全文获取类型
收费全文 | 22418篇 |
免费 | 1712篇 |
国内免费 | 1397篇 |
专业分类
化学 | 7381篇 |
晶体学 | 91篇 |
力学 | 1761篇 |
综合类 | 218篇 |
数学 | 4138篇 |
物理学 | 5562篇 |
无线电 | 6376篇 |
出版年
2024年 | 60篇 |
2023年 | 278篇 |
2022年 | 513篇 |
2021年 | 630篇 |
2020年 | 605篇 |
2019年 | 517篇 |
2018年 | 450篇 |
2017年 | 622篇 |
2016年 | 761篇 |
2015年 | 726篇 |
2014年 | 1047篇 |
2013年 | 1402篇 |
2012年 | 1099篇 |
2011年 | 1134篇 |
2010年 | 950篇 |
2009年 | 1218篇 |
2008年 | 1306篇 |
2007年 | 1391篇 |
2006年 | 1223篇 |
2005年 | 960篇 |
2004年 | 896篇 |
2003年 | 870篇 |
2002年 | 808篇 |
2001年 | 651篇 |
2000年 | 592篇 |
1999年 | 515篇 |
1998年 | 480篇 |
1997年 | 343篇 |
1996年 | 279篇 |
1995年 | 271篇 |
1994年 | 231篇 |
1993年 | 230篇 |
1992年 | 294篇 |
1991年 | 173篇 |
1990年 | 132篇 |
1989年 | 99篇 |
1988年 | 113篇 |
1987年 | 109篇 |
1986年 | 85篇 |
1985年 | 91篇 |
1984年 | 88篇 |
1983年 | 46篇 |
1982年 | 103篇 |
1981年 | 171篇 |
1980年 | 185篇 |
1979年 | 189篇 |
1978年 | 172篇 |
1977年 | 105篇 |
1976年 | 111篇 |
1973年 | 79篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
Saad S. M. Hassan 《Fresenius' Journal of Analytical Chemistry》1973,266(4):272-274
Summary The solid state ion-selective chloride and bromide electrodes are used for the microdetermination of chlorine and bromine in organic compounds. After combustion in an oxygen-filled flask, potentiometric titration with silver nitrate at pH 5–7 in presence of 50% dioxan is carried out. Results accurate to ±0.3% absolute are obtained with some partially and highly halogenated compounds.
Mikrobestimmung von Chlor und Brom in einigen organischen Verbindungen mit Hilfe von ionenselektiven Elektroden
Zusammenfassung Chlorid- und bromidselektive Festkörperelektroden wurden zur Chlor- und Brombestimmung in teilweise bzw. hochhalogenierten organischen Verbindungen benutzt. Nach Verbrennung im Sauerstoffkolben erfolgt eine potentiometrische Titration mit Silbernitrat bei pH 5–7 in Gegenwart von 50% Dioxan. Die erhaltenen Ergebnisse sind auf ±0,3 % genau.相似文献
42.
X. Y. Li G. J. Wang J. G. Sun Y. T. Zheng B. Yan H. T. Xie X. Wang 《Chromatographia》2007,65(1-2):13-18
To support preclinical pharmacokinetic investigation of 1-[4-[2-(4-bromobenzene-sulfonaminoethyl)phenylsufonyl]-3-(trans-4-methylcyclohexyl)urea
(G004), a rapid, sensitive and specific high-performance liquid chromatography–electrospray ionization mass spectrometry (LC–ESI-MS)
method was developed and validated. Glibenclamide was employed as internal standard. After liquid–liquid extraction the analyte
was analyzed on a Kromasil C18 column (150 × 2.0 mm i.d.) with a mobile phase consisted of acetonitrile–water (0.05% acetic acid), 30:70 (v/v). The flow
rate was 0.2 mL min−1. Detection was performed on a quadrupole mass spectrometer using an electrospray ionization interface and the selected-ion
monitoring (SIM) mode. The retention time was about 3.5 and 4.2 min for Glibenclamide and G004, respectively. The assay was
linear over the concentration range of 2.0–500.0 ng mL−1. Extraction Recovery of G004 in rat plasma was more than 87%. The intra- and inter-assay precision was lower than 11.5% (CV).
This validated method was successfully applied to the pharmacokinetics of G004 in rats. 相似文献
43.
Brendan Davis 《Journal of Electronic Testing》1994,5(2-3):157-169
A long and deep recession, coupled with continuous competitive pressure to reduce costs, is forcing many companies to review their test strategies. Testing costs have become a more significant proportion of the overall manufacturing cost even though manufacturing yields have increased dramatically over the past ten or twelve years. This causes attention to be focused on testing costs as a key source of cost reduction. The increased use of DFT and the integration of design and test are very positive moves towards controlling testing costs but other methods employed can often backfire. The increased use of low priced testers is one such method. The pressure to reduce costs, higher process yields and exhortations that testing adds no value can lead the test engineering manager to take the cheap route. In reality this can often turn out to be an expensive decision. The only way to avoid expensive mistakes is to perform an economic analysis of the alternative courses of action. In most cases this is done, but not always in the right manner or with the necessary amount of detail to make the comparisons meaningful. This article discusses the need for effective cost analysis of test strategies and highlights some of the pitfalls. 相似文献
44.
