电感耦合等离子体原子发射光谱法测定镍基单晶高温合金中Mo、W、Ta、Re、Ru时元素之间相互干扰的消除与校正的研究

称取镍基单晶高温合金0.100 0g于聚四氟乙烯烧杯中,先令其与盐酸9mL和硝酸1mL加热反应,待反应缓慢时滴加氢氟酸2mL并继续加热使样品完全溶解。加入500g·L^-1酒石酸溶液2mL,冷却至室温,在塑料容量瓶中加水定容至100.0mL。按仪器工作条件采用电感耦合等离子体原子发射光谱法测定其中5种合金元素(Mo、W、Ta、Re、Ru)的含量,选择分析谱线依次为204.598,207.911,240.063,197.312,240.272nm。结果发现:除了Re外,其余4种元素的测定中均受共存元素的光谱干扰,严重影响了测定结果的准确性。为克服其干扰,除了采用基体匹配法消除镍的基体干扰外,试验采用混合校正系数矩阵法对测定结果进行校准。通过一系列试验计算得到混合校准系数矩阵K,并应用于模拟样品的分析。结果表明:经过矩阵K的校准,所测定的5种元素的准确度显著提高,达到了消除共存元素之间光谱干扰的目的。通过精密度试验,测得上述5种元素测定值的相对标准偏差(n=11)均在1.5%以下,并通过标准加入法进行回收试验,测得5种元素的回收率为97.0%~105%。     

Antistatic applications of conducting polyaniline

A method is described to impart flexibility and mechanical strength to conducting polyaniline by polymerizing aniline on fabrics and on cellulose papers. The study indicates that these conducting fabrics offer 16–18 dB of shielding effectiveness for the control of electromagnetic interference (EMI) up to a frequency of 10³ MHz.     

夸克随机组合机制与激发态重子的产生

从强子化过程的两个基本性质出发,在夸克随机组合框架上,得出了包括所有激发态在内的重子产生权重的一组基本关系．解释了“自旋抑制”和单态重子产额大的原因．最后,讨论了进一步确定激发态重子产生比例的条件和方法．     

一种基于SPWVD-WVD的高质量时频分析方法及ISAR成像应用

交叉项干扰抑制与高时频聚集度是准确反应信号的时频分布特征的重要因素。传统的魏格纳-维尔分布(Wigner-Ville Distribution,WVD)算法虽能获得较高的时频分辨特征,但分析多成分信号时存在严重的交叉项干扰问题,限制了其实用性;而平滑伪魏格纳-维尔分布(Smoothed Pseudo Wigner-Ville Distribution,SPWVD)算法虽在一定程度上抑制交叉项干扰,但降低了时频聚集度。为了解决上述问题,提出了基于SPWVD-WVD的时频分析方法。该方法利用SPWVD与WVD之间的滤波互消效应,将SPWVD二值化结果与WVD结果进行矩阵运算,最终得到高质量的时频分析结果。实验结果表明,所提出的算法能够有效去除多分量信号的交叉项干扰,提高信号分析结果的时频聚集度,还原多分量信号的真实时频分布。最后将该算法成功应用于逆合成孔径雷达成像中。     

基于误码率的软件无线电射频干扰效应分析

针对通信系统工作过程中受到外界电磁干扰而无法通信的问题,研究了基于软件无线电的电磁干扰效应及误码特征。通过分析典型软件无线电电磁信号传输特性及其信息链路电磁干扰耦合路径,设计了软件无线电通信干扰实验系统。该系统利用Simulink软件观测、记录通信信号眼图、星座图信息等受扰特征,并通过分析接收信号的误码率,给出了不同干扰信号对通信系统的影响规律：当同频干扰功率达到-40 dBm时通信开始出现误码,干扰功率每增加5 dB,误码率增加一个量级,干扰功率增加到-18 dBm时,误码率达到阈值0.25;邻频干扰误码率随干扰功率变化趋势与同频干扰一致,但出现误码的最小干扰功率更大;带外强干扰信号也会影响通信系统可靠性,在相同误码率情况下,需要更大的干扰信号功率且大小与信号频偏成正比。     

一种降低FBMC-OQAM系统PAPR的ASSABC-PTS算法

针对滤波器组多载波-偏移正交幅度调制技术(Filter Bank Multicarrier-Offset Quadrature Amplitude Modulation,FBMC-OQAM)存在峰均功率比(Peak-to-Average Power Ratio,PAPR)过高的问题,以及传统部分传输序列(Partial Transfer Sequence,PTS)算法对PAPR抑制效果不明显,提出了一种新的基于自适应搜索策略的人工蜂群部分传输序列算法(Adaptive Search Strategy Based Artifical Bee Colony PTS,ASSABC-PTS)。首先,根据FBMC-OQAM系统特性,利用传统PTS算法对系统进行初步优化,以降低FBMC-OQAM系统的PAPR;然后,针对PTS算法中存在的计算复杂度问题,引入人工蜂群(Artificial Bee Colony,ABC)算法进行优化;最后,在ABC算法中引入自适应搜索策略提升算法的局部寻优能力,加快ABC算法的收敛速度和搜索精度。仿真实验表明,ASSABC-PTS在有效降低系统算法复杂度的同时,也极大降低了FBMC-OQAM系统的峰均功率比。     

