Entangled photon pairs must often be spatially separated for their subsequent manipulation in integrated quantum circuits. Separation that is both deterministic and universal can in principle be achieved through anti‐coalescent two‐photon quantum interference. However, such interference‐facilitated pair separation (IFPS) has not been extensively studied in the integrated setting, which has important implications on performance. This work provides a detailed review of IFPS and examines how integrated device dependencies such as dispersion impact separation fidelity and interference visibility. The analysis applies equally to both on‐chip and in‐fiber implementations. When coupler dispersion is present, the separation performance can depend on photon bandwidth, spectral entanglement and the dispersion. By design, reduction in the separation fidelity due to loss of non‐classical interference can be perfectly compensated for by classical wavelength demultiplexing effects. This work informs the design of devices for universal photon pair separation of states with tunable arbitrary properties.
Nonlinear wave mixing in mesoscopic silicon structures is a fundamental nonlinear process with broad impact and applications. Silicon nanowire waveguides, in particular, have large third‐order Kerr nonlinearity, enabling salient and abundant four‐wave‐mixing dynamics and functionalities. Besides the Kerr effect, in silicon waveguides two‐photon absorption generates high free‐carrier densities, with corresponding fifth‐order nonlinearity in the forms of free‐carrier dispersion and free‐carrier absorption. However, whether these fifth‐order free‐carrier nonlinear effects can lead to six‐wave‐mixing dynamics still remains an open question until now. Here we report the demonstration of free‐carrier‐induced six‐wave mixing in silicon nanowires. Unique features, including inverse detuning dependence of six‐wave‐mixing efficiency and its higher sensitivity to pump power, are originally observed and verified by analytical prediction and numerical modeling. Additionally, asymmetric sideband generation is observed for different laser detunings, resulting from the phase‐sensitive interactions between free‐carrier six‐wave‐mixing and Kerr four‐wave‐mixing dynamics. These discoveries provide a new path for nonlinear multi‐wave interactions in nanoscale platforms.
A novel biocompatible polymer was prepared by grafting the derivate of β ‐cyclodextrin (6‐SH ‐β ‐CD ) onto poly(3,4‐dihydroxycinnamic acid) (PDHCA ) via Michael addition. PDHCA ‐β ‐CD nanoparticles were prepared by the self‐assembly of amphiphilic PDHCA ‐β ‐CD polymer with N,N ‐dimethylformamide (DMF ) as good solvent and water as poor solvent. The PDHCA ‐β ‐CD nanoparticles were monodispersed with spherical morphology as shown in the scanning electron microscopic (SEM ) images in accord with the result of dynamic light scattering (DLS ) measurement. The size of the nanoparticles could be controlled from 60 to 180 nm by tuning the grafting degree (GD ) of PDHCA ‐β ‐CD polymer and also significantly influenced by the amount of water used during the process. These as‐prepared nanoparticles were stable without any significant change in the particle size after six‐months’ storage and even after being irradiated by UV at λ >280 nm for hours. The formation mechanism of PDHCA ‐β ‐CD nanoparticles was explored. The content of doxorubicin (DOX ) loaded onto the nanoparticles was up to 39% with relatively high loading efficiency (approximately 78.8% of initial DOX introduced was loaded). In vitro release studies suggested that DOX released slowly from PDHCA ‐β ‐CD nanoparticles. These features strongly support the potential of developing PDHCA ‐β ‐CD nanoparticles as carriers for the controlled delivery of drug. 相似文献
In all known Group 5 transition‐metal dichalcogenide monolayers (MLs), the metal centers carry a spin, and their ground‐state phases are either metallic or semiconducting with indirect band gaps. Here, on grounds of first‐principles calculations, we report that the Haeckelite polytypes 1 S ‐NbX2 (X=S, Se, Te) are diamagnetic direct‐band‐gap semiconductors even though the Nb atoms are in the 4+ oxidation state. In contrast, 1 S ‐VX2 MLs are antiferromagnetically coupled indirect‐band‐gap semiconductors. The 1 S phases are thermodynamically and dynamically stable but of slightly higher energy than their 1 H and 1 T ML counterparts. 1 S ‐NbX2 MLs are excellent candidates for optoelectronic applications owing to their small band gaps (between 0.5 and 1 eV). Moreover, 1 S ‐NbS2 shows a particularly high hole mobility of 2.68×103 cm2 V−1 s−1, which is significantly higher than that of MoS2 and comparable to that of WSe2. 相似文献
Capillary isoelectric focusing hyphenated with mass spectrometry detection, following the sequential injection of the carrier ampholytes and the sample zone, is highly efficient for the characterization of proteins. The main advantage of the sequential injection protocol is that ampholytes, with pH ranges, which are not supposed to cover the isoelectric points of the sample components, can be used for separation. The method then allows online mass spectrometry detection of separated analytes either in the absence (substances that have left the pH gradient) or in the presence of low‐level ampholytes (substances that are migrating within the pH gradient). The appearance of the substances within, or outside the pH gradient depends on, e.g., the composition of the ampholytes (broad or narrow pH range) or on the composition of electrolyte solutions. The experiments performed in coated capillaries (with polyvinyl alcohol or with polyacrylamide) show that the amount and the injection length of the ampholytes influence the length of the pH gradient formed in the capillary. 相似文献
This study investigates young students’ writing in connection to mathematical problem solving. Students’ written communication has traditionally been used by mathematics teachers in the assessment of students’ mathematical knowledge. This study rests on the notion that this writing represents a particular activity which requires a complex set of resources. In order to help students develop their writing, teachers need to have a thorough knowledge of mathematical writing and its distinctive features. The study aims to add to the body of knowledge about writing in school mathematics by investigating young students’ mathematical writing from a communicational, rather than mathematical, perspective. A basic inventory of the communicational choices, that are identifiable across a sample of 519 mathematical texts, produced by 9–12 year old students, is created. The texts have been analysed with multimodal discourse analysis, and the findings suggest diversity in students’ use of images, words, numerals, symbols and layout to organize their texts and to represent their problem-solving process along with an answer to the problem. The inventory and the indication that students have different ideas on how, what, for whom and why they should be writing, can be used by teachers to initiate discussions of what may constitute good communication. 相似文献
We study the response of a single-degree-of-freedom system with cubic nonlinearities to an amplitude-modulated excitation whose carrier frequency is much higher than the natural frequency of the system. The only restriction on the amplitude modulation is that it contain frequencies much lower than the carrier frequency of the excitation. We apply the theory to different types of amplitude modulation and find that resonant excitation of the system may occur under some conditions. 相似文献