Physico-chemical characterization of the fibre/matrix interaction in polyethylene fibre/epoxy matrix composites

The interphase in polyethylene fibre/epoxy matrix composites is studied with FT-IR microspectroscopy using a set-up to investigate the matrix as close to the fibre as a few μm or less. It is shown that moisture present on the fibre surface is able to influence the polymerization reaction of the epoxy/anhydride matrix in an irreversible manner. This effect is enhanced for composites from the more hydrophilic polyvinylalcohol fibre. The fibre/matrix interaction in these thermoplastic fibre composites is also studied with DSC through the characterization of the fibre melting. A decreased 'DSC interaction parameter' is found if the composition of the interphase is changed by moisture. For a composite with an epoxy/amine matrix, on the other hand, the DSC interaction parameter is unaffected by moisture from the fibre surface.     

Interfacial interaction in carbon fiber/thermoplastic composites

This work was undertaken in order to increase the understanding of the mechanism responsible for fiber/matrix interaction in carbon fiber/thermoplastic composite. From results of previous study on carbon fiber/PEEK composite, which suggested that the formation of the fiber/ matrix interaction was primarily related to a chemisorption mechanism, a study was done of the conditions required to obtain efficient fiber/matrix interaction in PA-12 and PP/carbon fiber composites. The interest in studying carbon fiber composite based on PP and PA-12 was that these two matrices are very different in terms of reactivity, polyamide having many more reactive groups than polypropylene. As expected, due to the non-reactive chemical structure of the polypropylene, fiber/matrix interaction in carbon fiber/PP composite occurred only when the matrix was thermally degraded, i.e. when the composite was molded at high temperature or under long residence time at the melt temperature. For the carbon fiber/PA-12 composite, strong fiber/matrix interaction occurred readily at relatively low molding temperature, i.e. well before thermal degradation of the matrix. It was also found that the short beam shear strength in these composites seems to evolve with molding temperature, and a maximum interfacial strength was observed at a molding temperature corresponding to the thermal degradation of the matrix. This indicates that although matrix degradation often results in strong reduction in the composite performance, some matrix degradation can be beneficial in terms of interfacial mechanical properties. Finally, this work demonstrated that while the formation of fiber/matrix interaction seems to be primarily related to a chemisorption mechanism, the contribution of interphase crystallinity to the interfacial strength is not negligible. In fact, interfacial crystallinity was found to be essential to ensure optimum interfacial strength.     

内屏蔽铁路数字信号电缆的设计与制造

主要介绍了内屏蔽铁路数字信号电缆的设计、生产工艺要点，并结合生产实践讨论了如何进行质量控制。     

A fibre microbuckling model for predicting the notched compressive strength of composite sandwich panels

Cohesive-zone models have been successfully applied to predicting the damage from notches in engineering materials loaded intension. They have also been used to determine the growth of fibre microbuckling from a hole in a composite laminate under compression. The usual strategy is to replace the in elastic deformation associated with plasticity or microbuckling with a line crack and to assume some form of stress-displacement bridging law across the crack faces. This paper examines recent published experimental data for notched glass-fibre epoxy/honey comb sand wich panels loaded in uniaxial compression. A plastic fibre kinking analysis and a linear softening cohesive-zone model are used for the prediction of the unnotched and open-hole compressive strength and the theoretical results are found to be in a good agreement with experimental data. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 43, No. 1, pp. 73–84, January–February, 2007.     

地下管道和光缆信息系统的设计与实现

研究了VC 环境下Mapinfo、MapX嵌入式系统实现技术，采用改进的Dijktra算法，实现了地下管道、光缆信息系统的设计，提出了一个实用的、具有线路测量优化功能的城市地下管道、光缆信息管理方案。并结合宁波大学校园进行了系统实现。     

Synthesis of poly(1.4.-benzamide) in solutions of randomly coiled polymers

The polycondensation of p-aminobenzoic acid by the use of triphenylphospine and hexachloroethane is described. One way to obtain a mixed solution of rigid rod and flexible coil polymers is the polycondensation of the rigid chains in a solution of a flexible polymer matrix. Results on matrix polycondensation of poly(p-benzamide) in solutions of poly(methyl methacrylate), poly(methyl methacrylate-co-styrene), polystyrene and polyacrylonitrile are reported. It is shown that there exists an interrelation between the phase behavior of the mixed polymer solutions and the influence of the matrix polymer on the synthesis of poly(1.4.-benzamide). The ternary phase diagrams of the rigid rod/flexible coil polymer solutions were determined.     

Design of Microstrip Antennas with Composite Laminates Considering Their Structural Rigidity

Two types of conformal load-bearing antenna structures (CLAS) were designed with microwave composite laminates and Nomex honeycomb cores to secure both the structural rigidity and a good electrical performance. One was a 4 × 8 array for the synthetic-aperture radar (SAR) system and the other was a 5 × 2 array for the wireless local-area network (LAN) system. The design was based on a wide bandwidth, high polarization purity, low losses, and high structural rigidity. The design, fabrication, and structural/electrical performances of the antenna structures were studied. Their flexural behavior was examined by three-point bending, impact, and buckling tests. The electrical measurements were in a good agreement with simulation results. The complex antenna structures obtained have good flexural characteristics. The design of this antenna structure is extended to give a useful guide for sandwich panel manufacturers as well as antenna designers.     

中国光纤光缆产业的历史、现状与前景

近年来国产光纤的市场份额正逐步上升,但国内光纤生产企业在原材料上受国外制约较大,光纤预制棒严重依赖进口,而且国内光纤光缆产业联系松散,在5家光纤光缆一体化企业中,仅有两家拥有完整产业链。中国正式加入WTO后,国内光纤光缆企业的整合在所难免,他们应积极进行产业升级,形成多个具有完整产业链的大集团。     

分支光纤的接续施工法

本介绍了日本电力公司开发的一项新的分支光纤的接续施工法。     

高级数字电视广播系统传输方案

作为高清晰度电视总体组在数字电视传输技术研究方面的组成部分，介绍一种由浙江大学、上海交通大学和西安电子科技大学共同提出并开发的高级数字电视广播系统（Advanced Digital Television Broadcasting System,ADTB)的传输方案。该方案在功能和性能上超越现有的国外数字电视标准，能够在使用民用级调谐器的前提下，实现大容量广播数据的稳定的无线固定、便携和移动接收，支持单频网络和同频道转发，包含高效的数字有线广播传输模式，易于兼容国外标准。这是我国数字电视广播标准理想的侯选方案之一。