Two-dimensional-growth small molecular hole-transporting layer by ultrasonic spray coating for organic light-emitting devices

Two-dimensional-growth small molecular organic thin film with high quality is fabricated by ultrasonic spray coating technology (USC) from the toluene solution of 4,4′,4″-tris (carbazol-9-yl) triphenylamine (TCTA). In comparison to the vacuum thermal evaporation (VTE) TCTA film, the USC-TCTA film obtained from liquid-phase solution possesses more uniform surface topography. The differences between the USC-TCTA and the VTE-TCTA in optical property, electrical property and formation mechanism are also studied in detail. Besides, to evaluate the hole transport and electron blocking ability of USC-TCTA film, the organic light-emitting devices (OLEDs) employing USC-TCTA film as hole transport layer are fabricated successfully. Additionally, the green OLEDs based on USC-TCTA film perform as well as the ones with VTE-TCTA film in current density, luminance, efficiency and color stability, and show even better tolerance to high bias voltage.     

TFT-LCD器件Al电极TFT特性研究

本文对Mo/Al/Mo作为TFT-LCD器件源/漏极的TFT特性进行了研究。与单层Mo相比,存在沟道界面粗糙,I_(off)偏大问题,通过优化膜层结构,改善界面状态,得到了平整的沟道界面和良好的TFT特性。增加Bottom Mo的厚度,可以有效减少Al的渗透,防止Al-Si化合物的形成,得到界面平整的沟道;N~+刻蚀后SF6处理对特性影响不大,增加刻蚀时间可以使I_(on)和I_(off)同时降低;PVX沉积前处理气体N_2+NH_3与H_2区别不大,都可以减少沟道缺陷,而增加H_2处理时间会增强等离子的轰击作用,减少了沟道表面Al-Si化合物,但处理时间过长可能会使沟道缺陷增加;采用bottom Mo加厚,N~+刻蚀以及PVX沉积前处理等最优条件,可以得到沟道界面良好,TFT特性与单层Mo相当的TFT器件。     

Construction of pseudorandom binary sequences using additive characters over GF(2 k )

In a series of papers Mauduit and Sárközy (partly with coauthors) studied finite pseudorandom binary sequences and they constructed sequences with strong pseudorandom properties. In these constructions fields with prime order were used. In this paper a new construction is presented, which is based on finite fields of order 2 ^k .     

Integrals of equivariant forms and a Gauss-Bonnet theorem for constructible sheaves

The Berline-Vergne integral localization formula for equivariantly closed forms ([N. Berline, M. Vergne, Classes caractéristiques équivariantes. Formules de localisation en cohomologie équivariante, C. R. Acad. Sci. Paris 295 (1982) 539-541], Theorem 7.11 in [N. Berline, E. Getzler, M. Vergne, Heat Kernels and Dirac Operators, Springer-Verlag, 1992]) is well-known and requires the acting Lie group to be compact. In this article, we extend this result to real reductive Lie groups G_R.As an application of this generalization, we prove an analogue of the Gauss-Bonnet theorem for constructible sheaves. If F is a G_R-equivariant sheaf on a complex projective manifold M, then the Euler characteristic of M with respect to F

     

Mechanistic studies on the formation of glycosidase-substrate and glycosidase-inhibitor covalent intermediates

Glycoside hydrolases catalyze the breaking of the glycosidic bond. This type of bond fashioned between two monosaccharides is very stable, and the polymers created are involved in multiple cellular processes, being crucial to life. In this article, computational methods were used to study the first step of the mechanism of reaction of retaining glycoside hydrolases in atomic detail. The systems modeled included a simplified reaction center and a small substrate/inhibitor. Using DFT calculations we were able to corroborate and provide molecular-level detail to the dissociative mechanism proposed in the literature. The role of the hydrogen bridge between the nucleophile and the C(2)--OH group of the ring was also investigated. Therefore, we concluded that this bridge is responsible for lowering the activation barrier by 5.1 kcal mol(-1) with functional BB1K/6-311+G(2d,2p), and the absence of the bridge explains, at least in part, the inhibitory effect of fluoro-substituted glycosides in the -2 position. The hydrogen bridge could also be involved in favoring the ring distortion verified in the transition state, and the dissociative character of the reaction mechanism. Using the NBO method, point atomic charges were calculated. In the transition state, the positive charge generated in the sugar ring is distributed nearly equally between the anomeric carbon and the ring oxygen, through a partial double bond involving the two atoms.     

