Visible Light-Driven Alkyne-Grafted Ethylene-Bridged Azobenzene Chromophores for Photothermal Utilization

Molecular photoswitches are considered to be important candidates in the field of solar energy storage due to their sensitive and reversible bidirectional optical response. Nevertheless, it is still a daunting challenge to design a molecular photoswitch to improve the low solar spectrum utilization and quantum yields while achieving charging and discharging of heat without solvent assistance. Herein, a series of visible-light-driven ethylene-bridged azobenzene (b-Azo) chromophores with different alkyne substituents which can undergo isomerization reactions promoted in both directions by visible light are reported. Their visible light responsiveness improves their solar spectrum utilization while also having high quantum yields. In addition, as the compounds are liquids, there is no need to dissolve the compounds in order to exploit this switching. The photoisomerization of b-Azo can be adjusted by alkyne-related substituents, and hexyne-substituted b-Azo is able to store and release photothermal energy with a high density of 106.1 J·g⁻¹, and can achieve a temperature increase of 1.8 °C at a low temperature of −1 °C.     

Joint Optimization of Control Strategy and Energy Consumption for Energy Harvesting WSAN

With the rapid development of wireless sensor technology, recent progress in wireless sensor and actuator networks (WSANs) with energy harvesting provide the possibility for various real-time applications. Meanwhile, extensive research activities are carried out in the fields of efficient energy allocation and control strategy design. However, the joint design considering physical plant control, energy harvesting, and consumption is rarely concerned in existing works. In this paper, in order to enhance system control stability and promote quality of service for the WSAN energy efficiency, a novel three-step joint optimization algorithm is proposed through control strategy and energy management analysis. First, the optimal sampling interval can be obtained based on energy harvesting, consumption, and remaining conditions. Then, the control gain for each sampling interval is derived by using a backward iteration. Finally, the optimal control strategy is determined as a linear function of the current plant states and previous control strategies. The application of UAV formation flight system demonstrates that better system performance and control stability can be achieved by the proposed joint optimization design for all poor, sufficient, and general energy harvesting scenarios.     

Optimal Energy-Storage Configuration for Microgrids Based on SOH Estimation and Deep Q-Network

Energy storage is an important adjustment method to improve the economy and reliability of a power system. Due to the complexity of the coupling relationship of elements such as the power source, load, and energy storage in the microgrid, there are problems of insufficient performance in terms of economic operation and efficient dispatching. In view of this, this paper proposes an energy storage configuration optimization model based on reinforcement learning and battery state of health assessment. Firstly, a quantitative assessment of battery health life loss based on deep learning was performed. Secondly, on the basis of considering comprehensive energy complementarity, a two-layer optimal configuration model was designed to optimize the capacity configuration and dispatch operation. Finally, the feasibility of the proposed method in microgrid energy storage planning and operation was verified by experimentation. By integrating reinforcement learning and traditional optimization methods, the proposed method did not rely on the accurate prediction of the power supply and load and can make decisions based only on the real-time information of the microgrid. In this paper, the advantages and disadvantages of the proposed method and existing methods were analyzed, and the results show that the proposed method can effectively improve the performance of dynamic planning for energy storage in microgrids.     

基于LSDANet的手机芯片屏蔽壳表面缺陷检测方法

为了解决手机芯片屏蔽壳表面白印缺陷微小、尺度各异等因素影响检测快速性和准确性的问题,本文提出一种基于长短连接通路和双注意力网络(long short link and double attention network, LSDANet)的手机芯片屏蔽壳表面缺陷检测方法。首先,通过构建基于编码和解码的语义分割模型和利用长短距离连接通路,提高网络模型对尺度各异缺陷的特征提取能力。其次,分别设计基于通道和空间的注意力机制,增大5—10 pixel尺寸的白印缺陷在空间和通道上的特征权重。最后,融合双注意力机制和长短距离连接通路分割模型,构建LSDANet缺陷检测网络,应用于手机芯片屏蔽壳表面缺陷检测。实验数据表明,LSDANet网络能够达到96.21%的平均像素精度、66.13%的平均交并比和39.03的每秒检测帧数,相比多种语义分割算法均具有更高的检测精度和速度。     

基于改进VGG网络的单体热电池X光图像无损检测方法研究

为解决单体热电池生产中出现的安装错误、人工检测耗时耗力的问题,提出一个结合迁移学习和卷积 神 经网络(convolutional neural network,CNN) 的单体热电池缺陷检测模型。首先,对数据集图像进行裁剪、加噪等预处理,以VGG16(visual geometry group 16) 网络作为 模型的骨干架构,在瓶颈层后增添选择性核(selective kernel,SK) 卷积;然后,增添全局平均池化(global average pooling,GAP) 层, 增加Dropout层及添加 L2 正则化等微调操作,得到单体热电池缺陷检测模型Q-VGGNet;最后,在大型公开数据集ImageNet上进 行预训练学习,将获得的权重参数迁移到单体热电池图像识别模型Q-VGGNet上。测试实验表明:6种 网络模型对数据集缺陷图像的总体识别准确率分别达到了98.39%、94.44%、97.27%、96.34%、93.71%、 95.61%,Q-VGGNet网 络模型 对合格图像和 漏装负极、极耳断裂、漏装集流片3种缺陷图像 识别准确率 分别达到了99.6%,95.9%,99.6%和98.4%。检测结果表明:该方法能够更准确、快速地检测热电池缺陷, 拥有良好的缺陷诊断能力,较传统方法提高近3%,为人工检测单体热电池缺陷提供了良好的解决途径。     