Slawomir Pilarski 《Journal of Electronic Testing》1995,6(1):139-140
The analysis of aliasing probability presented in a recent article, Aliasing Properties of Circular MISRs [1], is based on an error model that cannot adequately represent real circuits. We show why conclusions presented in [1] should not be used in practice, substantiating our claim with experimental results.This work was supported in part by grants from the Natural Sciences and Engineering Research Council of Canada and in part by the British Columbia Advanced Systems Institute 相似文献
45.
H. Reul 《Fresenius' Journal of Analytical Chemistry》1977,285(2):126
46.
J. G. van Raaphorst A. W. van Weers H. M. Haremaker 《Fresenius' Journal of Analytical Chemistry》1978,293(5):401-403
Summary The loss of cadmium, antimony and silver during dry ashing of marine weeds, mussels and shrimps was studied with the aid of radioactive tracers. Except for antimony all biological material was labelled by uptake of the radioactive tracers by the organisms while still alive. At an ashing temperature of 500° C and below no significant loss by volatilization of these elements occurs. The results obtained at higher temperatures with cadmium show that the behaviour of this element may depend on the composition of the organic material. Retention on the wall of quartz crucibles did not cause serious losses.
Über den Verlust an Cadmium, Antimon und Silber bei der Trockenveraschung von biologischem Material
Zusammenfassung Mit Hilfe radioaktiver Tracer wurden die Verluste an Cadmium, Antimon und Silber bei der Trockenveraschung von Seetang, Muscheln und Krabben untersucht. Mit Ausnahme von Antimon wurden alle Materialien mit den Tracern durch Aufnahme im lebenden Zustand markiert. Bei Veraschungstemperaturen von 500° C und darunter konnten keine signifikanten Verluste durch Verflüchtigung der Elemente festgestellt werden. Das Verhalten von Cadmium bei höheren Temperaturen kann von der Zusammensetzung des organischen Materials abhängen. Verluste durch Haften an der Wand des Quarztiegels waren unbedeutend.相似文献
47.
The convection in atmosphere discussed in ref. [1] is rigorously treated by considering the variation of environmental temperature
with the height. This represents an example of applications of the elementary catastrophe theory in Hamiltonian systems. 相似文献
48.
Summary An isotope dilution method for the determination of rare earth impurities in uranium has been developed and Ce, Nd, Sm, Eu and Gd have been determined in uranium oxide samples. The method involves isotopic dilution with enriched isotopes of the rare earths being measured, followed by the separation of rare earths from uranium. A mass spectrometer with thermionic source was used to determine the relative isotopic abundances in each of these rare earths. All these five elements were analysed selectively by preferential evaporation technique. Trace concentrations down to parts per billion range can be measured with good sensitivity and accuracy.
Bestimmung von Verunreinigungen an Seltenen Erden in hochreinem Uran durch Isotopenverdünnungsanalyse
Zusammenfassung Eine Isotopenverdünnungsmethode wurde ausgearbeitet zur Bestimmung von Ce, Nd, Sm, Eu und Gd in Uranoxidproben. Das Verfahren umfaßt isotopische Verdünnung mit angereicherten Isotopen der zu bestimmenden Elemente und nachfolgende Abtrennung der Seltenen Erden von Uran. Die relativen Isotopenhäufigkeiten wurden mit Hilfe eines Massenspektrometers mit thermischer Ionenquelle bestimmt. Alle fünf Elemente wurden durch selektive Verdampfung analysiert. Spurenkonzentrationen bis herab zum ppb-Bereich konnten mit guter Empfindlichkeit und Genauigkeit erfaßt werden.相似文献
49.
一种新型的表面声波阻抗传感器及其在液相体系中的应用姚守拙,陈康,刘德忠,聂利华(湖南大学化学化工系,长沙,410082)关键词表面声波,阻抗传感器,液相应用表面声波传感器(SAWS)具有较高的灵敏度和检测精度,已广泛应用于气体微量组分分析、色谱检测和... 相似文献
50.
Summary Clenbuterol has been determined in urine by solidphase extraction on a C18 cartridge, diazotization of the eluate with nitrite, coupling of the diazonium ion with 1-(naphthyl)ethylenediamine, and
separation of the azo dye formed by HPLC with a C18 column and a micellar mobile phase containing 0.1 M sodium dodecyl sulphate, 12%n-butanol and 0.05 M citrate buffer, pH 3. Recoveries higher than 90% were obtained by mixing the samples with a 20% 0.2 M
NaOH before extraction. Limits of detection of 51 and 6.7 ng L−1 were obtained with spectrophotometric and thermal lens spectrometric detection, respectively; respective repeatabilities
were 3.1% (5 μg mL−1) and 5.6% (0.16 μg mL−1). 相似文献