Interpretation of the polyelectrolyte and antipolyelectrolyte effects of poly(N‐vinylimidazole‐co‐sodium styrenesulfonate) hydrogels

Hydrogels of N‐vinylimidazole (VI) and sodium styrenesulfonate (SSS) were synthesized in aqueous solution by radical crosslinking copolymerization with N,N′‐methylene‐bis(acrylamide) as crosslinker. Swelling in several saline solutions was measured for hydrogel samples synthesized with different comonomer concentrations (C_T = 10, 25, or 40%) and with SSS mole fractions covering a broad range (f_SSS = 0–0.7), while the crosslinker ratio was 2 wt % in all cases. The degree of swelling in aqueous solution with a specific ionic strength (μ), plotted versus the SSS composition of the feed, shows a minimum for any set of samples synthesized with a fixed C_T. The dependence of swelling on μ shows both polyelectrolyte (f_SSS beyond the minimum) and antipolyelectrolyte behaviors (in the low f_SSS limit). It was found that the nonGaussian factor of the crosslinking density and the polymer‐solvent interaction parameter increase with f_SSS for any C_T. Moreover, in the low f_SSS limit, the osmotic swelling pressure is governed not only by the ionic contribution, but also by the polymer‐solvent mixing and, the concentration of mobile counterions inside the gel is not proportional to the net fixed charge but to the addition of cationic and anionic side groups, what discards the formation of ionic pairs. The antipolyelectrolyte effect is interpreted as due to the increasing protonation of VI as μ goes up. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1683–1693, 2007     

闭排队网络中性能势与无穷小实现因子之间的关系

In this paper,the concept of the infinitesimal realization factor is extended to the parameter-dependent performance functions in closed queueing networks. Then the concepts of realization matrix (its elements are called realization factors) and performance potential are introduced,and the relations between infinitesimal realization factors and these two quantities are discussed. This provides a united framework for both IPA and non IPA approaches. Finally,another physical meaning of the service rate is given.     

上海市电话局用户接入网发展状况

上海市电话局用户接入网建设经历了调研、网络规划、启动实施和进一步完善、规范四个怅阶段、现已基本形成了覆盖政府机关、大专院校、医院、商务大楼及高层建筑、新建住宅小区、区级以上图书馆等范围的用户光纤网络，为加快经济建设步伐、满足多层次用户需求、拓展电信新业务打下了坚实基础。     

用基函数神经网络实现多阈值图象分割

本文介绍了一种用基函数神经网络实现多阈值图象分割的新方法。它从函数逼近的角度研究基于灰度直方图的多阈值分割问题，提出了一种模糊反向传播学习算法，采用该算法的高斯基函数网络能够准确检测直方图中包含的子区域和它们的分布函数，而且速度很快。实验表明本文的方法在实际图象分割中是有效的。     

数字程控交换机与专网中的多媒体通信

本文以一个多媒体通信应用VISIT为实例,介绍了多媒体通信在数字程控交换机及专网中的应用情况。     

On the departure process of a leaky bucket system with long-range dependent input traffic

Due to the strong experimental evidence that the traffic to be offered to future broadband networks will display long-range dependence, it is important to study the possible implications that such traffic may have for the design and performance of these networks. In particular, an important question is whether the offered traffic preserves its long-range dependent nature after passing through a policing mechanism at the interface of the network. One of the proposed solutions for flow control in the context of the emerging ATM standard is the so-called leaky bucket scheme. In this paper we consider a leaky bucket system with long-range dependent input traffic. We adopt the following popular model for long-range dependent traffic: Time is discrete. At each unit time a random number of sessions is initiated, having the distribution of a Poisson random variable with mean λ. Each of these sessions has a random duration τ, where the integer random variable τ has finite mean, infinite variance, and a regularly varying tail, i.e., P(τ >К) ~ К^-Lα L(К), where 1 < α < 2 L(·) is a slowly varying function. Once a session is initiated, it generates one cell at each unit of time until its termination. We examine the departure process of the leaky bucket policing mechanism driven by such an arrival process, and show that it too is long-range dependent for any token buffer size and any - finite or infinite - cell buffer size. Moreover, upper and lower bounds for the covariance sequence of the output process are established. The above results demonstrate that long-range dependence cannot be removed by the kinds of flow control schemes that are currently being envisioned for broadband networks. This revised version was published online in June 2006 with corrections to the Cover Date.     

Gelation of poly(n-butylisocyanate) in benzene

Poly (n-butylisocyanate)-benzene solutions prepared by solubilization at 45°C, followed by aging at room temperature were found to be metastable for months, although, eventually, they separated into a birefringent polymer-rich phase and an isotropic solution. These metastable solutions, as well as isothermally phase-separated biphasic samples, flowed and exhibited dynamic moduli indicative of low polymer connectivity. By contrast samples prepared by a freeze-thaw cycle were uniformly and highly birefringent and showed network (gel) behavior at room temperature. The mechanism of gel formation is most likely the exclusion of the polymer from the benzene crystal during crystallization, forcing the polymer to align and exist at grain boundaries. Films formed from solutions have different moduli than those formed from gels, and are consistent with the proposed mechanism.     

偏最小二乘回归的贝叶斯正则化神经网络集成模型在证券分析预测中的应用

神经网络集成技术能有效地提高神经网络的预测精度和泛化能力,已经成为机器学习和神经计算领域的一个研究热点.利用Bagging技术和不同的神经网络算法生成集成个体,并用偏最小二乘回归方法从中提取集成因子,再利用贝叶斯正则化神经网络对其集成,以此建立上证指数预测模型.通过上证指数开、收盘价进行实例分析,计算结果表明该方法预测精度高、稳定性好.     

基于BP神经网络的企业未来获利能力智能综合评价

分析了相关分析——多指标综合评价法在确定企业未来获利能力方面的优点和不足 ;并在其基础上提出了基于 BP神经网络的多指标综合评价法 ;仿真试验证明了基于 BP神经网络的多指标综合评价法的有效性