A New Chromium(III) Microelectrode Based on Self‐Assembled Diethylenetriamminepentaacetic Acid‐Poly(fuchsin basic) Modified Electrode

A new selective, sensitive, and rapid response microelectrode for microamount chromium(III) determination was developed. For the electrode preparation, fuchsin basic was electropolymerized onto a carbon microdisk electrode, and then diethylenetriamminepentaacetic acid (DTPA) was self‐assembled on the electrode surface by the reaction between DTPA and poly(fuchsin basic). The determination conditions were optimized. The electrode showed a linear response to Cr³⁺ ions in the concentration range of 1.0×10^?6?1.0×10^?4 M and exhibits a super‐Nernstian slope of 32.5±0.4 mV per decade. The detection limit is 3.6×10^?7 M. The response time of the electrode is less than 10 s, and it can be used for at least 2 months with limited considerable divergences in its potentials. The proposed electrode was applied for monitoring the chromium ion level in wastewater of chromate industries.     

Microextraction,capillary electrophoresis,and mass spectrometry for forensic analysis of azo and methine basic dyes from acrylic fibers

Designed experiments based on a simplex mixture design were employed to explore the effects of three solvent components (water, formic acid, and aqueous acetic acid), extraction time, and extraction temperature for the automated microextraction of basic (cationic) dyes from acrylic fibers. Extractions were conducted by an automated liquid handling system, and dye extraction was evaluated using a UV/visible microplate reader. Highest extraction efficiency for two subclasses of basic dyes (methine and azo) from acrylic fibers was achieved with an extraction solvent containing 88% formic acid/12% water. Cationic dyes were analyzed by capillary electrophoresis using a 45 mM ammonium acetate buffer in acetonitrile–water at pH 4.7. The utility of microextraction combined with capillary electrophoresis–mass spectrometry for analysis of extracts from trace fibers was demonstrated by the detection and characterization of three basic dyes extracted from a 2-mm length of single acrylic fiber.     

纯正半群上的强同余及其格

给出了纯正半群S的强同余格上同余T的一些判别性质,证明了S上所有基础强同余所构成的集合FCP（S）是CP（S）的完备子格,最后讨论了由纯正半群的正规子半群决定的交完备子格的结构及由“求核”运算确定的（交完备格）同余K的若干性质,还顺带讨论了群同余格.     

欧氏空间子空间正交补的代数方法研究

在n维欧氏空间Rn中,对其任意的非零子空间V1,有子空间V2使V1⊥V2,且Rn=V1V2.本文对这一几何问题利用齐次线性方程组给予了代数方法的又一种证明.     

A fluorescent chemical sensor for Hg(II) based on a corrole derivative in a PVC matrix

A fluorescent chemical sensor for Hg(II) using 5,10,15-tris(pentafluorophenyl)corrole (H₃(tpfc)) as fluorophore is described in this paper. The response of the sensor is based on the fluorescence quenching of H₃(tpfc) by coordination with Hg(II). H₃(tpfc) based sensor shows a linear response towards Hg(II) in the concentration range from 1.2 × 10⁻⁷ to 1.0 × 10⁻⁴ M, with a working pH range from 5.0 to 8.0. The response time for Hg(II) concentration ≤1.0 × 10⁻⁵ M is less than 5 min. The sensor shows good selectivity for Hg(II) over alkali, and alkaline earth, and most of transition metal cations. The effect of the composition of the sensor membrane has been studied and the experimental conditions optimized. The corrole based sensor membrane can be easily regenerated just by washing with blank buffer solution after each measurement. The sensor has been used for determination of Hg(II) in water samples with satisfactory results.     

杂交元零能模式抑制的正交基本变形模式方法

通过杂交元位移场直接推导了单元基本变形模式,并且采用联合正交条件提出一种新的正交化方法,所得到的正交基本变形模式不仅具有简单的变形特征而且和材料参数无关,可以方便有效地考察单元性能,为评价不同杂交元提供了一个统一的参考标准．在此基础上利用柔度矩阵正定性给出一种简单有效的零能模式识别方法,并进一步利用基本变形模式和初始应力模式之间耦合关系,提出一种抑制杂交元零能模式的假设应力场方法,同时指出基本变形模式正交性是抑制单元零能模式的充分必要条件．2D-4节点和3D-8节点单元的数值算例说明了该文基本变形模式方法的有效性．     

集中式MIMO雷达发射方向图快速设计方法

该文提出了任意发射方向图可以由一组基波束合成的思想。基于该思想,先对集中式 MIMO雷达阵列进行切比雪夫幅度加权构造出一组具有较低副瓣的基波束,然后利用线性规划来快速求解出构成方向图的基波束和其比例系数。与已有的半正定二次规划方法相比较,采用线性规划综合出来的发射方向图具有较低的空域副瓣和较小的空域互相关,并且计算时间较快。     

基于和差波束极化特性的目标极化散射矩阵测量方法研究

该文建立了一种基于常规单脉冲体制的目标全极化散射矩阵测量算法。首先证明了该型雷达天线具有复杂的极化结构,并且对回波信号的极化特性有一定的敏感性。利用单脉冲雷达和差通道的极化特性在获取目标角度信息的同时利用一个脉冲重复周期即可完成目标极化散射矩阵的测量,降低了全极化单脉冲雷达研发的系统复杂度和设计成本,通过电磁计算和仿真分析验证了上述研究的正确性。这对于开发现有雷达装备的极化测量处理能力、提升其抗干扰和目标识别能力具有一定的启发和指导意义。     

基于信号幅相特性的副瓣跟踪自动识别方法

传统雷达测角系统副瓣跟踪识别方法主要根据副瓣信号幅度较主瓣明显偏低这一特性提出,该文通过对副瓣跟踪原理的理论分析、仿真分析与实测验证,得出了关于副瓣跟踪特性的新结论:副瓣跟踪时和差相位正交、差和幅度比相对主瓣跟踪明显增大。在此基础上提出一种基于信号幅相特性的副瓣跟踪识别方法:构造以差和幅度比、和差相位差为描述子的幅相特征向量,采用支持向量机(SVM)对特征向量进行分类完成识别过程。实验结果表明,该文方法识别准确率高,鲁棒性、实时性、通用性强。     

基于HSI高光谱和TM图像的土地盐渍化信息提取方法

选择黄河三角洲垦利县代表性盐碱化区域为研究区,以2011年3月15日HJ-1A卫星HSI高光谱影像和2011年3月22日TM影像为信息源,经几何纠正、图像裁剪、大气校正等预处理,分析不同盐渍化程度土地、水体、滩涂等主要地类的光谱特征,确定地类信息提取特征波段。结合土壤盐分含量,采用定量与定性相结合规则,构建地类信息提取模型,以决策树分类方法进行图像分类,提取土地盐渍化信息。利用地表点位土壤含盐量数据对地表土地盐渍化程度的化学分析结果,对遥感解译数据进行精度验证,并对高光谱和多光谱影像的分类精度进行比较分析。结果表明：HSI图像的总体分类精度达96.43%,Kappa系数为95.59%,而TM图像的总体分类精度为89.17%,Kappa系数为86.74%,说明相比多光谱TM数据,基于高光谱图像可以更为准确有效地提取土地盐渍化信息;由分类结果图可以看出,高光谱影像土地盐渍化的区分度高于多光谱影像。该研究探索了高光谱图像土地盐渍化信息的提取技术方法,提供了不同盐渍化土地的分布比例数据,可为黄河三角洲滨海盐碱土地资源的科学利用与管理提供决策依据。