全文获取类型
收费全文 | 2027篇 |
免费 | 162篇 |
国内免费 | 448篇 |
专业分类
化学 | 1912篇 |
晶体学 | 12篇 |
力学 | 37篇 |
综合类 | 30篇 |
数学 | 61篇 |
物理学 | 361篇 |
无线电 | 224篇 |
出版年
2024年 | 10篇 |
2023年 | 35篇 |
2022年 | 117篇 |
2021年 | 117篇 |
2020年 | 122篇 |
2019年 | 77篇 |
2018年 | 67篇 |
2017年 | 75篇 |
2016年 | 82篇 |
2015年 | 79篇 |
2014年 | 82篇 |
2013年 | 204篇 |
2012年 | 136篇 |
2011年 | 150篇 |
2010年 | 86篇 |
2009年 | 120篇 |
2008年 | 118篇 |
2007年 | 122篇 |
2006年 | 131篇 |
2005年 | 123篇 |
2004年 | 79篇 |
2003年 | 96篇 |
2002年 | 69篇 |
2001年 | 48篇 |
2000年 | 48篇 |
1999年 | 38篇 |
1998年 | 25篇 |
1997年 | 21篇 |
1996年 | 18篇 |
1995年 | 21篇 |
1994年 | 20篇 |
1993年 | 9篇 |
1992年 | 15篇 |
1991年 | 8篇 |
1990年 | 11篇 |
1989年 | 5篇 |
1988年 | 14篇 |
1987年 | 6篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 10篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 3篇 |
排序方式: 共有2637条查询结果,搜索用时 0 毫秒
111.
Chiono V Sartori S Rechichi A Tonda-Turo C Vozzi G Vozzi F D'Acunto M Salvadori C Dini F Barsotti G Carlucci F Burchielli S Nicolino S Audisio C Perroteau I Giusti P Ciardelli G 《Macromolecular bioscience》2011,11(2):245-256
A biocompatible and elastomeric PU was synthesized from low-molecular-weight PCL as macrodiol, CMD as chain extender and HDI as chain linker for applications in the field of peripheral nerve repair. PU cast films supported in vitro attachment and proliferation of NOBEC. The in vitro adhesion and proliferation of S5Y5 neuroblastoma cells on the inner surface of uncoated, gelatin- and PL-coated PU guides were compared. Due to their superior in vitro performance, PL-coated PU guides were tested in vivo for the repair of 1.8 cm-long defects in rat sciatic nerves. The progressive regeneration was confirmed by EMG and histological analysis showing the presence of regenerating fibers in the distal stumps. 相似文献
112.
113.
Orhan Acar 《Mikrochimica acta》2005,151(1-2):53-58
Lead, Cr, Mn and Zn in slurries of botanic and biological samples were determined by electrothermal atomic absorption spectrometry (ETAAS) using W, Ir, NH4H2PO4, W and NH4H2PO4, Ir and NH4H2PO4, W and Ir, and W + Ir + NH4H2PO4 chemical modifiers in an 0.2% (v/v) Triton X-100 plus 0.2% (v/v) nitric acid mixture. Zeeman effect background correction was performed and platforms inserted into graphite tubes were used. Comprehensive comparative studies were carried out with respect to pyrolysis and atomization temperatures, atomization and background absorption profiles, characteristic masses, detection limits and accuracy of the determinations in the presence and absence of modifiers. The mixture of W + Ir + NH4H2PO4 was found to be preferable for the determination of Pb, Cr, Mn and Zn in slurry samples. The pyrolysis temperatures of the analytes were increased up to 1250 °C for Pb, 1000 °C for Zn, 1400 °C for Cr and Mn by using W + Ir + NH4H2PO4 with an 0.2% (v/v) Triton X-100 plus 0.2% (v/v) nitric acid mixture used as diluent solution. The optimum masses of the mixed modifier components were found to be 20 µg W + 4 µg Ir + 50 µg NH4H2PO4. The characteristic masses of Pb, Cr, Mn and Zn obtained are 16.3, 5.6, 0.1 and 1.1 pg, respectively. The detection limits of Pb, Cr, Mn and Zn based on integrated absorbance for 0.5% (m v−1) slurries were found to be 0.14, 0.06, 0.02 and 0.01 µg g−1, respectively. The slurries of botanic and biological certified and standard reference materials were analyzed with and without the modifiers. Depending on the sample type, the percent recoveries increased from 63 up to 104% for analytes when using the proposed modifier mixture. 相似文献
114.
Cline Schneider Frdric Doucet Stanislav Strekopytov Christopher Exley 《Polyhedron》2004,23(18):3185-3191
Hydroxyaluminosilicates (HAS) are critical secondary mineral phases in the biogeochemical cycle of aluminium. They are formed from the reaction of silicic acid (Si(OH)4) with an aluminium hydroxide template and act as a geochemical control of the biological availability of Al. There are two main forms of HAS which we have called HASA and HASB and which of these will predominate will depend upon the Si(OH)4 to Al ratio in any one environment. In all but the most heavily weathered environments or those undergoing a progressive acidification Si(OH)4 will be present in significant excess to Al and HASB will be the dominant secondary mineral phase. We have tried to determine the solubility of HASB(s) so that its contribution to Al solubility control might be compared with other secondary minerals such as Al(OH)3(gibbsite). In preliminary experiments, the dissolution of HASB(s) was found to be non-congruent with almost no Al being released during 18 months ageing. We then demonstrated that HASB(s) was significantly less soluble than Al(OH)3(s) prepared under identical experimental conditions. We have used this information to describe a solubility expression for HASB(s) at a predefined quasi-equibrium and to calculate a solubility constant.
K*Al2Si2O5(OH)4=[Al2O4+][SiO2]2[OH-]4