全文获取类型
收费全文 | 9401篇 |
免费 | 2522篇 |
国内免费 | 1268篇 |
专业分类
化学 | 3482篇 |
晶体学 | 191篇 |
力学 | 186篇 |
综合类 | 51篇 |
数学 | 161篇 |
物理学 | 4595篇 |
无线电 | 4525篇 |
出版年
2024年 | 55篇 |
2023年 | 152篇 |
2022年 | 261篇 |
2021年 | 288篇 |
2020年 | 299篇 |
2019年 | 279篇 |
2018年 | 298篇 |
2017年 | 409篇 |
2016年 | 473篇 |
2015年 | 439篇 |
2014年 | 664篇 |
2013年 | 1101篇 |
2012年 | 778篇 |
2011年 | 803篇 |
2010年 | 638篇 |
2009年 | 614篇 |
2008年 | 643篇 |
2007年 | 689篇 |
2006年 | 611篇 |
2005年 | 574篇 |
2004年 | 518篇 |
2003年 | 459篇 |
2002年 | 445篇 |
2001年 | 280篇 |
2000年 | 262篇 |
1999年 | 224篇 |
1998年 | 171篇 |
1997年 | 134篇 |
1996年 | 111篇 |
1995年 | 91篇 |
1994年 | 94篇 |
1993年 | 48篇 |
1992年 | 52篇 |
1991年 | 54篇 |
1990年 | 31篇 |
1989年 | 31篇 |
1988年 | 16篇 |
1987年 | 14篇 |
1986年 | 10篇 |
1985年 | 12篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 12篇 |
1981年 | 11篇 |
1980年 | 10篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1973年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
TU Shu-Jianga② WANG Qiana ZOU Xianga b SHI Fenga MIAO Chun-Baoa FANG Fanga XU Jia-Ninga a 《结构化学》2005,24(3):255-258
1 INTRODUCTION 1,4-Dihydropyridines (1,4-DHPs) are well-knowncompounds because of their pharmacological pro-perty as calcium channel modulators[1, . The che- 2]mical modifications, such as the introduction of dif-ferent substituents[3, or heteroatoms[5], of the DHP 4]ring have allowed the expansion of researches onthe structure-activity relationship to gain new in-sights into the molecular interactions at the receptorlevel. In fact, it is well established th… 相似文献
122.
123.
124.
Dr. Alexandra R. McNeill Dr. Rodrigo Martinez-Gazoni Prof. Roger J. Reeves Prof. Martin W. Allen Prof. Alison J. Downard 《Chemphyschem》2021,22(13):1344-1351
ZnO is a strong candidate for transparent electronic devices due to its wide band gap and earth-abundance, yet its practical use is limited by its surface metallicity arising from a surface electron accumulation layer (SEAL). The SEAL forms by hydroxylation of the surface under normal atmospheric conditions, and is present at all crystal faces of ZnO, although with differing hydroxyl structures. Multilayer aryl films grafted from aryldiazonium salts have previously been shown to decrease the downward bending at O-polar ZnO thin films, with Zn−O−C bonds anchoring the aryl films to the substrate. Herein we show that the Zn-polar (0001), O-polar (000 ), and non-polar m-plane (10 0) faces of ZnO single crystals, can also be successfully electrografted with nitrophenyl (NP) films. In all cases, X-ray photoelectron spectroscopy (XPS) measurements reveal that the downward surface band bending decreases after modification. XPS provides strong evidence for Zn−O−C bonding at each face. Electrochemical reduction of NP films on O-polar ZnO single crystals converts the film to a mainly aminophenyl layer, although with negligible further change in band bending. This contrasts with the large upward shifts in band bending caused by X-ray induced reduction. 相似文献
125.
