全文获取类型
收费全文 | 9403篇 |
免费 | 2518篇 |
国内免费 | 1270篇 |
专业分类
化学 | 3482篇 |
晶体学 | 191篇 |
力学 | 186篇 |
综合类 | 51篇 |
数学 | 161篇 |
物理学 | 4595篇 |
无线电 | 4525篇 |
出版年
2024年 | 55篇 |
2023年 | 152篇 |
2022年 | 261篇 |
2021年 | 288篇 |
2020年 | 299篇 |
2019年 | 279篇 |
2018年 | 298篇 |
2017年 | 409篇 |
2016年 | 473篇 |
2015年 | 439篇 |
2014年 | 664篇 |
2013年 | 1101篇 |
2012年 | 778篇 |
2011年 | 803篇 |
2010年 | 638篇 |
2009年 | 614篇 |
2008年 | 643篇 |
2007年 | 689篇 |
2006年 | 611篇 |
2005年 | 574篇 |
2004年 | 518篇 |
2003年 | 459篇 |
2002年 | 445篇 |
2001年 | 280篇 |
2000年 | 262篇 |
1999年 | 224篇 |
1998年 | 171篇 |
1997年 | 134篇 |
1996年 | 111篇 |
1995年 | 91篇 |
1994年 | 94篇 |
1993年 | 48篇 |
1992年 | 52篇 |
1991年 | 54篇 |
1990年 | 31篇 |
1989年 | 31篇 |
1988年 | 16篇 |
1987年 | 14篇 |
1986年 | 10篇 |
1985年 | 12篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 12篇 |
1981年 | 11篇 |
1980年 | 10篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1973年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
131.
HU Rong TIAN Jinping & YIN Yingwu . College of Chemistry & Environment Protection Engineering Southwest University for Nationalities Chengdu China . TH-UNIS Insight Co. Ltd. Beijing China . Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology Ministry of Education Department of Chemistry Tsinghua University Beijing China 《中国科学B辑(英文版)》2006,49(4):351-356
The formation of peptides and then protein by small abiological molecules clusters such as amino acid is a key stage in the origin of life[1]. More and more ex- perimental results showed that phosphate plays an important role in the formation of biomolecules in prebiotic chemical evolution. The principal reservoirs of biochemical energy are phosphates (such as ATP). The peculiar role of phosphates in contemporary life might suggest its essential role in prebiotic energy conversion, syntheses … 相似文献
132.
微波辐射下LaNaY沸石的水热交换反应 总被引:8,自引:0,他引:8
报道微波辐射应用于NaY沸石与La(NO_3)_3溶液的离子交换反应,结果表明微波辐射可提高La ̄+的交换度,缩短交换时间。 相似文献
133.
134.
Fu-Ken Liu 《Analytica chimica acta》2005,528(2):249-254
This paper demonstrates that capillary electrophoresis (CE) can be employed for characterizing the sizes of nanometer-scale gold particles. We characterized the gold nanoparticles by effecting CE separation using a buffer of SDS (70 mM) and 3-cyclohexylamino-1-propanesulfonic acid (CAPS; 10 mM) at pH 11.0 and an applied voltage of 18 kV and obtained a linear relationship (R2 > 0.99) between electrophoretic mobilities and size for nanoparticles whose diameters fall in the regime from 5.0 ± 0.5 to 41.2 ± 3.3 nm; the relative standard deviations of these electrophoretic mobilities are <0.8%. We evaluated the feasibility of employing these separation conditions for the size characterization by of gold nanoparticle samples that were synthesized by a rapid microwave heating method. We confirmed that this CE method is a valid one for size characterization by comparing the results obtained by CE with those provided by scanning electron microscopy (SEM); a good correlation exists between these two techniques. Our results demonstrate that CE can be employed to accelerate the analysis of the sizes of nanomaterials. 相似文献
135.
