具有饱和项的互惠系统的分歧与稳定性

运用谱分析和分歧理论的方法,在齐次Dirichlet边界条件下,对具有饱和项的互惠系统的非负定态解的分歧及其稳定性进行研究.一方面,分别以生长率作为分歧参数,讨论了发自半平凡解的分歧;另一方面,以两物种的生长率作为分歧参数,利用Liapunov-Schmidt过程,研究了在二重特征值处的分歧;同时判定了这些分歧解的稳定性.     

基于动态概率攻击图的云环境攻击场景构建方法

针对复杂多步攻击检测问题,研究面向云计算环境的攻击场景构建方法.首先,构建了动态概率攻击图模型,设计了概率攻击图更新算法,使之能够随着时空的推移而周期性更新,从而适应弹性、动态性的云计算环境.其次,设计了攻击意图推断算法和最大概率攻击路径推断算法,解决了误报、漏报导致的攻击场景错误、断裂等不确定性问题,保证了攻击场景的...     

空对空多目标攻击载机攻击航线求解逻辑

介绍了空对空多目标攻击载机攻击航线的基本要求、航线选择和求解方法,以及载机航线、瞄准偏差、操纵指令的计算逻辑图.同时还介绍了多目标攻击"可能攻击扇形区"交集的概念和在载机航线求解中的应用等问题.     

Convolutional Neural Network Approach for Multispectral Facial Presentation Attack Detection in Automated Border Control Systems

Automated border control systems are the first critical infrastructure point when crossing a border country. Crossing border lines for unauthorized passengers is a high security risk to any country. This paper presents a multispectral analysis of presentation attack detection for facial biometrics using the learned features from a convolutional neural network. Three sensors are considered to design and develop a new database that is composed of visible (VIS), near-infrared (NIR), and thermal images. Most studies are based on laboratory or ideal conditions-controlled environments. However, in a real scenario, a subject’s situation is completely modified due to diverse physiological conditions, such as stress, temperature changes, sweating, and increased blood pressure. For this reason, the added value of this study is that this database was acquired in situ. The attacks considered were printed, masked, and displayed images. In addition, five classifiers were used to detect the presentation attack. Note that thermal sensors provide better performance than other solutions. The results present better outputs when all sensors are used together, regardless of whether classifier or feature-level fusion is considered. Finally, classifiers such as KNN or SVM show high performance and low computational level.     

萃取法研究Cu2+-dpx-PCA-体系配体间的芳环堆积作用及其配合物的组成

用萃取法测定Cu²⁺-dpx-PCA^-体系中的堆积百分数，其中dpx=2,2′-联吡啶胺(dpa)，2，2′-联吡啶甲烷(dpm)和2，2′-联吡啶酮(dpk); PCA^-=苯甲酸根(Bz^-), 2-苯乙酸根(PAc^-),3-苯丙酸根(PPr^-)和4-苯丁酸根(PBu^-)。结果表明：堆积百分数与羧酸根中亚甲基数有关，其顺序为Bz^---π电子协作效应的缘故。     

Insights into the Complexity of Weak Intermolecular Interactions Interfering in Host–Guest Systems

The recognition properties of heteroditopic hemicryptophane hosts towards anions, cations, and neutral pairs, combining both cation–π and anion–π interaction sites, were investigated to probe the complexity of interfering weak intermolecular interactions. It is suggested from NMR experiments, and supported by CASSCF/CASPT2 calculations, that the binding constants of anions can be modulated by a factor of up to 100 by varying the fluorination sites on the electron‐poor aromatic rings. Interestingly, this subtle chemical modification can also reverse the sign of cooperativity in ion‐pair recognition. Wavefunction calculations highlight how short‐ and long‐range interactions interfere in this recognition process, suggesting that a disruption of anion–π interactions can occur in the presence of a co‐bound cation. Such molecules can be viewed as prototypes for examining complex processes controlled by the competition of weak interactions.     

多支结构的均三嗪衍生物的合成及双光子吸收性质

合成了3个系列各含有单支、双支和三支结构的9个均三嗪衍生物, 测定了它们的线性吸收和发射性质以及双光子吸收和发射性质. 随着三嗪环上侧链数目的增加, 线性吸收谱(吸收峰位于390～440 nm)、荧光谱(发射峰位于460～580 nm)和双光子荧光谱(激发波长800 nm)都发生红移; 各种光谱的强度逐渐增强; 基态与激发态的偶极矩之差Δμ_eg也逐渐增大. 另外, 从单支到三支结构, 双光子吸收截面σ随侧链数目呈非线性增加. 这表明多支结构的双光子吸收存在显著的增强效应.     

间苯三酚修饰的吸附树脂对水中2,6-二氯苯酚和间苯三酚的吸附机理研究

制备了经间苯三酚进行化学修饰的吸附树脂并进行了红外光谱表征,以NDA150作为参照,对比了两种吸附树脂对不同温度下水溶液中间苯三酚、2,6-二氯酚以及间苯三酚/2,6-二氯酚双组分体系的吸附研究,并探讨了其吸附机理.结果表明：在合适的温度下FZH33对溶液中间苯三酚、2,6-二氯酚的吸附过程存在化学吸附效应,和NDA1...     

离子液体阴阳离子协同催化芳香胺与碳酸丙烯酯反应

以离子液体1-丁基-3-甲基咪唑乙酸盐([bmim]OAc)为催化剂,以芳香胺和碳酸丙烯酯为原料,一步合成了5-甲基-3-芳基噁唑烷-2-酮.系统考察了反应温度、反应时间以及催化剂用量对反应性能的影响.在优化的反应条件下,5-甲基-3-苯基噁唑烷-2-酮的收率可达99％.研究了离子液体阴阳离子结构对反应性能的影响,发现...     

双边配给问题的Shapley解及其在博物馆通票问题中的应用

双边配给问题描述了现实生活中一类带有二部图结构的稀缺资源配置问题, 例如, 在自然灾害期间救援物资的配给; 电力和天然气等自然资源按需分配; 高校引进人才调配等。本文通过求解线性规划, 并从联盟边际贡献的角度出发定义了双边配给问题的一个Shapley解。之后, 通过合作对策模型和解的公理化方法说明新解的合理性。首先, 建立双边配给问题的合作对策模型, 论证了新解与双边配给合作对策的Shapley值一致; 其次, 证明了Shapley解是唯一满足优先一致性的有效配给方案。最后, 将Shapley解应用于博物馆通票问题的研究, 探讨了博物馆合作制定通票后所得单票和通票收益的分配方式。