全文获取类型
收费全文 | 13312篇 |
免费 | 1744篇 |
国内免费 | 692篇 |
专业分类
化学 | 4504篇 |
晶体学 | 88篇 |
力学 | 1708篇 |
综合类 | 105篇 |
数学 | 391篇 |
物理学 | 4663篇 |
无线电 | 4289篇 |
出版年
2024年 | 27篇 |
2023年 | 156篇 |
2022年 | 298篇 |
2021年 | 389篇 |
2020年 | 456篇 |
2019年 | 334篇 |
2018年 | 280篇 |
2017年 | 489篇 |
2016年 | 594篇 |
2015年 | 720篇 |
2014年 | 856篇 |
2013年 | 1507篇 |
2012年 | 970篇 |
2011年 | 952篇 |
2010年 | 672篇 |
2009年 | 721篇 |
2008年 | 667篇 |
2007年 | 712篇 |
2006年 | 636篇 |
2005年 | 538篇 |
2004年 | 542篇 |
2003年 | 448篇 |
2002年 | 353篇 |
2001年 | 314篇 |
2000年 | 255篇 |
1999年 | 202篇 |
1998年 | 222篇 |
1997年 | 188篇 |
1996年 | 177篇 |
1995年 | 174篇 |
1994年 | 137篇 |
1993年 | 139篇 |
1992年 | 101篇 |
1991年 | 84篇 |
1990年 | 61篇 |
1989年 | 57篇 |
1988年 | 65篇 |
1987年 | 37篇 |
1986年 | 37篇 |
1985年 | 37篇 |
1984年 | 29篇 |
1983年 | 8篇 |
1982年 | 29篇 |
1981年 | 22篇 |
1980年 | 7篇 |
1979年 | 18篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1973年 | 4篇 |
1972年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
981.
J. S. Schilling 《高压研究》2013,33(3):145-163
At ambient pressure there are 29 elemental superconductors in the periodic table, none of which is an alkali metal. The first alkali metal to become superconducting under high pressure is Cs followed years later by Li. Alkali metals are believed to be exemplary free-electron systems. The fact that an alkali metal becomes superconducting at all is surprising and is a result of the fact that under pressure it shows marked deviations from free-electron behaviour where, counterintuitively, bands narrow and gaps widen. For this reason the alkali metals are among the most interesting systems known to study in high-pressure experiments and superconductivity is one of their most fascinating properties. 相似文献
982.
Toshiaki Shirakawa Hajime Ichimura Isao Ikemoto 《Molecular Crystals and Liquid Crystals》2013,570(1-4):101-107
Pressure-volume isotherms for 4-(trans-4-butylcylohexyl)benzonitrile were measured by means of piston-cylinder method. This substance has a monotropic nematic phase at atmospheric pressure. But over a pressure, the nature of isotropic to nematic phase transition changed from monotropic to enantiotropic phase transition. It is the first observation in P-V-T experiments that the monotropic isotropic-nematic transition changes enantiotropic under pressure. 相似文献
983.
In this work, the experimental vapor pressures of four amines 1,2-bis(dimethylamino)ethane, 1-methylmorpholine, 1,2-bis(2-aminoethoxy)ethane and N-benzylethanolamine using a static apparatus are reported. The temperature range is comprised between 273.18 and 364.97 K and the pressure range between 0.782 Pa and 333 kPa. The molar enthalpies of vaporization at 298.15 K were calculated from Clausius–Clapeyron equation fitted on the experimental results. 相似文献
984.
There is a need for evolving hydraulically efficient roof profile of bellmouth for high head sluice spillways, as sluice roof is susceptible to cavitation damage. In this paper, formulation and development of a numerical model for simulating the spillway flow and its application to a sluice spillway are presented. The main focus of the simulation study is to apply the developed model to investigate the effects of sluice roof profile geometry on the pressure distribution, the discharge coefficient and the nature of flow regime within the sluice bellmouth. From the analysis of results for eight different roof profiles by varying the entry and exit angles of elliptic bellmouth transition, some important observations have been suggested, which are of practical relevance to hydraulic design engineers. The numerical model results are compared for one profile with physical model study. The simulated results are in close agreement with the measured values. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
985.