U. K. Chakrabarti S. J. Pearton W. S. Hobson C. R. Abernathy 《Plasma Chemistry and Plasma Processing》1993,13(2):333-350
Vinyl iodide (C2H3I) microwave discharges with additions of H2 and Ar are found to provide faster etch rates than conventional CH4/H2/Ar discharges for InP, InGaAs, GaAs, and AlGaAs. This is a result of the relatively high volatilities of indium, gallium, and aluminum iodide species. The etched features are smooth and anisotropic over a wide range of do self-biases (–150 to –350 V), process pressures (1–20mTorr), and microwave powers (150–500 W). The polymer that forms on the mask during the plasma exposure can be readily removed in O2 discharges. Electron spectroscopy for chemical analysis (ESCA) showed that the etched surfaces are slightly deficient in the group V elements under most conditions, but changes to the optical properties of the semiconductors are minimal. No defects are visible by transmission electron microscopy (TEM) in GaAs or InP samples etched at dc biases –250 V. 相似文献
126.
FENG You-Jian JIA Run-Hong TU Shu-Jiang② ZHANG Xiao-Jin JIANG Bo ZHANG Yan ZHANG Jun-Yong 《结构化学》2005,24(12):1457-1461
1 INTRODUCTION aryl or methyl group to the nitrogen atom of these compounds leads to enhanced activities of fluo- A lot of natural and synthetic compounds con- rescence[7, . Since the pyridine scaffold is included 8] taining acridine skeletons display interesting biolo- in decahydroacridine-1,8-dione, a question is whether gical and physical activities[1]. Acridinedione, for the same modification on the nitrogen atom of de- example, has been identified as antimalarial and cahydroacridine-1… 相似文献
127.
128.
From the changes in energy band, density of state (DOS) and electronic structure calculated by the DFT/B3LYP method, the conductivity of carbon doped boron‐nitride nanotube (BNNT), which is formed by C‐C bond substituting B‐N bond, was discussed. The results indicate that the substitution will strengthen the conductivity of the tube, and its semi‐conductivity might be adjusted by controlling the substitution. 相似文献
129.
微波聚合制备单分散、超细聚甲基丙烯酸甲酯微球 总被引:9,自引:0,他引:9
在微波辐照下,通过甲基丙烯酸甲酯(MMA)的无乳化剂乳液聚合,制备出粒径单分散、超细聚甲基丙烯酸甲酯(PMMA)微球。微波显著缩短聚合诱导期,加快聚合反应,其部分原因是微波加快引发剂过硫酸钾(KPS)的分解。实验证明微波辐照下KPS的表观分解活化能(ED)由128.3kJ/mol降低到106.0kJ/mol。单体浓度是影响PMMA乳液粒子尺寸的主要因素,在[MMA]小于0.3mol/L时,平均粒径随单体浓度提高而线形增加;[MMA]为0.3~1.0mol/L时,平均粒径稳定在约200nm;之后随单体浓度进一步增加,乳液稳定性变差。引发剂浓度增加对平均粒径影响较小,但增大引发剂浓度可显著降低粒径分散度。选取[MMA]为0.23~0.3mol/L、[KPS]为3×10-3~6×10-3mol/L可以得到粒径200nm的单分散微球。以丙酮/水(体积比1/3)为反应介质,可制备出数均粒径45nm的PMMA纳米粒子。在体系中加入3.5×10-3mol/L的Cu2+,可制备出数均粒径67nm、单分散的PMMA纳米粒子。 相似文献
130.
Reactions in a Mixture of CH4 and CO2 under the Aciton of Microwave Discharge at Atmospheric Pressure
下载免费PDF全文
![点击此处可从《天然气化学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Reactions between CH4 and CO2 under the action of continuous microwave discharge at atmospheric pressure were studied in a special homemade reactor,The main products were CO and H2,while acetylene and ethylene were also found in the products.Experimental results show that conversions of CH4 and CO2 could be higher than 90% without the presence of any catalyst,Effects of CO2/CH4 molar ratio and total flow rate of the feed gas on the reaction were also investigated. 相似文献