Fluorescence line narrowed spectra of Zn and metal-free cytochrome c

Fluorescence line narrowing (FLN) spectroscopy was used to study the role of the polypeptide chain in influencing the spectrum of Zn-substituted cytochrome c (Zn cyt c) and metal-free cyt c (porphyrin cyt c). For both derivatives the spectra show characteristics of relaxed fluorescence from an inhomogeneously broadened sample. Zero phonon lines and phonon wings can be clearly distinguished, and vibrational frequencies of the ground and excited states were identified. The inhomogeneous distribution width for porphyrin cyt c is slightly wider than that of Zn cyt c and a second population of molecules was apparent in the porphyrin cyt c. The phonon coupling was greater for Zn cyt c than for porphyrin cyt c, which may be due to the extra coupling to the polypeptide chain by metal ligation.This work has been done in partial fulfillment of the requirements for the Doctor of Philosophy degree.     

过共晶Al－Si合金共生区激光表面处理

用２ｋＷ连续ＣＯ２激光对过共晶Ａｌ－１８Ｓｉ合金以不同能量密度和扫描速度进行快速熔凝处理。用扫描电镜、电子微区分析仪分析了微观结构。从计算机对Ａｌ－Ｓｉ合金ｆ－ｎｆ系统的非平衡理论计算所得的共生区及实验结果的分析可见，当能量密度和扫描速度决定的凝固条件处于共生区中部时，过共晶Ａｌ－Ｓｉ合金激光表面处理可以得到共晶间距低于２００ｎｍ的完全共晶结构。     

用于X光激光实验的反射式线聚焦光学系统的设计和分析

基于三维光线追迹的象差计算,对卢瑟福实验室用离轴球面反射线聚焦系统作了分析。然后,首次提出了用于X光激光实验的两类新的反射式线聚焦构型,即反射式光楔列阵和光锥列阵系统,并作了计算。最后,对所得结果作了比较和讨论。     

FIXED POINTS AND COUPLED FIXED POINTS FOR INCREASING OPERATORS WITH APPLICMIONS TO DIFFERENTIAL INCLUSIONS IN BANACH SPACES

ＦＩＸＥＤＰＯＩＮＴＳＡＮＤＣＯＵＰＬＥＤＦＩＸＥＤＰＯＩＮＴＳＦＯＲＩＮＣＲＥＡＳＩＮＧＯＰＥＲＡＴＯＲＳＷＩＴＨＡＰＰＬＩＣＭＩＯＮＳＴＯＤＩＦＦＥＲＥＮＴＩＡＬＩＮＣＬＵＳＩＯＮＳＩＮＢＡＮＡＣＨＳＰＡＣＥＳＺＨＡＮＧＳＨＩＳＨＥＮＧＡＮＤＨＵ...     

激光标线的原理和实验

根据几何光学知识分析了激光标线原理.理论和实验表明:激光标线长度与激光光束形状、光学元件形状及材料折射率有关.并讨论了激光标线向两侧扩展的原因.     

R~(2,1)中线性Weingarten曲面的Bcklund变换(英文)

本文对三维Minkowski空间R~(2,1)中具有性质K-2mH+m~2-l~2=0或H=constant的类时曲面定义了一个Darboux线汇,同时得到了相应的Bcklund变换。     

CCD光谱谱线标定方法研究

CCD作为光谱分析和测色仪器的光谱接收器件 ,光谱谱线定位受单色仪狭缝和CCD光敏元尺寸影响。提出采用最小二乘法做曲线拟合和质心法来确定光谱线在CCD上的精确定位 ,使光谱谱线的定位精度得到提高 ,并且不受CCD光敏元尺寸限制。实验结果表明 ,两种方法对光谱线的定位 ,具有重复性高 ,稳定性好等特点。在定位精度上 ,两者具有一致性。     

Coupled Thermo-Hydro-Mechanical and Chemical Analysis of Expansive Clay Subjected to Heating and Hydration

A fully coupled formulation combining reactive transport and an existing thermo-hydro-mechanical (THM) code is presented. Special attention has been given to phenomena likely to be encountered in clay barriers used as part of containment systems of nuclear waste. The types of processes considered include hydrolysis, complex formation, oxidation/reduction reactions, acid/base reactions, precipitation/dissolution of minerals and cation exchange. Both kinetically-controlled and equilibrium-controlled reactions have been incorporated. The total analytical concentrations (including precipitated minerals) are adopted as basic transport variables and chemical equilibrium is achieved by minimizing Gibbs Free Energy. The formulation has been incorporated in a general purpose computer code capable of performing numerical analysis of engineering problems. A validation exercise concerning a laboratory experiment involving the heating and hydration of an expansive compacted clay is described.     

沿直线的垂直方向匀速直线运动的带电直线的电场

本文利用相对论变换关系计算了沿直线的垂直方向匀速运动的带电直线的电场.     

一种光时分制交换时隙分配计算算法

介绍了一种专为时分复用系统设计的时院分配计算算法。这种算法中主要用到的技术是从一个话务矩阵的各行选出一个区别代表的系统方法。对于任何话务矩阵，这种算法的分配效率都能达到１００％，所产生的模式矩阵个数最多为ｎ２－２ｎ＋２个（对于ｎ×ｎ矩阵）。