Ka 波段宽带单边带调制器集成电路的设计

基于相移法实现SSB(单边带)调制器理论,设计制造了一种Ka 波段宽带SSB 调制器集成电路。对相移法产生单边带调制信号的原理进行了分析,利用无源电路的3D 电磁仿真分析和ADS 整体电路非线性仿真相结合的方法对调制器进行了优化。设计制造的90°相移电桥网络和同相合成器满足了产生Ka 波段SSB 信号的幅相要求,同时给出了测试结果。调制器在30 ~36GHz 频带内插入损耗臆14dB;载波和对称边带抑制逸15dB;其它边带抑制逸13dB;输入1dB 压缩功率38dBm;外形尺寸18mm×6mm。这种相移法单边带调制器不需要带通滤波器,具有电路简单,载波抑制比高,对相位误差要求不高的优点。     

基于C8051f040单片机的光离子化气体浓度检测电路设计

对光离子化气体浓度的测量,本质上是对其产生的微电流的测量。为此以C8051f040单片机为核心器件,采用内部ADC、信号采集单元设计一种测量系统,可以对0~200×10-6量程范围内的待测气体浓度实时检测并用数码管显示。该系统通过金属屏蔽信号采集单元和在软件编程中采用过采样、数字滤波相结合的方法来提高系统的信噪比。在计算机自动配气系统中测试了二甲醚的气体浓度,误差范围≤0.07×10-6,响应速度快、工作可靠、可作为实际应用。     

A low-distortion multi-bit sigma–delta ADC with mismatch-shaping DACs for WLAN applications

A low-distortion feed-forward MASH2_4b-2_4b sigma–delta analog-to-digital converter (ADC) for wireless local area network (WLAN) applications was presented. The converter exhibits improved performances than the ADCs which have been presented to date by adding a feedback factor in the second stage and employing a 2nd-order noise-shaping dynamic element matching (DEM) scheme. The feedback factor induces a zero in the noise transfer function (NTF) and therefore improves the in-band signal to noise and distortion ratio (SNDR) of the modulator. The mismatch-shaping DEM was introduced and applied to the 4-bit DACs in this paper to improve the resolution and linearity of the ADC. Fabricated in a 0.18 μm CMOS process with single 1.8 V supply voltage, the converter achieves a peak SNDR of 85.4 dB over a 10 MHz bandwidth which implies an effective number of bits (ENOB) of 13.90-bit. The spurious free dynamic range (SFDR) is –94 dB for a 1.25 MHz@–6dBFS input signal at 160 MHz sampling frequency. The occupied area is 0.44 mm² and dissipation power 23.4 mW.     

All-digital controlled boost DC–DC converter with all-digital DLL-based calibration

Traditional digital controls mostly use digital–analog converters to convert input and output voltages into digital coding to achieve control. This paper proposes the use of two digital ramps with two different frequencies to replace a digital–analog converter. This approach can produce seven bit resolution for the DPMW signal. In addition, we use an all-digital DLL phase correction concept to further enhance the resolution of the DPWM signal by an additional three bits, resulting in 10-bit DPWM signal resolution. The proposed circuit uses 0.35 μm CMOS processes, with a core area of 0.987 mm², a system switching frequency of 500 KHz, an input voltage range of 3.3–4.2 V, and an output voltage range of 5 V. Output voltage measurement accuracy reaches 99%, while the system reaches efficiency of 91% with output loads of up to 500 mA.     

稀疏多带信号的压缩采样技术的研究

实现宽带压缩采样的结构有多种类型,在分析调制宽带转换器的采样结构的原理的基础上,针对稀疏多带信号的压缩采样,搭建了四通道的宽带压缩采样系统的原型系统平台,其中,混频调制信号是现场可编程门阵列硬件电路产生的序列。采用稀疏多频带信号作为系统的输入测试信号,并且利用另一已知的稀疏多带信号作为系统的同步信号,对宽带压缩采样原型系统进行系统仿真。该系统中的混频调制信号容易生成、实现结构简单、参数设置灵活。软件仿真及硬件测试,验证了该宽带压缩采样系统的硬件平台的正确性和可行性。     

滤膜冷凝收集-离子色谱法测定固液气溶胶中5种水溶性阴离子北大核心CSCD

水溶性离子是固、液气溶胶的重要组成部分,对于气溶胶的理化性质和空气质量具有重大影响,研究水溶性离子的含量对于大气环境的污染与防治具有深远意义。该研究建立了一种滤膜冷凝收集-离子色谱技术采集固体气溶胶和液体气溶胶并测定其中的5种水溶性阴离子(Cl^(-)、F^(-)、NO^(-)_(3)、NO2^(-)、SO4^(2-))含量的方法。首先,采用固体颗粒过滤器和冷凝收集法分别收集固体气溶胶和液体气溶胶,固体气溶胶以固体颗粒物的形式被收集在固体颗粒过滤器内,液体气溶胶以冷凝液的形式在冷阱中被收集。其次,以离子色谱法对固、液体气溶胶中的水溶性阴离子含量进行检测。在以Dionex IonPac AS11-HC-4μm作为分析柱,流速为1 mL/min,柱温为30℃,淋洗液氢氧化钾(KOH)浓度在0~40 min内由1 mol/L线性增至25 mol/L,进样量100μL的条件下,各离子在40 min内有效分离,5种阴离子在0.1~10 mg/L范围内线性关系良好(相关系数为0.9992~0.9997),检出限低(0.02~0.04 mg/L)。对样品采集条件(采样时间、采样温度和采样流量)进行了优化,结果表明,在采样时间2 h、采样温度-13℃、采样流量1.0 L/min的条件下,可获得较为满意的结果。在优化的条件下分别对实际样品的两类溶胶中的5种阴离子含量进行了检测,测得实际样品的液体气溶胶中5种阴离子含量分别为5.7402μg/m^(3)(F^(-))、1.1599μg/m^(3)(Cl^(-))、3.3233μg/m^(3)(NO^(-)_(2))、2.4861μg/m^(3)(NO^(-)_(3))和0.9745μg/m^(3)(SO^(2-)_(4)),固体气溶胶中5种阴离子含量分别为14.1037μg/m^(3)(F^(-))、5.0398μg/m^(3)(Cl^(-))、9.3052μg/m^(3)(NO^(-)_(2))、8.4528μg/m^(3)(NO^(-)_(3))和5.6314μg/m^(3)(SO^(2-)_(4))。该方法可应用于实际的大气检测中,也为其他离子的采集和分析条件的摸索提供了方法。     