Masoud Darbandi Ehsan Roohi Vahab Mokarizadeh 《Numerical Methods for Partial Differential Equations》2008,24(2):583-604
The main objective of the current work is to introduce a new conceptual linearization strategy to improve the performance of a primitive shock‐capturing pressure‐based finite‐volume method. To avoid a spurious oscillatory solution in the chosen collocated grids, both the primitive and extended methods utilize two convecting and convected momentum expressions at each cell face. The expressions are obtained via a physical‐based discretization of two inclusive statements, which are constructed via a novel incorporation of the continuity and momentum governing equations. These two expressions in turn provide a strong coupling among the Euler conservative statements. Contrary to the primitive work, the linearization in the current work respects the definitions and essence of physics behind deriving the Euler governing equations. The accuracy and efficiency of the new formulation are then investigated by solving the shock tube as a problem with moving normal and expansion waves and the converging‐diverging nozzle as a problem with strong stationary normal shock. The results show that there is good improvement in performance of the primitive pressure‐based shock‐capturing method while its superior accuracy is not deteriorated at all. © 2007 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2008 相似文献
986.
Samrat Chatterjee Ezio Venturino Subhendu Chakraborty Joydev Chattopadhyay 《Mathematical Methods in the Applied Sciences》2009,32(13):1738-1750
We show how the inclusion of the defense strategy by different species can alter the prediction of simple models. One of the defense strategy by the phytoplankton population against their grazer is the release of toxic chemicals. In turn the zooplankton population reduces there predation rate over toxin producing phytoplankton (TPP) to protect themselves from those toxic chemicals. Thus, when the level of toxicity is high, the grazing pressure is low and when the level of toxicity is low or when the toxin is absent, the grazing pressure is high. Here we have considered a TPP–zooplankton system where the rate of toxin liberation and the predation rate vary with zooplankton abundance. We observe that our proposed model has the potential to show different dynamical behaviour that are similar to that seen in real‐world situations. Further, we consider three different functional forms for the distribution of the toxins and compare them using latin hypercube sampling technique and found that the functional forms seem to have no effect in determining the final outcome of the system. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
987.
It has long been known that homologous blood transfusion will result in a lot ofserious problems such as viral infections,for example AIDS,hepatitis,antigenicsensitization and GVHD;therefore aggressive testing of donor blood has beenadopted[1 ,2 ] .Even after this introduction,which is time-consuming and expensive,wecould not eliminate all the risks. In the wake of these kinds of pitfalls,production andclinical use of the blood substitutes have emerged.The essential aim of blood substitutei… 相似文献
988.
T. Portolés J. V. Sancho F. Hernández A. Newton P. Hancock 《Journal of mass spectrometry : JMS》2010,45(8):926-936
The potential applications of a new atmospheric pressure source for GC‐MS analysis have been investigated in this work. A list of around 100 GC‐amenable pesticides, which includes organochlorine, organophosphorus and organonitrogenated compounds, has been used to evaluate their behavior in the new source. Favoring the major formation of the molecular ion in the source has been the main goal due to the wide‐scope screening possibilities that this fact brings in comparison with the traditional, highly fragmented electron ionization spectra. Thus, the addition of water as modifier has been tested as a way to promote the generation of protonated molecules. Pesticides investigated have been classified into six groups according to their ionization/fragmentation behavior. Four of them are characterized by the abundant formation of the protonated molecule in the atmospheric pressure source, mostly being the base peak of the spectrum. These results show that wide‐scope screening could be easily performed with this source by investigating the presence of the protonated molecule ion, MH+. The developed procedure has been applied to pesticide screening in different food samples (nectarine, orange and spinach) and it has allowed the presence of several pesticides to be confirmed such as chlorpyriphos ethyl, deltamethrin and endosulfan sulfate. The availability of a quadrupole time‐of‐flight instrument made it feasible to perform additional MS/MS experiments for both standards and samples to go further in the confirmation of the identity of the detected compounds. Results shown in this paper have been obtained using a prototype source which exhibits promising features that could be applied to other analytical problems apart from those illustrated in this work. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
989.
利用改进的Ginder-Epstein模型计算了翠绿亚胺聚合物在参数V4,0取值于1.8~35.8 eV的自洽变分基态,并通过芳环扭角的变化来估算聚合物压强,给出了V4,0,芳环扭角及能隙与理论压强之间的最小二乘拟合.结果表明随此参数的增大,芳环扭角和能隙都缩减而理论压强升高.当理论压强由零压增至3.0 GPa左右时,能隙先快后慢从2.0 eV减小至最小值0.87 eV.这理论与该聚合物的高压电导测试结果一致. 相似文献
990.
The vast numbers of molecular objects and chemical transformations of a substrate cannot be evaluated even intuitively, which necessitates the development of simple reaction monitoring methods. Here this problem is formulated for the first time, and possible solutions are substantiated. 相似文献