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141.
高钠煤中钠的赋存形态研究 《燃料化学学报》2017,45(10):1172-1177
以高钠煤为研究对象,采用X射线衍射(XRD)、扫描电子显微镜(SEM)、红外光谱仪(FT-IR)傅里叶分析手段相结合的方法研究了煤中钠的赋存形态及其含量分布。结果表明,大多数煤中钠主要是以水溶性钠为主,有机钠次之,不溶性钠含量较低。水溶性钠主要是以钠硝石(NaNO_3)、岩盐(NaCl)和水合离子(Na·xH_2O)形式存在;有机钠主要是以羧基钠(-COONa)形式存在;不溶性钠主要是以钠长石(Na AlSi_3O_8)形式存在。 相似文献
142.
Wenfen Zhang Yongming Zhang Guangrui Zhang Xin Ba Shaige Xia Wuduo Zhao Dan Yin Shusheng Zhang 《Journal of separation science》2019,42(7):1374-1383
A new water‐soluble tetra‐proline‐modified calix[4]arene‐bonded silica stationary phase was prepared straightforwardly by an indirect method and characterized by elemental analysis, energy dispersive Spectrometry, solid‐state 13C NMR spectroscopy, Fourier‐transform infrared spectroscopy, and thermogravimetric analysis. Due to the simultaneous introduction of polar tetra‐proline and nonpolar calix[4]arene, the developed column possessing a double retention mode of reverse‐phase liquid chromatography and hydrophilic interaction liquid chromatography. A series of hydrophobic and hydrophilic test samples, including nucleosides and nucleotides, amines, monosubstituted benzenes, chiral compounds, and phenols, were used to evaluate the developed stationary phase. A rapid separation capability, high separation efficiency, and selectivity were achieved based on the multiple interactions between solutes and tetra‐proline‐modified calix[4]arene‐bonded silica stationary phase. Moreover, the developed stationary phase was further used to detect and separate hexamethylenetetramine in rice flour. All the results indicated the potential merits of the developed stationary phase for simultaneous separation of complex hydrophobic and hydrophilic samples with high selectivity. 相似文献
143.
Direct thermally induced reactions between rare earth metals (Ln = Y,Ce, Dy, Ho, and Er) activated by Hg metal and 3,5‐diphenylpyrazole (Ph2pzH) or 3,5‐di‐tert‐butylpyrazole (tBu2pzH) yielded either homoleptic complexes [Lnn(R2pz)3n] or a heteroleptic complex [Ln(Ph2pz)3(Ph2pzH)2] From Ph2pzH, [Ce3(Ph2pz)9], [Dy2(Ph2pz)6], [Ho2(Ph2pz)6], and [Y(Ph2pz)3(Ph2pzH)2] were isolated. The first has a bowed trinuclear Ce3 backbone with two η2 pyrazolate ligands on the terminal metal atoms and one on the middle, and bridging by both μ‐η2:η2 and μ‐η2:η5 ligands between the terminal and the central Ce atoms. Although both the Dy and Ho complexes are dinuclear, the former has the rare μ‐η2:η1 bridging whilst the latter has μ‐η2:η2 bridging. Thus the dysprosium complex is seven‐coordinate and the holmium is eight‐coordinate, in contrast to any correlation with Ln3+ ionic radii, and the series has a remarkable structural discontinuity. The heteroleptic Y complex is eight coordinate with three chelating Ph2pz and two transoid unidentate Ph2pzH ligands. From tBu2pzH, dimeric [Ln2(tBu2pz)4] (Ln = Ce, Er) were isolated and are isomorphous with eight coordinate Ln atoms ligated by two chelating terminal tBu2pz and two μ‐η2:η2 tBu2pz donor groups. They are also isomorphous with previously reported La, Nd, Yb, and Lu complexes. 相似文献
144.
Colligative properties of dilute solutions are the basic contents for chemistry, chemical engineering and biomedicine majors. The teaching model of multidimensional interact takes teachers as the leader and students as the main body. Through the multi-dimensional interaction among teachers and students, students and groups, students' interest in learning, strong sense of cooperation and independent learning ability can be cultivated. This paper introduces the implementation process of the multi-dimensional interactive teaching mode of "colligative properties of dilute solutions", which includes clarifying the purpose of interaction, constructing learning groups, raising interactive questions, launching interactive activities and implementing interactive evaluation, etc. Multi-dimensional teaching goals can be achieved through group explorations, group presentations and group discussions. 相似文献
145.