离子色谱法同时测定不同时段酸雨中17种离子

应用离子色谱法同时测定不同时段酸雨中17种离子的含量。样品经离心沉淀后,经0.45μm滤膜过滤,滤液供离子色谱分析。阴离子分离时用Shodex SI-52 4E阴离子色谱柱,并用3.6mmol·L-1碳酸钠-0.6 mmol·L-1碳酸氢钠缓冲溶液作为淋洗液;阳离子分离时用TSKGEL阳离子色谱柱,并用2mmol·L-1硝酸溶液作为淋洗液,采用电导检测器进行检测。17种离子均在一定的质量浓度范围内与其峰面积呈线性关系,方法的检出限(3S/N)在1.4~18.7μg·L-1之间。回收率在95.0%~105%之间,测定值的相对标准偏差(n=6)在1.7%~7.2%之间。     

离子色谱法测定合成气制烯烃产物中的C_1~C_6有机酸

采用离子色谱建立了合成气制烯烃(SGTO)水相产物和油相产物中C1~C6有机酸的测定方法。对分离条件进行了优化,使用标准样品测定了线性范围和工作曲线,考察了方法的精密度和准确度,确定了SGTO油相产物样品的碱洗条件,并对SGTO水相产物和油相产物样品进行了测定。结果表明:C1~C6有机酸的质量浓度在各自配制的质量浓度范围内呈现良好的线性关系,相关系数均大于0.99。标准溶液的回收率测定表明回收率在95.6%~104.3%之间,5次重复测定的相对标准偏差(RSD)在0.4%~3.6%之间,表明该方法具有良好的准确性和精密度。SGTO油相产物中的加标回收率在91.1%~96.8%之间,5次重复测定的RSD为0.7%~2.3%,准确性可以满足实际分析的需要。实际SGTO水相产物和油相产物中C1~C6有机酸的分析结果表明,SGTO水相产物中C2~C4有机酸含量较高,而SGTO油相产物中C4~C6有机酸含量较高。本研究对SGTO反应研究、催化剂制备、工艺优化以及设备材料的选择具有重要意义。     

Maximum power point tracker based on maximum power point resistance modeling

This paper presents a new, simple, accurate, and inexpensive practical methodology and experimental solution for the modeling of conventional (domestic and commercial facilities) photovoltaic generators (PVG), so that they can work at their maximum power point (MPP). The PVG may be a panel, an array of panels, or a photovoltaic field. As a starting restriction (actual) it has to be assumed that it is not possible to isolate the PVG variables dependence (mainly current, voltage, and hence power) with solar radiation and temperature, because they are highly correlated. This methodology proposes the modeling facility on its MPP by its MPP resistance (R_MPP = V_MPP/I_MPP), being V_MPP and I_MPP the voltage and current of the PVG, respectively, at its MPP. The analysis shows, by simulation first and then experimentally, that R_MPP does not present significant temperature dependencies, at least in the usual range. This important result allows us to model the PVG only in terms of solar radiation. From a set of experimental data, different models to estimate R_MPP are proposed. The obtained results are very accurate. These models allow an immediate practical application that it is also developed in the paper: MPP tracker (MPPT) design by the calculation of the DC/DC converter duty cycle which places the PVG at its MPP directly and continuously. This new methodology and experimental system has been registered in the Spanish Patent and Trademark Office with the number P201530352. Copyright © 2015 John Wiley & Sons, Ltd.     

Direct separation of the enantiomers of ramosetron on a chlorinated cellulose‐based chiral stationary phase in hydrophilic interaction liquid chromatography mode

Ramosetron is an enantiopure active pharmaceutical ingredient marketed in Japan since 1996 and later in a few Southeast Asian countries predominantly as an antiemetic for patients receiving chemotherapy. In this study, a simple and rapid high‐performance liquid chromoatography method for the separation of ramosetron and its related enantiomeric impurity by using hydrophilic interaction liquid chromatography mode is presented. Chiral resolution was performed on an analytical column (100 mm × 4.6 mm id) packed with 3 μm particles of cellulose‐based Chiralpak IC‐3 chiral stationary phase. Using a mobile phase containing acetonitrile–water–diethylamine (100:10:0.1, v/v/v) and setting the column temperature at 35°C, the resolution value was 7.35. At a flow rate of 1 mL/min, the enantioseparation was completed within 5 min. The proposed method was partially validated and it has proven to be sensitive with limit of detection and limit of quantitation of the (S)‐enantiomer impurity of 44.5 and 133.6 ng/mL.