隔膜对双电层电容器和混合型电池-超级电容器的电化学性能的影响

隔膜是双电层电容器和混合型电池-超级电容器等电化学储能器件的重要组成元件.本文采用1 mol?L-1四乙基四氟硼酸铵的丙烯碳酸酯电解液制备了基于活性炭的扣式双电层电容器,并采用1 mol?L-1六氟磷酸锂锂离子电解液制备了(LiNi0.5Co0.2Mn0.3O2+活性炭)/石墨体系的混合型电池-超级电容器.研究了不同类型隔膜的物理化学性能,以及其对双电层电容器和混合型电池-超级电容器的电化学性能的影响.四种隔膜分别是无纺布聚丙烯毡、多孔聚丙烯薄膜、Al2O3涂层的聚丙烯薄膜和纤维素纸隔膜.进行了表面形貌、差示扫描量热、电解液吸液量和表观接触角测试表征.电化学测试表明,采用纤维素隔膜的双电层电容器具有最高的比电容和更优的倍率性能,电容器的自放电性能差别不大.而对于混合型电池-超级电容器,采用聚丙烯薄膜和无纺布聚丙烯毡隔膜器件的比容量比其它器件约高20%,且采用纤维素隔膜的器件自放电率最高.     

Dynamic and Quantitative Control of the DNA‐Mediated Growth of Gold Plasmonic Nanostructures

Reproducible and controllable growth of nanostructures with well‐defined physical and chemical properties is a longstanding problem in nanoscience. A key step to address this issue is to understand their underlying growth mechanism, which is often entangled in the complexity of growth environments and obscured by rapid reaction speeds. Herein, we demonstrate that the evolution of size, surface morphology, and the optical properties of gold plasmonic nanostructures could be quantitatively intercepted by dynamic and stoichiometric control of the DNA‐mediated growth. By combining synchrotron‐based small‐angle X‐ray scattering (SAXS) with transmission electron microscopy (TEM), we reliably obtained quantitative structural parameters for these fine nanostructures that correlate well with their optical properties as identified by UV/Vis absorption and dark‐field scattering spectroscopy. Through this comprehensive study, we report a growth mechanism for gold plasmonic nanostructures, and the first semiquantitative revelation of the remarkable interplay between their morphology and unique plasmonic properties.     

Alkali treatment of lignocellulosic fibers extracted from sugarcane bagasse: Composition,structure, properties

Lignocellulosic fibers extracted from sugarcane bagasse were treated with NaOH solutions of different concentration (0-40 wt%) to study the effect of alkali treatment on the composition, structure and properties of the fibers. Composition was determined by the van Soest method, structure was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), while mechanical properties by tensile testing. Hemicellulose and lignin content decrease, while cellulose content goes through a maximum as a function of alkali concentration. Crystallinity changes only slightly and microfibril angle (MFA) remains constant thus structural effects and especially MFA are not the primary reasons for changing properties. The Young's modulus of the fibers shows a slight maximum at around 2-4 wt% NaOH content, while tensile strength goes through a much more pronounced one at around 5-8 wt%. Direct correlation between structure and mechanical properties was not found indicating that composition is more important in the determination of properties than structure. Regression analysis proved that the combination of several compositional variables determines mechanical properties in a non-linear manner. The improvement in fiber properties was explained with the dissolution of weak amorphous fractions and the relative increase of cellulose content.     

立体角在结构化学中的应用

The concept of solid angle is used to explain the necessary and sufficient conditions for a three-dimensional gapless structure to be achieved by combining one or several polyhedrons. In this paper, the solid angle and dihedral angle of the common regular polyhedron and the common Archimedean semi regular polyhedron are presented, and the examples of structural chemistry are analyzed. In space, the sum of solid angles must be equal to 4π(sr), so by simply adding, we can judge the possibility of gapless accumulation, know the common situation of each point, and then deduce the space structure. By using this method, we can predict some structures that do not exist yet.     

