全文获取类型
收费全文 | 18963篇 |
免费 | 3914篇 |
国内免费 | 1801篇 |
专业分类
化学 | 10530篇 |
晶体学 | 125篇 |
力学 | 673篇 |
综合类 | 124篇 |
数学 | 1918篇 |
物理学 | 5720篇 |
无线电 | 5588篇 |
出版年
2024年 | 61篇 |
2023年 | 323篇 |
2022年 | 420篇 |
2021年 | 598篇 |
2020年 | 755篇 |
2019年 | 675篇 |
2018年 | 578篇 |
2017年 | 678篇 |
2016年 | 1023篇 |
2015年 | 1054篇 |
2014年 | 1294篇 |
2013年 | 1772篇 |
2012年 | 1408篇 |
2011年 | 1412篇 |
2010年 | 1161篇 |
2009年 | 1235篇 |
2008年 | 1351篇 |
2007年 | 1398篇 |
2006年 | 1208篇 |
2005年 | 1083篇 |
2004年 | 873篇 |
2003年 | 775篇 |
2002年 | 525篇 |
2001年 | 479篇 |
2000年 | 399篇 |
1999年 | 360篇 |
1998年 | 290篇 |
1997年 | 248篇 |
1996年 | 175篇 |
1995年 | 182篇 |
1994年 | 139篇 |
1993年 | 119篇 |
1992年 | 83篇 |
1991年 | 72篇 |
1990年 | 60篇 |
1989年 | 55篇 |
1988年 | 59篇 |
1987年 | 36篇 |
1986年 | 36篇 |
1985年 | 44篇 |
1984年 | 31篇 |
1983年 | 13篇 |
1982年 | 25篇 |
1981年 | 24篇 |
1980年 | 17篇 |
1979年 | 14篇 |
1978年 | 11篇 |
1977年 | 13篇 |
1974年 | 8篇 |
1973年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 609 毫秒
991.
992.
1,1,2,2,3,3,4‐Heptafluorocyclopentane (F7A) has considerable potential to be a new halon replacement due to its environmental friendliness and low‐toxicity. However, the reaction processes of F7A with hydroxyl and hydrogen free radicals, which are of great importance for investigating its fire suppression mechanisms, are still unclear. In this paper, ab inito and density functional theory are used to deduce the possible reaction pathways for the reactions of F7A with hydroxyl and hydrogen free radicals at the CCSD/cc‐pVDZ//B3LYP/6‐311++G (d,p) level of theory. Two distinct reaction pathways including ten elementary reaction channels for F7A with hydroxyl free radical, and five distinct reaction pathways including twenty elementary reaction channels for F7A with hydrogen free radical are investigated. The geometries, vibrational frequencies and reaction energy barriers are also determined. Based on the calculated results, the possible reaction mechanisms are proposed and discussed. The most feasible reaction channel for F7A with hydroxyl free radical is that leads to CH(OH)CH2(CF2)3+·F, and the most feasible reaction channel for F7A with hydrogen free radical is that leads to (CF2)3CH2CH·+HF. The study is helpful to further study its fire suppression mechanisms and promote it to be a new generation of halon replacement. 相似文献
993.
UV-Vis spectrum and the third-order nonlinear optical properties of the chiral camphor-derived β-diketonate have been studied at the B3LYP/6-31G* level. The results showed that the introduction of electron-drawing group-CF3 and-C3F7 on β-diketonate made the strongest absorption peak red-shift and the lowest energy absorption blue-shied. Introduction of-OC2H5 on the benzene or pyridine ring made the lowest energy absorption blue-shift. When the-C2H3 was introduced on the benzene or pyridine ring, the lowest energy absorption was red-shifted. Introduction of electron-donating group on β-diketonate can enlarge their nonlinear optical properties. On the contrary, the introduction of electron-drawing group dropped it down. 相似文献
994.
Pure and Mn-doped NaTaO3 nanoparticles were synthesized by a simple hydro- thermal method. XRD and XPS results suggested that manganese ions were successfully doped into the NaTaO3 crystalline in Mn2+ state. UV-vis diffuse reflectance spectra revealed the obvious red-shift in the series of manganese doped NaTaO3 nanoparticles, resulting in a decrease in the band gap of NaTaO3 with the increase of Mn2+ doping concentration. The photo-degradation experiment indicated that manganese doped NaTaO3 showed good photocatalytic performance and methylene blue(MB) degradation is improved with lower doping concentration of manganese ions under visible light. The simulation of energy band structure by density functional theory unfolded that the substitution of Ta5+ ions by Mn2+ ions resulted in an intermediate band(IB) below the bottom of the conduction band(CB), which was mainly attributed to the state of Mn 3d. 相似文献
995.
Density functional theory calculations have been performed to study the interaction of small silver clusters, Ag2 ~Ag9, with HCN. The adsorption of HCN on-top site of the silver cluster, among various possible sites, is energetically preferred. The adsorption energies of HCN on the silver clusters reach a local maximum at n = 4, which is only about 0.450 eV, indicating that the adsorbed HCN molecule is weakly perturbed. The adsorbed C–N and C–H stretching frequencies are blue- and red-shifted compared with the values of free HCN, respectively. 相似文献
996.
