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151.
152.
研究了重金属氧氟硅铋酸盐玻璃 (50-x)SiO2 xBi2O3 50PbF2(x=0, 3, 5, 8, 10, 13, 15 mol%)中Er3+离子的吸收光谱、荧光光谱、荧光半高宽、荧光 寿命和热稳定性能.应用Judd Ofelt理论计算了玻璃的强度参数Ωt(t=2,4,6),应用 McCumber计算了能级4I13/2→4I15/2跃迁的受激发射截面. 结果发现荧光半高宽与Ω6有较大联系,Ω6越大,荧光半高宽越宽.对Er3+
关键词:
重金属氧氟硅铋酸盐玻璃
光谱性质
Er3+离子
Judd Ofelt参数 相似文献
153.
The enhancement of phase-conjugnte wave in cerium-doped bismuth germanatecrystal(Ce:BGO) was investigated.The result indicated that the phase congugate mirror(PCM) reflectivity of the doped BGO is one order higher than that of pure BGO and the re-sponse time is also decreased for doped BGO.Their mechanism were discussed. 相似文献
154.
REN Ping-Da PAN Shi-Feng DONG Ting-Wei WU Shi-HuiDepartment of Chemistry Pudan University Shanghai China 《中国化学》1996,14(5):462-466
In the presence of active metal bismuth (Bi) which was prepared from the combination of bismuth trichloride and sodium borohydride,aldehydes have been found to react with allyl bromide in aqueous media,and the corresponding homoallylic alcohols were obtained in excellent yields with high chemo-and stereoselectivity. 相似文献
155.
156.
Toshinobu?YogoEmail author Reimon?Fukuzawa Wataru?Sakamoto Shin-ichi?Hirano 《Journal of nanoparticle research》2005,7(6):633-640
Nanocrystalline BaTiO3 particles modified with polarizable ligands were synthesized through hydrolysis of modified metal–organics below 100°C. BaTiO3 precursor was synthesized from barium metal, titanium isopropoxide and polarizable ligands in a mixture of ethanol and 2-ethoxyethanol.
The modified Ba–Ti complex alkoxide was hydrolyzed yielding BaTiO3 particles modified with organics. The crystallinty of nanometer-sized particles was dependent upon the hydrolysis conditions,
and increased with increasing water amount and time. The nanocrystalline particles were identified to be BaTiO3 by X-ray diffraction (XRD) and electron diffraction. A fluid consisting of modified BaTiO3 particles and silicone oil revealed a typical electrorheological (ER) behavior on applying DC field. The ER behavior was
found to depend upon the kind of ligand. 4-Fluorobenzyloxy modifier revealed the highest yield stress in the ER measurement
among 4-substitued benzyloxy ligands examined. 相似文献
157.
A surface plasma wave (SPW) over bismuth-vacuum interface has a signature of mass anisotropy of free electrons. For SPW propagation
along the trigonal axis there is no birefringence. The frequency cutoff of SPW
lies in the far infrared region and can be accessed using free electron laser. The damping rate of waves at low temperatures
is low. The surface plasma wave may be excited by an electron beam of current ∼100 mA propagating parallel to the interface
in its close proximity. 相似文献
158.
159.
160.
Cristina Rosu Dan Rasu Timothy J.R. Weakley 《Journal of chemical crystallography》2003,33(10):751-755
The reaction of [Bi2W22O74(OH)2]12– with Cu2+ in hot aqueous solution in the presence of Na+ affords the polyoxometalate salt Na12[Cu3Bi2W18O66]32H2O. Single-crystal X-ray analysis [monoclinic, space-group C2/m, a = 33.082(6) Å, b = 19.615(5) Å, c = 14.885(2) Å, = 90.632(12)°, Z = 4; R(F) = 0.065 for 6029 data with I> (I), wR(F
2) = 0.135 for all 8793 independent reflections] shows that the anion [{Cu(H2O)}3{BiW9O33}2]12–, on a crystal mirror-plane, has noncrystallographic symmetry close to D3h. Two B--[BiIIIW9O33]9– units are linked by an equatorial belt of three Cu(H2O)2+ units. Three Na(H2O)2
+ units are also attached in the equatorial plane. The bond geometry is square-pyramidal about each Cu atom and trigonal–prismatic about each Na. 相似文献