全文获取类型
收费全文 | 13190篇 |
免费 | 2594篇 |
国内免费 | 890篇 |
专业分类
化学 | 813篇 |
晶体学 | 52篇 |
力学 | 757篇 |
综合类 | 111篇 |
数学 | 1097篇 |
物理学 | 4062篇 |
无线电 | 9782篇 |
出版年
2024年 | 72篇 |
2023年 | 139篇 |
2022年 | 288篇 |
2021年 | 321篇 |
2020年 | 376篇 |
2019年 | 326篇 |
2018年 | 343篇 |
2017年 | 471篇 |
2016年 | 525篇 |
2015年 | 591篇 |
2014年 | 978篇 |
2013年 | 963篇 |
2012年 | 1026篇 |
2011年 | 1101篇 |
2010年 | 887篇 |
2009年 | 767篇 |
2008年 | 892篇 |
2007年 | 970篇 |
2006年 | 939篇 |
2005年 | 719篇 |
2004年 | 601篇 |
2003年 | 560篇 |
2002年 | 428篇 |
2001年 | 417篇 |
2000年 | 324篇 |
1999年 | 266篇 |
1998年 | 237篇 |
1997年 | 185篇 |
1996年 | 172篇 |
1995年 | 148篇 |
1994年 | 115篇 |
1993年 | 80篇 |
1992年 | 81篇 |
1991年 | 89篇 |
1990年 | 36篇 |
1989年 | 31篇 |
1988年 | 27篇 |
1987年 | 27篇 |
1986年 | 18篇 |
1985年 | 21篇 |
1984年 | 23篇 |
1983年 | 11篇 |
1982年 | 10篇 |
1981年 | 15篇 |
1980年 | 16篇 |
1979年 | 8篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 8篇 |
1971年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 11 毫秒
91.
92.
用量子化学原理,CIS/6-31+G(d,p)方法研究了2-甲基环戊酮离子前6个激发态的解离过程,通过虚频的振动分析,计算其可能产物,寻求2-甲基环戊酮离子的解离通道和解离产物. 相似文献
93.
We present a simple model to rationalize the effects of environment on the reaction barrier frequencies derived from free energy profiles. These frequencies are relevant in deviations of a rate constant from its transition state theory value and in determining which environmental dynamics participate in the reaction. In particular, this simple model can be used to understand the changes in the reaction barrier frequencies of an enzymatic catalyzed reaction and the corresponding uncatalyzed process in aqueous solution, a change which has implications for dynamical environmental effects on the enzymatic reaction. Two possible cases are analyzed, in which the polarity (charge separation/localization) of the reacting system increases or decreases as the reaction advances. A simple modeling of the environment′s effects allows the explanation of an unusual “inverse” effect on the reaction frequencies, that is, a free energy barrier lowering accompanied by an increase of the reaction frequency, a behavior observed in some enzymes. The model predictions are successfully compared with results from full simulations for four different enzyme reactions. 相似文献
94.
Kirill F. Sheberstov Eduard Sistaré Guardiola Damien Jeannerat 《Magnetic resonance in chemistry : MRC》2020,58(5):376-389
The fundamental concept of phase discussed in this tutorial aimed at providing students with an explanation of the delays and processing parameters they may find in nuclear magnetic resonance (NMR) pulse programs. We consider the phase of radio-frequency pulses, receiver, and magnetization and how all these parameters are related to phases and offsets of signals in spectra. The impact of the off-resonance effect on the phase of the magnetization is discussed before presenting an overview of how adjustment of the time reference of the free induction decay avoids first-order correction of the phase of spectra. The main objective of this tutorial is to show how the relative phase of a pulse and the receiver can be used to change the reference frequency along direct and indirect dimensions of NMR experiments. Unusual of phase incrementation with non-90° angles will be illustrated on one- and two-dimensional NMR spectra. 相似文献
95.
A. Amari A. Walther M. Huang M. Afzelius B. Lauritzen H. de Riedmatten 《Journal of luminescence》2010,130(9):1579-1585
We present an efficient photon-echo experiment based on atomic frequency combs [Phys. Rev. A 79 (2009) 052329]. Echoes containing an energy of up to 35% of that of the input pulse are observed in a Pr3+-doped Y2SiO5 crystal. This material allows for the precise spectral holeburning needed to make a sharp and highly absorbing comb structure. We compare our results with a simple theoretical model with satisfactory agreement. Our results show that atomic frequency combs has the potential for high-efficiency storage of single photons as required in future long-distance communication based on quantum repeaters. 相似文献
96.
刘奉岭 《化学物理学报(中文版)》2003,16(2):103-106
采用C60分子之间相互作用势的Kihra形式,研究了立方面心C60晶体的晶格振动问题,得到了质心振动沿[111]、[110]及[100]方向的声子散射圆频率分布曲线及C60晶格振动频率的态密度分布.采用所得到的C60晶格振动频率的态密度分布,计算了晶体C60在298 K时的等压热容,所得数值与实验值相符. 相似文献
97.
将直链烷烃分子看成是一个多自由度振动系统,用机械振动理论中的传递矩阵法计算了C2~C32直链烷烃的固有频率,分析了固有频率随化合物结构单元的变化规律.发现各阶固有频率中的基频与直链烷烃的结构型性质呈现出优良的相关性,用各阶固有频率之和表示的总频与直链烷烃的加和型性质也呈现出优艮的相关性,将两者组合后还能够反映直链烷烃的凝聚型性质的变化规律.在此基础上建立了直链烷烃的物化性能与基频和总频之间的定量相关模型.用该模型对直链烷烃的电离能、沸点、临界温度、临界压力、密度、粘度、标准生成焓、离子标准生成焓、常压热容、折光指数等10种不同类型性质的实验数据进行回归分析,相关系数均大于0.999. 相似文献
98.
99.
通过钌的络合物前驱体和硝酸钡的共浸渍制备的Ru Ba K/AC催化剂氨合成转化效率高,其氨合成转化频率在0.87~1.30 s-1之间,与氯化钌制备的Ru/AC催化剂相比,其转化频率提高幅度在26%~88%。共浸渍法制备的催化剂氨合成转化效率高,其主要原因可能是共浸渍法制备的催化剂钌粒子粒径分布区间较窄,易形成更多的活性位;钌表面氢的吸附受到抑制,氮更易活化,因而催化效率更高。 相似文献
100.
AbstractHerein the bioaccessibility of Mn, Cu, Zn, Cd, and Pb, selected from essential and toxic elements, was determined in commercially sold vegetable purees intended for infant and toddler consumption. Chemical fractionation studies using water, acetone, diethyl ether, chloroform:methanol, and n-hexane were employed to predict the importance of the protein and lipid parts of a matrix to assess the bioaccessibility data. In addition, in-vitro gastrointestinal digestion was performed to determine the bioaccessibility of the elements using a five level, three factor central composite design (CCD) to maximize the elemental solubility. The total elemental concentrations in all of the fractions were determined by inductively coupled plasma – mass spectrometry (ICP-MS). Based on the consumption of one jar of vegetable/rice-based baby food, Zn was 1.3% of the recommended dietary allowance and Mn was 4.2% of the adequate intake level, while Cu was almost 100% of the adequate intake level. Additionally, Pb was always below the detection limit and Cd was sometimes under the detection limit for the percent bioaccessibility. However, in some samples, Cd was as high as 80% of the tolerable weekly intake level depending on the body weight. 相似文献