Theoretical study of the potential energy curves of the diatomic radicals MeIIX. III. Application to MgCl,CaF and CaCl radicals and some preliminary remarks

The series of calculations of the potential energy curves of the diatomic radicals Me_IIX (Me_II = second group metal, X = halogen), has been extended to MgCl, CaF and CaCl. The calculations have been performed according to a stepwise procedure, outlined in previous works. The presently available results allow comparisons for the first members of the series.     

“In-situ” monitoring activation and reaction on very absorbing catalytic solid by DRIFT spectrometer

The FTIR's well-known advantages are strongly shown by the use of new infrared techniques. Both advantages of FTIR and diffuse reflectance make this coupling particularly important in the development of infrared studies.Sensitivity and rapidity of the FTIR spectrometer, added to the extremely simple preparation of the sample, allowed by diffuse reflectance attachment, give a high performing tool particularly in catalysis in the view of understanding the catalytic reactions mechanisms. We have chosen thein-situ study of two catalytic systems active in selective hydrogénation of dienes: a copper-chromium oxide and Cu/Al₂O₃ .     

An investigation of the reliability of the Galerkin-Petrov method

The Galerkin-Petrov method is applied to the determination of the ground state energy of the beryllium atom. The basis set of the coordinate subspace consists of correlated wavefunctions of the combined configuration-interaction-Hylleraas type. The basis set of the projective subspace is of the configuration-interaction type. The usefulness of a previously proposed way of characterization of pairs of subspaces has been further confirmed. Experience in constructing close pairs of subspaces gathered in the case of two-electron systems is used for the larger system. Two methods for constructing pairs of subspaces are used in the calculations.     

Polarographic determination of microgram amounts of thorium(IV)

Summary Among various salt solutions tested 0.01 N LiNO₃ proved to be most suitable as supporting electrolyte for the polarographic determination of microgram amounts of thorium. Well-developed, maxima-free and reproducible waves were obtained for a Th(IV) concentration range of 1.4–23 g/ml. The minimum detectable limit of the element was 0.8 g/ml. No relationship has been found between Th(IV) and H⁺-ion concentration.

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Polarographische Bestimmung von Mikrogramm-Mengen Thorium(IV)

Zusammenfassung Von verschiedenen untersuchten Salzlösungen hat sich als Grundelektrolyt 0,01 N LiNO₃-Lösung als am günstigsten erwiesen. Es wurden damit gut ausgebildete, maxima-freie und reproduzierbare Stufen für einen Konzentrationsbereich von 1,4–23 g Th(IV)/ml erhalten. Die Nachweisgrenze betrug 0,8 g Th(IV) in 1 ml Lösung. Es wurde kein Zusammenhang zwischen Thoriumkonzentration und H⁺-Ionenkonzentration nachgewiesen.

     

Coupling constants in the direct configuration interaction method

A general algorithm of evaluation of the coefficients of molecular integrals (coupling constants) appearing in the direct configuration interaction method is derived. The configurations are assumed to be spin-adapted antisymmetrized products of orthonormal orbitals. No limitation is imposed either upon the reference state (the number of the singly occupied orbitals may be arbitrary) or upon the excitation multiplicity.     