一种土壤剖面CO2气体通量的测试方法

设计和研制了一套土壤剖面CO2气体通量原位测试的方法和装置,该方法和装置可用于土壤剖面不同深度（0～200 cm）土壤CO2气体通量的观测、不同深度土壤层CO2气体存储量的估测、土地利用/土地覆盖变化引起土壤CO2气体释放量变化的测算和估计,以及植被或地力恢复速率的评价等。     

Photoluminescence and Electroluminescence of Organic Light Emitting Diodes Based on Tris‐(8‐quinolinolato) Aluminum Nanoparticles

利用共沉淀方法制备出平均粒径为20nm的有机物8-羟基喹啉铝纳米粒子,8-羟基喹啉铝纳米粒子呈球形且粒度不随老化时间的增加而改变。本文研究了8-羟基喹啉铝纳米粒子的光致发光及基于8-羟基喹啉铝纳米粒子制作的电致发光器件的电致发光特性。8-羟基喹啉铝形成纳米粒子后,其光致发光及电致发光发射光谱的谱峰均出现蓝移。随着驱动电压的增加,器件中8-羟基喹啉铝纳米粒子的发射峰逐渐红移。在驱动电压为16伏时,8-羟基喹啉铝纳米粒子器件的最大亮度达600cd/m²,电流密度为150mA/cm^-2时,器件的发光效率为0.19cd/A。基于8-羟基喹啉铝纳米粒子器件的发射光谱证实了AlQ₃纳米粒子具有量子尺寸效应的存在,这为有机纳米电致发光器件的研究开辟了一条新的研究路线,同时也为那些传统的有机材料如有机分子晶体的基础研究探索出新的研究方向。     

The cycle structure of two rows in a random Latin square

Let L be chosen uniformly at random from among the latin squares of order n ≥ 4 and let r,s be arbitrary distinct rows of L. We study the distribution of σ_r,s, the permutation of the symbols of L which maps r to s. We show that for any constant c > 0, the following events hold with probability 1 ‐ o(1) as n → ∞: (i) σ_r,s has more than (log n)^1?c cycles, (ii) σ_r,s has fewer than 9 cycles, (iii) L has fewer than n^5/2 intercalates (latin subsquares of order 2). We also show that the probability that σ_r,s is an even permutation lies in an interval and the probability that it has a single cycle lies in [2n^‐2,2n^‐2/3]. Indeed, we show that almost all derangements have similar probability (within a factor of n^3/2) of occurring as σ_r,s as they do if chosen uniformly at random from among all derangements of {1,2,…,n}. We conjecture that σ_r,s shares the asymptotic distribution of a random derangement. Finally, we give computational data on the cycle structure of latin squares of orders n ≤ 11. © 2008 Wiley Periodicals, Inc. Random Struct. Alg., 2008     

A note on the -th power mean of character sums over the quarter interval

We obtain an asymptotic formula for the -th power mean of odd primitive character sums over the interval .

     

新型煤矿供电网防越级跳闸保护装置的研制

以煤矿供电网越级跳闸现象为研究对象,在分析电流纵联差动保护、级联闭锁工作原理和防越级跳闸保护逻辑的基础上,介绍了一种煤矿供电网防越级跳闸保护装置的研制过程。保护装置以32位ARM处理器MB9BF618S为控制核心,可以实时检测供电网输电线路的工作状态,对输电线路故障进行有效的保护。文中主要叙述了保护装置的总体结构,给出了电流/电压输入模块、开关量输入/输出模块和通信模块的设计方案。该保护装置具有结构简单、操作方便、可靠性高等特点,能够满足煤矿供电网防越级跳闸保护的要求,具有较高的应用价值。