严重遮挡非视距环境下的三维定位方法

在严重遮挡非视距环境中,由于定位源与未知节点之间被障碍物遮挡而无法检测直射路径,极大地制约了无线定位方法的应用。提出一种能够规避直射路径遮挡现象的三维定位框架,利用单次反射路径和方位信息,论证了定位源、未知节点和散射体的三维空间位置关系,提出了基于最小二乘准则的空间位置优化算法,并推导出空间位置的求解方法。同时对定位算法进行均方根误差（RMSE, root mean-square error）的理论分析。通过蒙特卡罗仿真实验分析了三维定位框架中距离和方位偏差对算法性能的影响,仿真结果与算法的RMSE理论结果相符,说明了三维非视距定位算法的有效性。     

基于代价策略的H.264/AVC半脆弱水印算法

In order to solve some existing problems on detecting malicious tampering by video watermarking based on H.264/AVC video compression standard,a semi-fragile video watermarking algorithm for H.264/AVC based on cost strategy was proposed.To further improve the robustness of the feature codes in semi-fragile video watermarking algorithm,a new generation algorithm for feature codes by eliminating the correlation of them was proposed.In order to meet the requirement that the semi-fragile watermarks should be uniformly embedded into the video frames to locate the tampered region accurately,a minimal cost function was introduced to select a DCT coefficient in the 4 × 4 block residual to embed watermark which had minimal impact on the video quality and bit rates.Experimental results show that the proposed algorithm can significantly reduce impact on video quality and bit rate because of embedding the watermarking by adopting the minimum cost function and it is sensitive to malicious manipulations.The retrieved feature code and watermarking can detect and locate malicious manipulations.     

一维磁流体掺杂光子晶体缺陷模的磁控可调特性

磁流体的有效介电常数 与磁性粒子体积分数P和外加磁场因子 有关。本文首先计算了水基MnFe2O4磁流体的有效折射率随纳米磁性粒子体积分数P和外加磁场强度因子 的变化关系,发现通过调节外加磁场因子 的大小可实现不同纳米磁性粒子体积分数P的磁流体具有相同的有效折射率。然后,应用传输矩阵法,数值模拟了水基MnFe2O4磁流体中的纳米磁性粒子体积分数P=0.745时结构为(AB)8C(BA)8的一维磁流体掺杂光子晶体的透射谱。结果表明：缺陷模随着磁流体有效折射率nc的增大出现红移现象,即缺陷模中心波长随着随有效折射率nc的增大而变长,最大改变量为36.6nm。最后讨论了缺陷模品质因子 ,发现缺陷模半峰值带宽 不变,缺陷模品质因子 与缺陷模波长 随磁流体有效折射率nc的变化具有相同的线性变化特性,即品质因子 随有效折射率nc的增大而增大。     

向列相液晶弹性各向异性诱导液晶盒产生漏光的研究

为了阐述具有体缺陷结构的向列相液晶盒在暗态出现漏光的原因,以及边界锚定条件对漏光的影响,首先,建立了3个向列相液晶盒模型,它们具有不同的初始指向矢排布。接着,基于Landau-de Gennes理论,通过对指向矢场的缺陷动力学计算,得到液晶盒截面内平衡态的指向矢分布。最后,使用琼斯矩阵法将该截面内的指向矢分布以透过率的形式表示出来。模拟结果显示,在无外场条件下,当向列相液晶的弹性常数满足L2/L1≥1(K22/K11≤2/3)时,具有体缺陷结构的液晶盒展现出了自发的扭曲结构,导致了漏光的出现。且漏光强度随着缺陷结构和边界条件的不同而不同。本文模型很好地解释了体缺陷造成液晶盒在暗态出现漏光的原因,且模拟结果与工业生产过程中观察到的现象是一致的。     

基于最小均方误差选择参考节点的RSS测距定位算法

无线传感网中的多类应用均需要准确的定位算法.为了降低定位成本,减少能量消耗,常采用基于接收信号强度RSS(Received Signal Strength)测距,并建立相应的方程,再利用线性最小二乘LLS(Linear Least Squares)法求解节点的位置,将此定位算法记为RSS+LLS算法.RSS+LLS算法随机选择参考节点,这有损定位精度,同时,LLS算法并没有考虑每个测距值的误差,这些不足降低算法的定位性能.为此,提出基于RSS+LLS的优化算法,记为RSS+WLS+OPT算法.该算法先通过RSS测距,并基于最小均方误差原则选择参考节点,从而提高定位精度,同时,给每个测距值引入权重系数,采用基于协方差矩阵的加权最小二乘法WLS(Weighted Least Squares)求解节点位置,进而降低了测量误差对定位精度的影响.仿真结果表明,与RSS+ LLS相比,提出的RSS+WLS+OPT算法的定位精度提高了约2米,并没有增加计算时间,降低对测距误差的敏感性.     

