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71.
Michelina Soccio Lara Finelli Nadia Lotti Valentina Siracusa Tiberio A. Ezquerra Andrea Munari 《Journal of Polymer Science.Polymer Physics》2007,45(13):1694-1703
Poly(butylene naphthalate) (PBN), poly(diethylene naphthalate) (PDEN), and poly(thiodiethylene naphthalate) (PTDEN) were synthesized and characterized in terms of chemical structure and molecular weight. The polyesters were examined by TGA, DSC, and DMTA. All the polymers showed a good thermal stability, even though depending on chemical structure. At room temperature they appeared as semicrystalline materials; the effect of the introduction along the PBN polymer chain of ether oxygen atoms or sulfur ones was a lowering in the Tg value, a decrement of Tm, and a decrease of the crystallization rate. Changing in chemical structure also affects the main α absorption associated with the glass transition which moves to lower temperature and whose energetic requirements decrease. The results were explained as due to the presence of highly flexible C? S? C or C? O? C bonds in the polymeric chain. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1694–1703, 2007 相似文献
72.
基于Karhunen-Loève变换和小波谱特征矢量量化的三维谱像数据压缩 总被引:1,自引:1,他引:0
提出了基于Karhunen Lo埁ve变换的小波谱特征矢量量化三维谱像数据压缩方法耍幔颍瑁酰睿澹?Lo埁ve变换 /小波变换 /小波谱特征矢量量化方法应用了Karhunen Lo埁ve变换的消除谱相关性优良性能 ,应用二维小波变换消除空间相关性 ,在小波变换域内应用二维集分割嵌入块编码和一维谱特征矢量量化对三维谱像数据压缩 ,获得较高的压缩性能。实验结果表明 :Karhunen Lo埁ve变换 /小波变换 /小波谱特征矢量量化编码比Karhunen Lo埁ve变换 /小波变换 /改进对块零树编码和Karhunen Lo埁ve变换 /小波变换 /快速矢量量化编码方法在同样压缩比条件下 ,峰值信噪比提高 2dB和 1dB以上 ,而速度提高了 1.5和 8倍 ,整体压缩性能有较大的提高 相似文献
73.
Stefan Jaschke Claudia Klüppelberg Alexander Lindner 《Journal of multivariate analysis》2004,88(2):252-273
We derive results on the asymptotic behavior of tails and quantiles of quadratic forms of Gaussian vectors. They appear in particular in delta–gamma models in financial risk management approximating portfolio returns. Quantile estimation corresponds to the estimation of the Value-at-Risk, which is a serious problem in high dimension. 相似文献
74.
Support vector machine (SVM), developed by Vapnik et al., is a new and promising technique for classification and regression and has been proved to be competitive with the best available learning machines in many applications. However, the classification speed of SVM is substantially slower than that of other techniques with similar generalization ability. A new type SVM named projected SVM (PSVM), which is a combination of feature vector selection (FVS) method and linear SVM (LSVM), is proposed in present paper. In PSVM, the FVS method is first used to select a relevant subset (feature vectors, FVs) from the training data, and then both the training data and the test data are projected into the subspace constructed by FVs, and finally linear SVM(LSVM) is applied to classify the projected data. The time required by PSVM to calculate the class of new samples is proportional to the count of FVs. In most cases, the count of FVs is smaller than that of support vectors (SVs), and therefore PSVM is faster than SVM in running. Compared with other speeding-up techniques of SVM, PSVM is proved to possess not only speeding-up ability but also de-noising ability for high-noised data, and is found to be of potential use in mechanical fault pattern recognition. 相似文献
75.
We study a system of quasilinear equations describing one-dimensional flow of a viscous compressible heat-conducting medium with a nonmonotone state function and mass force. The large-time behavior of solutions is considered for arbitrarily large initial data. In spite of possible nonuniqueness and discontinuity of the stationary solution, we prove L2-stabilization for the stress and heat flux as t → ∞ along with corresponding global energy estimates for them. The new method of proof utilizes a combination of energy type equalities for the stress and heat flux. Consequently, H1-stabilization of the velocity and temperature along with global estimates for their derivatives are valid as well. 相似文献
76.
77.
A study of the electrochemical reduction of the mesotrione pesticide on a hanging mercury drop electrode (HMDE) was performed
as a basis for the development of a sensitive analytical method for natural samples. The electrochemical characteristics of
herbicide mesotrione dissolved in a phosphate buffer (pH 7.0) have been determined by means of electrochemical techniques
such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV) over a wide range of pH from 2.0 to 10.0. The experimental
parameters, such as electrolyte type and its pH, pulse amplitude, and scan rate were optimized. The method was applied to
the determination of the pesticide in a spiked soil samples. Using this method, a linear calibration curve for mesotrione
was obtained up to the 0.1 μM range in pH 7 phosphate buffer solution with a detection limit (S/N = 3) of 50 nM. The method
can be applied successfully to the determination of mesotrione in soils.
The text was submitted by the authors in English. 相似文献
78.
I. Capek J. Chudej S. Janí
kov 《Journal of polymer science. Part A, Polymer chemistry》2003,41(6):804-820
The sterically stabilized emulsion polymerization of styrene initiated by a water‐soluble initiator at different temperatures has been investigated. The rate of polymerization (Rp) versus conversion curve shows the two non‐stationary‐rate intervals typical for the polymerization proceeding under non‐stationary‐state conditions. The shape of the Rp versus conversion curve results from two opposite effects—the increased number of particles and the decreased monomer concentration at reaction loci as the polymerization advances. At elevated temperatures the monomer emulsion equilibrates to a two‐phase or three‐phase system. The upper phase is transparent (monomer), and the lower one is blue colored, typical for microemulsion. After stirring such a multiphase system and initiation of polymerization, the initial coarse polymer emulsion was formed. The average size of monomer/polymer particles strongly decreased up to about 40% conversion and then leveled off. The initial large particles are assumed to be highly monomer‐swollen particles formed by the heteroagglomeration of unstable polymer particles and monomer droplets. The size of the “highly monomer” swollen particles continuously decreases with conversion, and they merge with the growing particles at about 40–50% conversion. The monomer droplets and/or large highly monomer‐swollen polymer particles also serve as a reservoir of monomer and emulsifier. The continuous release of nonionic (hydrophobic) emulsifier from the monomer phase increases the colloidal stability of primary particles and the number of polymer particles, that is, the particle nucleation is shifted to the higher conversion region. Variations of the square and cube of the mean droplet radius with aging time indicate that neither the coalescence nor the Ostwald ripening is the main driving force for the droplet instability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 804–820, 2003 相似文献
79.
在管理信息系统的开发以及分布式数据库系统的设计中,已开始使用面向对象的技术.本文论述了面向对象的设计特征,介绍了用于面向对象设计的各种实现语言,并着重分析了各种实现语言支特面向对象设计的能力. 相似文献
80.
Li Chen Ling Hsiao Gerald Warnecke 《应用数学学报(英文版)》2007,23(1):9-28
This paper considers a kind of strongly coupled cross diffusion parabolic system,which can be usedas the multi-dimensional Lyumkis energy transport model in semiconductor science.The global existence andlarge time behavior are obtained for smooth solution to the initial boundary value problem.When the initialdata are a small perturbation of an isothermal stationary solution,the smooth solution of the problem under theinsulating boundary condition,converges to that stationary solution exponentially fast as time goes to infinity. 相似文献