Won Young Jung Byung Ho Noh Seung Hee Baek Gun-Dae Lee Seong Soo Park Seong-Soo Hong 《Reaction Kinetics and Catalysis Letters》2007,91(2):223-231
SBA-15 mesoporous material was prepared by microwave-hydrothermal method and was used as support in TiO2-loaded SBA-15 photocatalysts. The physical properties of these particles were investigated. We also examined the activity
of these samples as photocatalysts for the decomposition of orange II. Titania loaded on a silica matrix decreases the surface
area of the support as expected for TiO2 incorporation. For TiO2-loaded SBA-15 photocatalysts, the IR absorption at ∼960 cm−1 commonly accepted as the characteristic vibration of the Ti-O-Si bond. The photocatalytic activity increases with an increase
of the TiO2 loading. 相似文献
136.
CAI Shu-Hui LI Jun LIU Chun-WanFujian Institute of Research on the Structure of Matter Chinese Academy of Sciences State Key Laboratory of Structural Chemistry Fuzhou Fujian China 《中国化学》1994,12(5):385-391
The band structures of several analogous superconducting A-15 type solid compounds, Nb3X (X=Si, Ge, Sn, Pb), have been calculated by use of the tight-binding method within the Extended Huckel approximation (EHT). By analysis of their energy bands, densities of states and crystal orbital overlap populations, the dependence of the superconducting transition temperatures (Tc) on the electronic structures and bondings is qualitatively elucidated. 相似文献
137.
M. Katkevičs A. Kontijevskis I. Mutule E. Sūna 《Chemistry of Heterocyclic Compounds》2007,43(2):151-159
A 30-membered library of coumarins has been synthesized in a microwave-assisted Pechmann reaction using neat trifluoroacetic
acid both as an acidic reagent and a reaction medium. Alternatively, polymer-supported sulfonic acid Amberlyst-15 could also
be employed to facilitate the formation of coumarins. The use of a specially-built microwave synthesizer with liquid handling
tools rendered the automated synthesis of a coumarin library feasible.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 200–208, February, 2007. 相似文献
138.
HUA Guo-Pinga ZHU Xiao-Tongb ZHANG Jin-Pengb XU Jia-Ningb WANG Qianb JI Shun-Junc ZHANG Yongc TU Shu-Jiangb② a 《结构化学》2006,25(5):599-603
1 INTRODUCTION Various quinolone derivatives are known to dis- play interesting biological properties ranging from microbial activity to cytotoxicity[1]. They have been reported as antiviral (HIV-1)[2] and antitumor agents[3] as well as used as tubulin[4], topoisomerase[5] and thrombocyte inhibitors[6]. As a member of the quino- lone family, substituted N-phenyl-2-quinolones re-present the structural basis of many biologically active compounds, such as protein kinase inhibitors, immunodu… 相似文献
139.
改进的微波辅助无溶剂法提取薄荷和陈皮中的挥发油组分 总被引:1,自引:0,他引:1
An improved solvent free microwave extraction, in which a kind of microwave absorption medium (carbonyl iron powder) was used, was applied to the extraction of essential oil from dried menthol mint and orange peel without addition of any solvent and pretreatment. It took much less time of extraction (30 min) than microwave-assisted hydrodistillation (90 min) and conventional hydrodistillation (180 min). The kinds of chemical compositions in essential oil extracted by different methods were almost the same and such improved solvent free microwave extraction can be a feasible way in extraction of essential oil from dried plant materials. 相似文献
140.
A. M. Wrobel B. Lamontagne M. R. Wertheimer 《Plasma Chemistry and Plasma Processing》1988,8(3):315-329
We have investigated O2/CF4 plasma etching of five commercial polymers: polyimide, polyamide, polyethylene terephthalate, polycarbonate and cured epoxy resin. A new large-area microwave plasma apparatus has been used in this work, but the same apparatus can also be used as a capacitively coupled radiofrequency (13.56 MHz) discharge reactor. The effect of operating parameters such as pressure, etchant gas composition, excitation frequency and sample temperature upon etch kinetics has been examined. We have observed distinct maxima in the etch rate as functions of pressure and CF4 concentration. Activation, energies evaluated from the Arrhenius plots fall in the range 0.04-0.2 eV, in agreement with data in the literature. Dry etch susceptibility of a given polymer correlates strongly with the degree of unsaturation in the polymer's structure 相似文献