An Efficient Architecture for a Lifted 2D Biorthogonal DWT

This paper presents a new algorithm for a 2D non-separable lifted bi-orthogonal wavelet transform. The algorithm is derived by factoring complementary pairs of wavelet transform 2D filters. The results are efficient architectures for real time signal processing, which do not require transpose memory for the 2D processing of data. The proposed architecture exploits in place implementation, inherit from the algorithm, and can take advantage of both vertical and horizontal parallelism in the direct implementation. The processing in our architecture is scheduled by carefully pipelining the lifted steps, which allows for up to four times faster processing than the direct implementation. The proposed architecture operates at high speed, consumes low power and has reduced computational complexity as compared to previously published filter and lifted based bi-orthogonal wavelet architectures.M. Alam (Student) is currently M.Sc. student in the Department of Electrical and Computer Engineering at University of Calgary. His research interest includes VLSI signal processing. He is recipient of iCORE International Graduate Scholarship.Wael Badawy (Ph.D. 00, M.Sc 98, 97; B.Sc. 94) is an associate professor in the Department of Electrical and Computer Engineering. He holds an adjunct professor in the Department of Mechanical Engineering, University of Alberta.Dr. Badawys research interests are in the areas of: Microelectronics, VLSI architectures for video applications with low-bit rate applications, digital video processing, low power design methodologies, and VLSI prototyping. His research involves designing new models, techniques, algorithms, architectures and low power prototype for novel system and consumer products. Dr. Badawy authored and co-authored more than 100 peer reviewed Journal and Conference papers and about 30 technical reports. He is the Guest Editor for the special issue on System on Chip for Real-Time Applications in the Canadian Journal on Electrical and Computer Engineering, the Technical Chair for the 2002 International Workshop on SoC for real-time applications, and a technical reviewer in several IEEE journals and conferences. He is currently a member of the IEEE-CAS Technical Committee on Communication. Dr. Badawy was honored with the 2002 Petro Canada Young Innovator Award, 2001 Micralyne Microsystems Design Award and the 1998 Upsilon Pi Epsilon Honor Society and IEEE Computer Society Award for Academic Excellence in Computer Disciplines. He is currently the Chairman of the Canadian Advisor Committee (CAC) and Head of the Canadian Delegation on ISO/IEC/JTC1/SC6 Telecommunications and Information Exchange Between Systems. Member, The Canadian Advisory Committee for the Standards Council of Canada-Subcommittee 29: Coding of Audio, Picture Multimedia and Hypermedia Information, and Canadian Delegate, The ISO/IEC MPEG standard committee. He is a voting Member on the VSI Alliance. He is also the Chair of the IEEE-Southern Alberta Society-Computer Chapter.Vassil S. Dimitrov was born in Plovdiv, Bulgaria, in 1964. He received his Ph.D. degree in mathematics in 1995 from the Mathematical Institute of the Bulgarian Academy of Sciences. Since then, he has spent two years as a postdocral fellow at the VLSI Research Group, University of Windsor, Canada, one year as a research scientist at the Reliable Software Technology Corporation, Virginia, USA, one year as a chief research scientist at the Signal Processing and Computer Technology Laboratory, Helsinki University of Technology, Finland, and one year as an Associate Professor at the University of Windsor, Canada. Since July 2001 he has held the position of Associate Professor at the Department of Electrical and Computer Engineering, University of Calgary, Canada. His main interests are in the area of number theoretic algorithms, computational complexity, cryptography, optimization theory, fast algorithms for digital signal processing and related topics. Dr. Dimitrov is a member of the New York Academy of Sciences.Graham Jullien (Fellow IEEE) was educated in the United Kingdom, receiving degrees, in Electrical Engineering, from the Universities of Loughborough, Birmingham and Aston (Ph.D., 1969). He was a student engineer and data processing engineer at English Electric Computers, UK, from 1961 to 1966, and a visiting senior research engineer at the Central Research Laboratories of EMI Ltd., UK, from 1975 to 1976. From 1969 until 2000 he was with the Department of Electrical and Computer Engineering at the University of Windsor, Ontario, Canada, where he held the rank of University Professor and was the Director of the VLSI Research Group. Since January 2001, he has been with the Department of Electrical and Computer Engineering at the University of Calgary, where he holds the iCORE Research Chair in Advanced Technology Information Processing Systems. He is a member of the Board of Directors of the Canadian Microelectronics Corporation (CMC) and is a member of the Steering Committee and Board of Directors of the Micronet Network of Centres of Excellence. He has published widely in the fields of Digital Signal Processing, Computer Arithmetic, Neural Networks and VLSI Systems, and teaches courses in related areas. He has served on the technical committees of many international conferences; he currently serves on the Editorial Board of the Journal of VLSI Signal Processing; and is a past Associate Editor of the IEEE Transactions on Computers. He hosted and was program co-chair of the 11th IEEE Symposium on Computer Arithmetic, was program chair for the 8th Great Lakes Symposium on VLSI, and was the technical program chair for the 1999 Asilomar Conference on Signals, Systems and Computers. He is general chair for the 2003 Asilomar Conference and general co-chair of the International Workshop on System-on-Chip for Real-Time Systems, Calgary, Alberta 2003.     

Synthesis, Spectral and Structural Study of N-[1-(N,N,N′,N′-Tetramethylphosphoramidoyl)- 1H-Benzimidazol-2-yl]-Propionimidic Ethyl Ether

The preparation of N-[1-(N,N,N,N-tetramethylphosphoramidoyl)-1H-benzimidazol-2-yl]-proponimidic ethyl ester 2 has been achieved by the reaction of N-(1H-benzimidazol-2-yl)-proponimidic acid ethyl ester 1 with N,N,N,N-tetramethylchlorophosphoramide. The structure of compound 2 has been determined by X-ray diffraction. The results of (¹H, ¹³C, ³¹P) NMR, IR, EI-MS spectral data are consistent with those obtained from the X-ray diffraction. The compound crystallizes in the triclinic system, following the EsZ conformation. In the crystal, there are two weak C3–H3s1 and C15–H15sO1 intermolecular hydrogen bonds.