Polymerization behaviors of racemic and chiral amphiphilic monomers in organized bilayer membranes of lamellar liquid crystalline phase

A racemic amphiphilic monomer, n‐dodecyl glyceryl itaconate (DGI), forms bilayer membranes in water in the presence of small amount of ionic cosurfactant and shows iridescent color. A chiral DGI, S‐DGI, also shows an iridescent property, but with a rather red shift in the color, which can be ascribed to the increased packing density of the monomer in the bilayer membranes. Chrial DGI has a more compact packing density than racemic one owing to closer distance between the monomer molecules; the conversion rate, however, is slower than that of racemic one when H₂O₂ is used as an initiator. When the initiator is changed to an amphiphilic one, 4‐(2‐hydroxyethoxy) phenyl‐(2‐hydroxy‐2‐propyl) ketone (Irgacure 2959), the chiral DGI shows even a little faster conversion rate than that of racemic one. The NMR chemical shift results of protons in benzene ring show that the molecules of Irgacure 2959 insert into the bilayer membranes. The molecular weights of the corresponding polymers prove that the initiation by H₂O₂ is restricted compared to that by Irgacure 2959. It is concluded that the decelerated polymerization behavior of chiral DGI initiated by H₂O₂ is a result of limited diffusion of the initiator into the lamellar bilayer structures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4891–4900, 2007     

HLS直线加速器调制器系统设计与改造

介绍了合肥同步辐射光源速调管调制器改造项目.在新的设计中采用了开关型恒流PFN充电电源,计算了充电参数,建立了主放电回路的仿真模型,重点分析了电路中反向电压问题,依据仿真结果及分析设计了反向保护电路.给出了运行中的主要波形.最后介绍了新的调制器控制系统.     

Synthesis of chiral 2′,3′-pyranone(pyrrolidinone)-fused tryptamines

Chiral pyrano- and pyrrolidino-fused tryptamines were prepared by a diasteroselective trimolecular condensation between indole, Garner's aldehyde and Meldrum's acid, followed by selective functional group transformations.     

风力发电机组变速恒频控制系统研究

全面介绍了一种最新应用于风力发电中的新型电机—无刷双馈电机，并分析了这种新型电机作变速恒频运行的原理并对这种电机进行了动态特性仿真研究，给出了形式简洁的控制方程和易于实现的控制方案。     

Use of a range scaling method to determine alanine/water stopping power ratios

A phantom composed of alanine dosimeter material has been constructed and depth–dose measurements made in a 10 MeV electron beam. The results have demonstrated the feasibility of using relative depth–dose measurements to determine stopping power ratios in materials of dosimetric interest. Experimental stopping power ratios for alanine dosimeter material and water agreed with the data of ICRU Report 37 within the uncertainty of the experiment (±1.2% at a 95% confidence level).     

32位MIPS微处理器中乘法器的设计和实现

在Booth算法的基础上,结合MIPS 4KC微处理器中的流水线结构和乘法器的工作过程,提出了一种改进的Booth乘法器的设计方法,并采用全制定方法实现,用这种方法实现的乘法器单元具有面积小、单元电路可重复性好、版图设计工作量小、功耗低等特点.     

SoC低功耗设计中的DVS技术

随着系统芯片(SoC)集成更多的功能并采用更先进的工艺,它所面临的高性能与低功耗的矛盾越来越突出.动态电压调整(DVS)技术可以在不影响处理器性能的前提下,通过性能预测软件根据处理器的繁忙程度调整处理器的工作电压和工作频率,达到降低芯片功耗的目的.文中讨论了DVS技术降低功耗的可能性,介绍了如何利用两种不同的DVS技术让处理器根据当前的工作负荷运行在不同的性能水平上,以节省不必要的功耗.     

250W带功率因数校正整流电源模块的研制

功率因数校正技术越来越成为电源行业研究的热点。文中介绍了适用于雷达等设备的250W带功率因数校正整流电源模块的设计，分析了其中升压电感器设计、主开关管保护、控制电路消振、散热设计和表面贴装等关键技术，完成了实验研究，获得了满意的试验结果。     

大功率开关电源的设计与实现

介绍了开关电源设计中需要考虑的几个基本问题,包括频率的确定、最大占孔比Dm的确定、逆变变压器的设计和开关功率管的选择,并以一种1 kW的PWM大功率半桥式开关电源为例,详细介绍实际的开关电源设计方案,并给出了实验结果.     

CDMA系统中联合功率控制、波束赋形与多用户检测

应用功率控制、波束赋形和多用户检测可以有效地消除和减少CDMA系统中的干扰。本文结合波束赋形和多用户检测的特性，提出一种应用波束赋形增益和多用户相关矩阵的解相关算法。基于算法的复杂性，提出一种区分聚集用户进行多用户检测的的算法。由于波束赋形能够消减主瓣波束之外的多用户干扰，对聚集移动台采用解相关检测达到减少运算量和消除多用户干扰的目的。对算法进行了仿真分析，证明了本算法的优越性。