Synthesis of two A-B-C type conjugated amphiphilic triblock fullerene derivatives and their application in organic solar cells

Two A-B-C type conjugated amphiphilic triblock fullerene derivatives C60-2 HMTPB and C60-2 EHTPB were obtained in multi steps synthesis with three different blocks,and the amphiphilic diblock molecular C60-4 TPB was also preferred as a reference.When as modifying layer on zinc oxide(ZnO),the three fullerene derivatives can all reduce the work function of ZnO via modulation of the interfacial dipoles and lead a better electrical coupling.As introducing treatment of toluene,the obvious self-assembly of fullerene derivatives were observed,which were supported by X-ray diffraction and contact angle of water measurement.Base on PTB7-Th:PC71 BM system,the inverted organic solar cells devices with structure of ITO/ZnO/fullerene derivatives/PTB7-Th:PC71BM/Mo03/Al got power conversion efficiencies of 8.62%,8.83%and 9.00%for C60-4 TPB,C60-2 HMTPB and C60-2 EHTPB,respectively,compared 8.13%of devices with bare ZnO.The result of conjugated amphiphilic triblock fullerene derivatives provides a straightforward approaching by simultaneously modulating the morphology and interfacial work function of ZnO,which can also lead high performance in optoelectronic devices.     

Theoretical Studies on Dihedral Angle-Bending Isomers of M2Pt20/-Clusters

The structures and electronic properties of the gaseous M\begin{document}$ _2 $\end{document}Pt\begin{document}$ _2 $\end{document}\begin{document}$ ^{0/-} $\end{document} clusters (M represents the alkaline earth metal) were investigated using the density functional theory (B3LYP and PBE0) and wave function theory (SCS-MP2, CCSD and CCSD (T)). The results indicate that the D\begin{document}$ _{2{h}} $\end{document} isomers with the planar structures are more stable than the C\begin{document}$ _{2v} $\end{document} isomers with smaller dihedral angles and shorter Pt-Pt bond lengths. The mutual competition of M(s, p)-Pt(5d) interaction and Pt-Pt covalent bonding contributes to the different stabilizations of the two kinds of isomers. The M(s, p)-Pt(5d) interaction favors the planar isomers with D\begin{document}$ _{2h} $\end{document} symmetry, while the Pt-Pt covalent bonding leads to the C\begin{document}$ _{2v} $\end{document} isomers with bending structures. Two different crossing points are determined in the potential energy curves of Be\begin{document}$ _2 $\end{document}Pt\begin{document}$ _2 $\end{document} with the singlet and triplet states. But there is just one crossing point in potential energy curves of Ra\begin{document}$ _2 $\end{document}Pt\begin{document}$ _2 $\end{document} and Ca\begin{document}$ _2 $\end{document}Pt\begin{document}$ _2 $\end{document}\begin{document}$ ^- $\end{document} because of flatter potential energy curves of Ra\begin{document}$ _2 $\end{document}Pt\begin{document}$ _2 $\end{document} with the triplet state or Ca\begin{document}$ _2 $\end{document}Pt\begin{document}$ _2 $\end{document}\begin{document}$ ^- $\end{document} with quartet state. The results reveal a unique example of dihedral angle-bending isomers with the smallest number of atoms and may help the understanding of the bonding properties of other potential angle-bending isomers.     

数字角位移传感器在航空发动机系统中的应用研究

根据某型发动机角位移传感器的工作原理,设计了一种数字角位移传感器,分析了其静态和动态特性。该传感器以角位移传感器和CMOS低频锁相环电路为核心,用于航空发动机控制系统中角位移测量。实验表明,该传感器相位移动小,干扰噪声抑制能力强,响应速度较快;测量精度可达±0.01°,可以及时有效地对角位移进行跟踪测量。     

宽带单脉冲跟踪雷达的最大熵测角新方法

为抑制单脉冲雷达的测角闪烁,本文提出宽带单脉冲跟踪雷达的最大熵测角新方法.文中分析了由于差波束方向图调制引起的回波谱展宽现象,证明了目标角运动中心与谱展宽程度和波形熵之间的关系,提出基于最大波形熵搜索的目标角度估计方法,并给出了改进的最大熵测角步骤以降低计算量.与现有的高分辨体制下的角度估计方法相比,本方法具有更强的角闪烁抑制能力.仿真结果说明了本方法的有效性.     

双向分束角对称的偏光分束镜设计与性能分析

为了获得分束角对称的偏光分束棱镜,在双Wollaston棱镜结构的基础上,通过合理设计棱镜左右两端晶体光轴的取向,使棱镜整体呈中心切面对称;在保证对正向入射的光对称分束的同时,对反向入射光同样可以对称分束,达到了双向对称分束的目的;在此基础上给出了晶体光轴的旋转角δ与棱镜结构角S以及与波长的关系;并分析了对633 nm设计的棱镜用于其他波长时分束角的对称性.结果表明：在±300 nm的光谱范围内,分束角的不对称度均小于0.24°.