Synthesis,Electrical, Electronic and Charge Transport Properties of Poly(aniline‐co‐p‐toluidine)

Copolymers of aniline with p‐toluidine were synthesized for different molar ratios of the respective monomers in acid medium. The electrical conductivity, charge transport and spectral characteristics upon incorporation of p‐toluidine units into the polyaniline backbone were investigated. The electrical conductivity of the copolymers showed frequency dependence which became more prominent with an increase in the number of p‐toluidine units in the polyaniline backbone. A direct relationship between the frequency dependence and electron localization was observed in the copolymers. Electronic spectra showed blue shifts in the π→π*and benzenoid→quinoid transitions revealing a decrease in the extent of conjugation in the copolymers. The protonated forms of the copolymers were soluble in DMSO giving polaron band around 400 nm. The decrease in electrical conductivity was attributed to the greater electron localizations as revealed from the broader ESR signals. Temperature dependence of electrical conductivity showed that charge transport was mainly through variable range hopping though a mixed conduction behavior was observed at higher temperature range.     

无机固体材料中的忆阻效应

缺陷调控是固体化学中的基本问题,也是决定材料性能的核心要素。基于缺陷调控的忆阻效应将给未来电子信息领域带来全新的变革。本文综述了无机固体材料中忆阻效应的研究进展,主要总结了忆阻效应的产生机制和忆阻材料的类型,结合原子级p-n结的相关工作,提出深入明确电场下缺陷迁移机制将是从无机固体化学角度研究忆阻效应的重要方向。     

Effect of metal cations [Li+, Na+, K+, Be2+, Mg2+, and Ca2+] on the structure of 2‐(3′‐hydroxy‐2′‐pyridyl)benzoxazole: A theoretical investigation

Density functional theory calculations were performed at the B3LYP/6‐311++G(d,p) level to systematically explore the geometrical multiplicity and binding strength for the complexes formed by alkaline and alkaline earth metal cations, viz. Li⁺, Na⁺, K⁺, Be²⁺, Mg²⁺, and Ca²⁺ (Mⁿ⁺, hereinafter), with 2‐(3′‐hydroxy‐2′‐pyridyl)benzoxazole. A total of 60 initial structures were designed and optimized, of which 51 optimized structures were found, which could be divided into two different types: monodentate complexes and bidentate complexes. In the cation‐heteroatom complex, bidentate binding is generally stronger than monodentate binding, and of which the bidentate binding with five‐membered ring structure has the strongest interaction. Energy decomposition revealed that the total binding energies mainly come from electrostatic interaction for alkaline metal ion complexes and orbital interaction energy for alkaline earth metal ion complex. In addition, the electron localization function analysis show that only the Be? O and Be? N bond are covalent character, and others are ionic character. © 2012 Wiley Periodicals, Inc.     

纳米孔缺陷导致单层黑磷电荷局域极大抑制非辐射电子-空穴复合的时域模拟

通常认为缺陷加速黑磷的非辐射电子-空穴复合,阻碍器件性能的持续提高。实验打破了这一认识。采用含时密度泛函理论结合非绝热分子动力学,我们发现P-P伸缩振动驱动非辐射电子-空穴复合,使纳米孔修饰的单层黑磷的激发态寿命比完美体系延长了约5.5倍。这主要归因于三个因素。一,纳米孔结构不但没有在禁带中引入深能级缺陷,而且由于价带顶下移使带隙增加了0.22 eV。二,除了带隙增加,纳米孔减小了电子和空穴波函数重叠,并抑制了原子核热运动,从而使非绝热耦合降低至完美体系的约1/2。三,退相干时间比完美体系延长了1.5倍。前两个因素战胜了第三个因素,使纳米孔结构激发态寿命延长至2.74 ns,而其在完美体系中约为480 ps。我们的研究表明可以制造合理数量和形貌的缺陷,如纳米孔,降低黑磷非辐射电子-空穴复合,提高光电器件效率。这一研究对于理解和调控黑磷和其它二维材料的激发态性质有重要意义。