以高校基础化学实验"从海带中提取碘""三草酸合铁(Ⅲ)酸钾的制备"为例,分别探讨了微视频技术在化学基本操作实验和综合设计型实验中的具体应用;此外,举例说明利用Flash软件制作的虚拟微视频可以在仪器分析实验中清晰地再现仪器真实操作中的每一个步骤,弥补了学生在实验前无法实际操作仪器的不足。实践证明,微视频技术的应用,丰富了基础化学实验教学模式,增强了学生自主学习的能力和动手能力,提高了实验成功率和实验教学效果。 相似文献
146.
Qianying Sheng Wenqing Zhang Yan Wang Yi Zhao Haiyan Liu Junhong Qian Bo Zhang Qing Wang Ping Hu 《大学化学》1986,36(1):2002027-0
In order to solve the issues of traditional teaching methods in the undergraduate basic theory course, the blended learning mode was put forward by taking analytical chemistry as an example. With concept of student-centered, personalized teaching, together with assistant means, was introduced to achieve the breakthrough in solving the problems. We hope to reinforce the adaptability and targeting of the course teaching. 相似文献
147.
Xiang Pu Hanguang Wang Ping Zou Guangtu Wang Guizhou Yue Kuan Liu Li Cheng Juhua Feng Huixian Zhang Qianming Huang Hanbing Rao 《大学化学》1986,36(1):2002053-0
The crop science of Sichuan Agricultural University is an authorized first-class discipline. As the strategic supporting department for innovative talent cultivation in agriculture and forestry major, we are facing a long-term challenge in reforming the teaching mode for basic course-organic chemistry and cultivating talented students with solid basic knowledge and strong sense of innovation. Herein a thorough survey was performing to establish the executable teaching programs for this course during the "Double-First Class Universities Plan" period. A multidimensional teaching resource library for organic chemistry course was also constructed. The new classroom teaching mode "Interest cultivation-Creative thought development-Autonomous and Cooperative learning", along with a stepwise practice teaching mode "Foundation skills-Integrated application-Innovative trial" was proposed and practiced among thirty-five majors including agriculture, forestry and veterinary, to improve the quality for innovative talent cultivation and support our first-class discipline construction. This research could probably serve as a reference for congeneric agricultural university. 相似文献
148.
Raman phonon spectroscopy has been used to study photodimerization reaction inp-chloro cinnamic acid (pCCA) crystal. The β-form of the crystal yields the 4,4′-dichloro-β-truxinic acid dimer. Six distinct low frequency phonon
bands are observed in thepCCA monomer crystal. On reaction progress, these bands show a monotonic shift to lower frequencies and broaden out. Finally,
in the dimer crystal the phonon spectrum shows two weak broad bands. These results suggest that the reaction is homogeneous
in the initial stages and, as the product concentration increases, the lattice becomes highly disordered. The reactant and
the product were characterised by infrared and Raman spectroscopy. The disappearance of aliphatic C=C bond stretching vibration
and appearance of cyclobutane ring deformation and cyclobutane ring-breathing vibrations on reaction confirm photodimerization
by cyclobutane ring formation. The large Stoke's shift between the absorption and emission band suggest strong exciton-phonon
coupling in the monomer lattice. This reaction seems to be phonon-mediated. 相似文献
149.
150.
“奇妙的化学世界”是天津师范大学面向全校非化学专业的本科生开设的一门通识选修课。课程主要采用启发式教学模式、案例式教学模式、互动式教学模式等相结合的混合式教学模式,涉及当今活跃的科研领域和生活实际。课程采用多种方式如图片展示、教学辅助视频、小组讨论、调查问卷等,调动学生的积极性和主动性,使学生在较为轻松的状态下掌握课程内容。此外,力求做到集知识性、实用性、趣味性于一体,避免了化学专业课程中的复杂多变的化学结构描述。 相似文献