用密度泛函理论优化了三苯甲烷(1)和一系列三(4-硝基苯基)甲烷衍生物2,3和4的几何结构,并计算了其红外光谱和拉曼光谱;通过与实验光谱的对比,对实验光谱中的谱峰进行了指认,并从理论上纠正了部分对3和4红外光谱谱峰不合适的实验指认;同时预测了2,3和4的拉曼光谱.结果表明,几种化合物的振动光谱计算结果与相应的实验结果吻合良好;且化合物2,3和4的拉曼光谱具有相似性. 相似文献
997.
Bingqing Lin Xi Wu Prof. Dr. Lin Xie Yongqiang Kang Prof. Dr. Hongda Du Prof. Dr. Feiyu Kang Prof. Dr. Jia Li Prof. Dr. Lin Gan 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(46):20528-20532
Resolving interstitial hydrogen atoms at the surfaces and interfaces is crucial for understanding the mechanical and physicochemical properties of metal hydrides. Although palladium (Pd) hydrides hold important applications in hydrogen storage and electrocatalysis, the atomic position of interstitial hydrogen at Pd hydride near surfaces still remains undetermined. We report the first direct imaging of subsurface hydrogen atoms absorbed in Pd nanoparticles by using differentiated and integrated differential phase contrast within an aberration-corrected scanning transmission electron microscope. In contrast to the well-established octahedral interstitial sites for hydrogen in the bulk, subsurface hydrogen atoms are directly identified to occupy the tetrahedral interstices. DFT calculations show that the amount and the occupation type of subsurface hydrogen atoms play an indispensable role in fine-tuning the electronic structure and associated chemical reactivity of the Pd surface. 相似文献
998.
Hossein Nourmohamadi Valeh Aghazadeh Mehdi D. Esrafili 《Surface and interface analysis : SIA》2020,52(3):110-118
Pyrite acts as a catalyst in the mineral processing, and the speed of ferric ion reduction and mineral decomposition increases with increasing cathodic points. In this study, the ferric ion interaction on the (100) and (110) surfaces of pyrite was studied using the density functional theory calculations. The analysis of stability, density of states, and electron density were performed to understand the interaction between the ferric ion and pyrite surfaces. The results showed that pyrite surface is chemically active and tends to absorb ferric ion between two surface sulfur atoms. The hyperconjugation between the 3d orbital of ferric ion and the 3p or 3d orbitals of surface atoms provides the conditions for the Fe3+ ion adsorption. The molecular orbital (MO) and electron density analyses indicate that the 3p orbitals of S atoms play a more important role in bonds formations relative to the 3d orbitals. The (110) surface is more active, and the adsorption energy is larger than that of surface (100), which is the result of decreased cation coordination and the presence of sulfur at the surface. Subsequently, the interaction of the Fe2+ ion, as product of Fe3+ ion reduction and its competitor for adsorption, on the surfaces was studied. The Fe2 + ion adsorbs stronger at the surface of (110), and the adsorption energies at (100) and (110) surfaces were obtained as −24 and −47 kcal/mol, respectively. In general, the Fe3+ ion is a stronger oxidizing agent than Fe2+ on pyrite surfaces. 相似文献
999.
Chong Ding Yihe Zhang Na Zhang Xinke Wang Qi Wei Youpeng Zhang 《Surface and interface analysis : SIA》2020,52(10):645-655
In this study, surface modification of coal gangue (CG) was performed with titanate coupling agent 201 (isopropyl tri(dioctylpyrophosphate) titanate), and the effects of surface modifier on mechanical properties and thermal stability of high-density polyethylene filled with CG (HDPE/CG) and high-density polyethylene filled with modified CG (HDPE/mCG) composites were investigated. The coupling agent was successfully grafted on CG surface through chemical reaction according to the analyses of Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS), and the coupling agent can effectively enhance the hydrophobicity of surface that was verified by water contact angle beyond 90° of modified CG sample. With the introduction of coupling agent, some enhancements of tensile strength, flexural strength, and impact strength were observed in HDPE/mCG compared with HDPE/CG, due to the improved compatibility between mCG fillers and matrix. The increased storage modulus and decreased loss factor of HDPE/mCG composite further confirm the stronger interface adhesion after modification. Moreover, it is found that titanate coupling agent 201 can improve the thermal stability of HDPE/mCG composite to some extent. 相似文献
1000.
Unfilled natural rubber compounds composed of conventional (CV), semi-efficient (SEV), efficient (EV) and sulfur donor (SD) vulcanization systems were heat aged to promote sulfur reversion. Rheometry, hardness, strain-strain characteristics including Mooney-Rivlin analysis, equilibrium solvent swell and Double Quantum (DQ) Nuclear Magnetic Resonance (NMR) were used to monitor crosslink density changes. A loss of crosslink density was observed by rheometry, C1, equilibrium swelling and by DQ NMR as a function of cure extent. No chain scission reactions were operating in the time/temperature conditions used. All crosslink distributions were unimodal and the network homogeneity followed the order of EV > SD > SEV > CV. The crosslink distribution narrowed during the curing process for the CV and SEV systems. Non-oxidative maturation reactions were advantageous in promoting a more random distribution of crosslinks in the polymer matrix. 相似文献