光纤电压传感器传感头优化与热致非互易误差抑制

针对普通光纤电压传感器在外界温度扰动下其输出精度和稳定性会受到严重影响这一问题,本文提出了一种采用保偏光子晶体光纤(polarization maintaining photonic crystal fiber,PM-PCF) 作为传感光纤的传感头优化方法抑制温度扰动下的系统非互易误差。在综合考虑PM-PCF与传统熊猫型保偏光纤(panda polarization maintaining fiber,panda-PMF) 尾纤间的熔接损耗、传输损耗以及现有工艺条件下的光纤制备等问题的基础上,优化得到了与panda-PMF间的熔接损耗低至0.14 dB的PM-PCF;并对比分析了这两种保偏光纤的双折射温度依赖特性,建立了全光纤类型的光学电压传感器(fiber optic voltage sensor,FOVS) 热致系统误差输出模型,分析验证了PM-PCF在解决反射式逆压电型FOVS热致非互易问题的可行性。结果表明,采用PM-PCF优化后的FOVS热致非互易误差约是传统保偏光纤电压传感器 的10-2量级。这在提高系统输出精度和稳定性等方面具有显著优势,同时这种低损耗的优化方法在光纤传感及通信等领域具有重要的应用价值。     

差分无源器件的设计

在现代无线通信系统中,差分电路相比单端电路而言具有更强的抗干扰能力,因此受到了国内外学者的广泛关注。文章介绍了混合模散射参数、差分器件设计中常用的微带线和缝隙线及两种传输线之间的相互转化,并介绍了基于微带线和缝隙线转换结构的两种全差分带通滤波器。两种滤波器分别实现了多频段和宽带的差模传输特性以及宽带的共模抑制特性。文章还给出了差分耦合器、差分功分器和差分天线等差分器件的设计。仿真与实测结果吻合较好,验证了设计方法的正确性。     

Hyperelastic,Robust, Fire-Safe Multifunctional MXene Aerogels with Unprecedented Electromagnetic Interference Shielding Efficiency

MXene aerogels have shown great potential for many important functional applications, in particular electromagnetic interference (EMI) shielding. However, it has been a grand challenge to create mechanically hyperelastic, air-stable, and durable MXene aerogels for enabling effective EMI protection at low concentrations due to the difficulties in achieving tailorable porous structures, excellent mechanical elasticity, and desired antioxidation capabilities of MXene in air. Here, a facile strategy for fabricating MXene composite aerogels by co-assembling MXene and cellulose nanofibers during freeze-drying followed by surface encapsulation with fire-retardant thermoplastic polyurethane (TPU) is reported. Because of the maximum utilization of pore structures of MXene, and conductive loss enhanced by multiple internal reflections, as-prepared aerogel with 3.14 wt% of MXene exhibits an exceptionally high EMI shielding effectiveness of 93.5 dB, and an ultra-high MXene utilization efficiency of 2977.71 dB g g⁻¹, tripling the values in previous works. Owing to the presence of multiple hydrogen bonding and the TPU elastomer, the aerogel exhibits a hyperelastic feature with additional strength, excellent stability, superior durability, and high fire safety. This study provides a facile strategy for creating multifunctional aerogels with great potential for applications in EMI protection, wearable devices, thermal management, pressure sensing, and intelligent fire monitoring.     

Fast Ion Transport in Li-Rich Alloy Anode for High-Energy-Density All Solid-State Lithium Metal Batteries

All-solid-state Li batteries (ASSLBs) with solid-polymer electrolytes are considered promising battery systems to achieve improved safety and high energy density. However, Li dendrite formation at the Li anode under high charging current density/capacity has limited their development. To tackle the issue, Li-metal alloying has been proposed as an alternative strategy to suppress Li dendrite growth in ASSLBs. One drawback of alloying is the relatively lower operating cell voltages, which will inevitably lower energy density compared to cells with pure Li anode. Herein, a Li-rich Li₁₃In₃ alloy electrode (LiRLIA) is proposed, where the Li₁₃In₃ alloy scaffold guides Li nucleation and hinders Li dendrite formation. Meanwhile, the free Li can recover Li's potential and facilitate fast charge transfer kinetics to realize high-energy-density ASSLBs. Benefitting from the stronger adsorption energy and lower diffusion energy barrier of Li on a Li₁₃In₃ substrate, Li prefers to deposit in the 3D Li₁₃In₃ scaffold selectively. Therefore, the Li–Li symmetric cell constructed with LiRLIA can operate at a high current density/capacity of 5 mA cm⁻²/5 mAh cm⁻² for almost 1000 h.