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91.
Norio Yoshino Munetoshi Morita Atsushi Ito Masahiko Abe 《Journal of fluorine chemistry》1995,70(2):187-191
Anionic surfactants having two polyfluoroalkyl chains per molecule, i.e. the sodium salt of bis(1H, 1H, 2H,2H-heptadeca-fluorodecyl)-2-sulfosuccinate, CF3(CF2)7(CH2)2OCOCH2CH(SO3Na)COO(CH2)2(CF2)7CF3, the sodium salt of bis(1H, 1H, 2H, 2H-tridecafluoro-octyl)-2-sulfosuccinate, CF3(CF2)5(CH2)2OCOCH2CH(SO3Na)COO(CH2)2(CF2)5CF3, and the sodium salt of bis(1H, 1H, 2H, 2H-nonafluorohexyl)-2-sulfosuccinate, CF3(CF2)3(CH2)2OCOCH2CH(SO3Na)COO(CH2)2(CF2)3CF3, have been prepared from maleic anhydride, the corresponding alcohols possessing a polyfluoroalkyl chain and sodium hydrogen sulfite. The flocculation and redispersion abilities of these surfactants for dispersed magnetic particles in water have been examined to investigate the effect of the chain length. It was found that this ability was enhanced by an increase in the chain length. The contact angles for water for pelleted surface-modified magnetite have been measured. In order to compare this ability and the contact angles, data for other fluorinated surfactant have been obtained. The Kraff point, the surface tension and the pNa of the aqueous surfactant solutions have also been measured. 相似文献
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Sumitra Tavornvipas Hidetoshi Arima Fumitoshi Hirayama Kaneto Uekama Toshihiro Ishiguro Masahide Oka Kenichi Hamayasu Hitoshi Hashimoto 《Journal of inclusion phenomena and macrocyclic chemistry》2002,44(1-4):391-394
Some physicochemical and biological properties of a new branched cyclodextrin, 6-O--(4-O--d-glucuronyl)-d-glucosyl--cyclodextrin GUG--CyD) were investigated. Further, theinteraction of GUG--CyD with several drugs was studied by the solubility and spectroscopic methods, and compared with those of parent -CyD and 6-O--maltosyl--CyD(2--CyD).The hemolytic activity of GUG--CyD on rabbit erythrocytes was lower than those of -CyD and 2--CyD. GUG--CyD and 2--CyD showed negligible cytotoxicity on Caco-2 cells up to at least 0.1 M. The inclusion ability of GUG--CyD to neutral and acidic drugs was comparable to or slightly smaller than those of -CyD and 2--CyD, probably because of a steric hindrance of the branched sugar. On the other hand, GUG--CyD showed greater affinity for the basic drugs, compared with -CyD and 2--CyD, owing to the electrostatic interaction of its carboxylate anion with positive charge of basic drugs. Thus GUG--CyD may be useful as a safe solubilizing agent particularly for basic drugs. 相似文献
94.
教学改革的最终目标都是为了有益于学生的全面发展以及实践能力的提高。以大学物理实验改革为例,介绍了"少台套大循环"的实验改革与教学管理方法。经过两年多"少台套大循环"的运行,这种改革不仅提高了学生的实验操作能力,而且在教学资源有效配置方面探索出一种可行的运行模式。 相似文献
95.
Tibor Novák Péter Bakó György Keglevich András Dobó Károly Vékey László Tóke 《Journal of inclusion phenomena and macrocyclic chemistry》2001,40(3):207-212
Five chiral -D-glucose-based monoaza-15-crown-5 ethers with phosphinoxidoalkyl side chains of one to five carbon atoms (5a–e)have been synthesised. The cation binding ability of the new lariat ethers was evaluated bythe picrate extraction method. The substituents at the nitrogen atom were not a major influenceon the cation extraction ability of the azacrown ether; the compounds showed, however, a significant asymmetric induction as phase transfer catalysts in the Michael addition of2-nitropropane to chalcone (95% ee). 相似文献
96.
水资源可再生能力综合评价的遗传加权物元模型 总被引:6,自引:0,他引:6
为了科学地计算水资源可再生能力评价指标的权重 ,使评价方法具有可操作性 ,采用主、客观相结合的赋权基点法 ,以全局收敛的格雷码加速遗传算法为工具来确定权重 ,并结合物元分析理论 ,建立了一种新的评价模型——遗传加权物元模型 .文中给出了该模型实施的详细步骤 ,对黄河流域 9个行政分区的水资源可再生能力进行了综合评价 ,取得了较好的效果 . 相似文献
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Two membrane bioreactors (MBRs; volume = 300 L) equipped with different types of immersed membrane modules were operated simultaneously
under the same laboratory conditions as a low-loaded activated sludge process without any membrane regeneration and excess
sludge uptake (sludge retention time SRT up to 170 d; activated sludge concentration MLSS up to 11 g L−1). The aim was to verify the quality of treated water and to study the properties of "very old" activated sludge. Another
aim was to compare different selected membrane types and choose the best one for further pilot-scale testing.
Presented at the 35th International Conference of the Slovak Society of Chemical Engineering, Tatranské Matliare, 26–30 May
2008. 相似文献
100.