基于球面晶体背光成像系统的性能模拟研究

为了实现球面晶体背光成像、验证球面晶体背光成像系统性能,采用模拟软件SHADOW对该背光成像系统进行了模拟研究,并对实际成像过程中影响系统成像的探测器位置、背光源的大小等参量进行了模拟分析。结果表明,探测器位置的微小变化对成像系统的相对放大率影响较小;背光源越小,成像系统的空间分辨率越高。该成像系统具有很好的空间分辨率,系统性能稳定可靠。     

机动飞行条件下前斜SAR分辨率分析

在机动飞行的前斜合成孔径雷达(SAR)系统中,成像的几何构型随时间显著变化,传统的分辨率分析方法不适用于这种情况.为了描述该系统下的分辨率特性,提出了一种基于分辨椭圆的计算不同几何构型下的前斜SAR分辨率的方法,通过评估分辨椭圆面积找到目标识别最优位置.仿真结果表明,该方法适用于不同飞行参数和几何构型条件下的机动飞行的前斜SAR分辨率分析.     

Highly Enantioselective Reactions of Configurationally Labile Epimeric Diamine Complexes of Lithiated S‐Benzyl Thiocarbamates

Substitution reactions that employ primary‐carbamoyl‐protected arylmethanethiols are described. The enantiodetermining step was found to occur in the post‐deprotonation step as a dynamic thermodynamic resolution with a chiral bis(oxazoline) ligand. The configurationally labile lithium complexes were trapped with various electrophiles to yield different substitution products in good to excellent yields and enantiomeric excesses. The absolute configurations of the substitution products were determined, and the stereochemical pathway of the substitution reaction was elucidated for different classes of electrophiles. The temperature‐dependent epimerization process was monitored by ¹H and ⁶Li NMR spectroscopy.     

Thermogravimetric analysis of wheatleyite Na<Subscript>2</Subscript>Cu<Superscript>2+</Superscript>(C<Subscript>2</Subscript>O<Subscript>4</Subscript>)<Subscript>2</Subscript>·2H<Subscript>2</Subscript>O

Evidence for the existence of primitive life forms such as lichens and fungi can be based upon the formation of oxalates. These oxalates form as a film like deposit on rocks and other host matrices. The anhydrous oxalate mineral moolooite CuC₂O₄ as the natural copper(II) oxalate mineral is a classic example. Another example of a natural oxalate is the mineral wheatleyite Na₂Cu²⁺(C₂O₄)₂·2H₂O. High resolution thermogravimetry coupled to evolved gas mass spectrometry shows decomposition of wheatleyite at 255°C. Two higher temperature mass losses are observed at 324 and 349°C. Higher temperature mass losses are observed at 819, 833 and 857°C. These mass losses as confirmed by mass spectrometry are attributed to the decomposition of tennerite CuO. In comparison the thermal decomposition of moolooite takes place at 260°C. Evolved gas mass spectrometry for moolooite shows the gas lost at this temperature is carbon dioxide. No water evolution was observed, thus indicating the moolooite is the anhydrous copper(II) oxalate as compared to the synthetic compound which is the dihydrate.     

Asymmetric dehydration of β-hydroxy esters and application to the syntheses of flavane derivatives

Catalytic asymmetric dehydration of β-aryl or alkyl substituted β-hydroxy esters via kinetic resolution has been investigated. A brief survey of 10 different chiral ligands is conducted to examine the effects of chiral ligand structure on selectivity of the dehydration. The kinetic resolution of a variety of rac-β-hydroxy tert-butyl esters in the presence of prolinol chiral ligand 2 and BrZnCH₂CO₂-t-Bu can provide highly enantioenriched β-hydroxy esters 14-21 with selectivity factors ranging from 11 to 66. Also, application of this asymmetric synthetic methodology to the preparation of enantioenriched flavane derivatives 25-29 is demonstrated.