基于双通道注意力的轻量化PCB缺陷检测研究

印刷电路板 (printed circuit board,PCB)在实际生产过程中存在缺陷样式多种多样、缺陷小、缺陷位置难以定位的问题,而一个巨大的模型难以实现实时检测的要求,且大量的深度可分离卷积层建立的轻量级模型也不能达到足够的精度,为此提出一种基于YOLOv5s的PCB缺陷检测算法。 将原始Backbone的Conv模块跟C3模块用GhostConv替换,在Neck部分则引入了一种新的轻量级卷积技术GSConv,减轻模型大小的同时保持精度,GSConv在模型的准确性和速度之间完成了一个极好的权衡,针对许多注意力模块无法关注全局信息同时模型大的问题,提出了多尺度的轻量化双通道注意力模块(double channel depthwise attention module,DWAM),进一步提高模型精度。通过多组实验, 结果表明,改进算法所有类别的平均mAP为99.14%,且模型的GFLOPs为7.194 G,Params为7.175,原始的YOLOv5s平均mAP为96.86%,GFLOPs为6.89 G,Params为6.596,虽然Params以及GFLOPs有所增大,但是还是满足轻量网络的要求,并且精度相对于YOLOv5s提高了2.25%,且对于每个类别的缺陷识别准确率都有改善,大幅减少计算量和模型参数的同时保证了准确率,满足工业检测生产需求的同时便于移动端部署。     

氦原子及类氦离子基态的二参数变分法研究

提出了一种计算氦原子及类氦离子基态能量和波函数的二参数变分法,包括试探波函数的设计和基态能量表达式的推导,并用Mathematica 5.0软件的优化计算功能方便快捷地计算出基态能量,将计算结果与实验结果和部分所列文献的结果进行对比.结果表明,本文所得精度较高,变分参数个数较少.同时强调交换对称性和量子态的交缠在双电子原子体系问题中的重要性.     

一种通用的数据采集系统设计及其FPGA实现

基于多相滤波技术和能量检测方法,完成了一种通用的数据采集系统设计及其FPGA实现,可兼容低速、高速和突发信号的采集。仿真和实测结果表明,该系统满足实际需要。     

Effect of Poly(methacrylic acid) on the Cytokine Level in an In Vivo Tumor Model

Cancer is a leading cause of mortality globally. Despite remarkable improvements in cancer-treatment approaches, disease recurrence and progression remain major obstacles to therapy. While chemotherapy is still a first-line treatment for a variety of cancers, the focus has shifted to the development and application of new approaches to therapy. Nevertheless, the relationship between immune response, neoplastic diseases and treatment efficiency is not fully understood. Therefore, the aim of the study was to investigate the immunopharmacological effects of methacrylic acid homopolymer in an in vivo tumor model. Materials and methods: Monomeric methacrylic acid was used to synthesize polymers. Methacrylic acid was polymerized in dioxane in the presence of 4-Cyano-4-[(dodecylsulfanylthiocarbonyl)sulfanyl]pentanoic acid. To study the molecular weight characteristics of PMAA by GPC, carboxyl groups were preliminarily methylated with diazomethane. An experimental cancer model was obtained by grafting RMK1 breast cancer cells. The serum levels of IL-6, IL-10, IL-17, transforming growth factor β1 (TGF-β1), and tumor necrosis factor α (TNF-α) were measured by ELISA. Results: The effect of PMAA on the serum concentrations of several cytokines was studied upon its single administration to laboratory animals in early neoplastic process. The IL-6, IL-17 and TGF-β1 concentrations were found to change significantly and reach the level observed in intact rats. The IL-10 concentration tended to normalize. Conclusion: The positive results obtained are the basis for further studies on the effect of methacrylic-acid polymers with different molecular-weight characteristics on the neoplastic process.     

Fe膜硫化法制备FeS_2薄膜

由于ＦｅＳ２具有窄的禁带宽度（Ｅｇ＝０．９５ｅＶ）和高的吸收系数（α＞６×１０５ｃｍ－１），使它成为一种很有发展前途的太阳能材料。本文主要介绍了用射频溅射制备铁膜，然后在真空中（１０－１Ｐａ），通过控制时间和温度进行硫化。经ＸＲＤ和ＡＥＳ对薄膜进行分析，表明试样在硫化温度Ｔ＝４００℃，时间ｔ＝４８ｈ的条件下，Ｆｅ膜转变为ＦｅＳ２膜