate Pt layer of 150 Å, which gave rise to several Kiessig fringes in the experimentally accessible q-range. The position of the fringes is very sensitive to slight changes of the interfacial composition induced by adsorption of a thin monolayer, otherwise very difficult to detect. Unfortunately, in the studied case this sensitivity is immediately lost due to undesired adsorption of a protonated material on the Pt surface exposed to the lab air. A decrease of surface energy (increase of contact angle) of both Si/SiO2 and Si/Pt upon exposure to toluene solutions of ACEs suggests that the latter are attached to the surface via the hydrophilic azacrown ether head with alkyl chains standing upright towards the liquid phase. 相似文献
66.
为完成极化合成孔径雷达(PolSAR)图像中点散射像素目标的检测,从几何扰动滤波检测点散射像素的基本原理出发,分析了经典方法存在的相干度参数阈值无法自适应获取和不同散射机制共享同一阈值两个问题,提出利用Cloude-Pottier分解结果中熵参数的分布情况计算得到阈值,利用平均阿尔法角参数完成不同散射机制的初分类,对初分类的结果排序得到的某种散射机制对应的相干度参数的比例因子,根据比例因子计算得到该类散射机制的阈值,从而完成点散射目标的检测。对机载合成孔径雷达(AIRSAR)数据集中的San Francisco Bay图像进行了实验,结果表明,改进方法在检测性能上优于经典方法。 相似文献
67.
为了研究三种不同散射相函数下紫外光大气传输特性,文章采用非直视紫外光通信的单次散射简化模型,对系统接收机接收到的能量及紫外光传输路径损耗随传输距离和散射角的变化情况进行分析.结果表明:三种相函数下,都表现为随传输距离的增大,接收能量减小,路径损耗增大,但三者之间存在一定的差异,对于紫外光通信系统,其传输性能的影响以前向散射为主,后向散射作用很小;随着散射角增大,后向散射作用相对明显;三种散射相函数下,紫外光通信链路的最佳散射角不同,但均随发射仰角的增大或接收仰角的增大最佳散射角增大,而接收能量减小. 相似文献
68.
69.
Wei Chang Lijuan Liu Jin Zhang Qiwei Pan 《Journal of Dispersion Science and Technology》2013,34(5):639-642
A kind of emulsifier-free latex (FL) was successfully synthesized from styrene (St) and butyl acrylate (BA) with 2-acrylamido-2-methyl propane sulfonic acid (AMPS) as a reactive emulsifier. The particle size of latex particles, stability against electrolytes, minimum film forming temperature (MFT) and water contact angle (CA) were evaluated and compared with a conventional latex (CL). Test results show that FL has larger particle size, better stability against electrolytes and lower MFT value compared with CL; higher AMPS content leads to smaller particle size and smaller water CA. 相似文献
70.
Lignocellulosic fibers extracted from sugarcane bagasse were treated with NaOH solutions of different concentration (0-40 wt%) to study the effect of alkali treatment on the composition, structure and properties of the fibers. Composition was determined by the van Soest method, structure was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), while mechanical properties by tensile testing. Hemicellulose and lignin content decrease, while cellulose content goes through a maximum as a function of alkali concentration. Crystallinity changes only slightly and microfibril angle (MFA) remains constant thus structural effects and especially MFA are not the primary reasons for changing properties. The Young's modulus of the fibers shows a slight maximum at around 2-4 wt% NaOH content, while tensile strength goes through a much more pronounced one at around 5-8 wt%. Direct correlation between structure and mechanical properties was not found indicating that composition is more important in the determination of properties than structure. Regression analysis proved that the combination of several compositional variables determines mechanical properties in a non-linear manner. The improvement in fiber properties was explained with the dissolution of weak amorphous fractions and the relative increase of cellulose content. 相似文献