Sr2SiO4∶Dy3+材料制备及发光特性

采用高温固相法制备了Sr2SiO4∶Dy3+发光材料. 在365 nm紫外光激发下, 测得Sr2SiO4∶Dy3+材料的发射光谱为一个多峰宽谱, 主峰分别为486, 575和665 nm; 监测575 nm的发射峰, 所得材料的激发光谱为一个多峰宽谱, 主峰分别为331, 361, 371, 397, 435, 461和478 nm. 研究了Dy3+掺杂浓度对Sr2SiO4∶Dy3+材料发射光谱强度的影响. 研究结果显示, 随着Dy3+浓度的增大, 黄、蓝发射峰比值(Y/B)也逐渐增大; 随着Dy3+浓度的增大, 575 nm发射峰强度先增大后减小. 加入电荷补偿剂Li+, Na+和K+均提高了Sr2SiO4∶Dy3+材料的发射光谱强度, 其中以Li+的情况最为明显.     

Effect of synthesis parameters on the structural,morphological characteristics,and photocatalytic activity of La2O3 nanoparticles

This study investigates the influence of synthesis processes such as sonication, sol-gel, and microwave on the production of highly crystalline Lanthanum oxide nanoparticles (La₂O₃) employing Lanthanum nitrate and Ammonium hydroxide (NH₄OH) as precursors. X-ray diffraction (XRD), particle size analysis (DLS), Field emission scanning electron microscopy (FESEM), Fourier-transform infrared spectroscopy (FTIR), ultraviolet–visible absorption spectroscopy (UV–Vis), and electrochemical impedance spectroscopy (EIS) were used to examine the most effective processing method and its effects on the nanoparticle characteristics, such as structure, morphology, and optical and electrical behavior. Sonication produces La₂O₃ NPs with a smaller crystalline size, an agglomerated nanorod structure, a higher bandgap, and better electrical responsiveness than sol-gel and microwave techniques. Structural and optical characterization tests discovered this. The photocatalytic degradation activity of cationic Safranin and anionic Congo red dye exhibits degradation efficiency of around 90.13% and 89.66%, respectively.     

A non‐volatile,bistable, and rewritable memory device fabricated with poly(nitroxide radical) and silver salt layers

A non‐volatile, bistable, and rewritable organic memory device was successfully fabricated with the layers of poly(2,2,6,6‐tetramethylpiperidine‐1‐oxyl methacrylate) (PTMA) and poly(methyl methacrylate) (PMMA) containing silver salt. The PTMA layer was employed as a p‐dopable material, while the silver salt‐dispersed PMMA layer acted as an n‐dopable material. The ON–OFF ratio between low‐conductivity and high‐conductivity states amounted to more than four orders of magnitude, and the retention time was longer than 10³ sec. The device was characterized by excellent rewritability. Copyright © 2007 John Wiley & Sons, Ltd.     

Targeted identification of phosphorylated peptides by off-line HPLC-MALDI-MS/MS using LC retention time prediction

Protein phosphorylation is a type of posttranslational modification which plays an important role in cell regulation and signal transduction. Because of its biological relevance, a considerable amount of interest has been paid to the development of efficient techniques for phosphopeptide analysis. Although advances in MS control have enabled the high-throughput discovery of proteins from limited amounts of sample, automated selection of MS/MS precursor ions based on intensity alone can significantly hamper the detection of low-abundance phosphopeptides. On the basis of the observation that the introduction of a phosphate moiety does not dramatically change peptide retention time in reverse-phase chromatography, phosphopeptide specific MS/MS fragmentation attempts based on LC retention time and m/z were evaluated using a standard protein mixture, then using in vitro phosphorylated myelin basic protein. Results indicated that the majority (98%) of phosphopeptides identified eluted within a +/- 4-min window of the predicted LC elution time. While studies presented here are primarily proof of concept in nature, data suggest that the use of LC retention time prediction could be a valuable constraint for the identification of phosphopeptides within a set of off-line LC deposited sample spots. It is expected that the development of these methods will not only permit the targeted identification of protein phosphorylation sites but also allow the in-depth analysis of the dynamic events linked to the posttranslational modification.     

原位合成CoPc/SnO2的键合特性及可见光光催化活性

报道了酞菁钴(CoPc)分子原位自组装于纳米SnO2颗粒表面, CoPc大环分子与SnO2表面形成Co—O轴向相互作用, 测定了原位合成方法(标记为i)制备的CoPc/SnO2(i)与浸渍法(标记为d)制备CoPc/SnO2(d)间的结合特性, 并进行了可见光光催化表征及CoPc敏化机理探讨. 结果表明, 在结合位点数相当的情况下, CoPc/SnO2(i)结合常数比CoPc/SnO2(d)的高两个数量级, 前者的光催化效率亦比后者高32.5%(光照150 min), 且CoPc/SnO2(i)光催化稳定性较高(重复十次循环使用). 其CoPc敏化SnO2的机理为, 由于敏化剂与半导体之间存在的强相互作用, 不仅增强了光生电荷在CoPc的LUMO与SnO2半导体导带间的导入效率及光生电荷对的分离效率, 而且提高了敏化剂的负载稳定性与循环光催化效率的持续性.     

含山网络广播电视台建设与发展

随着计算机技术、通信技术和网络技术的迅速发展,以互联网为平台的多终端全媒体传播方式是广电向新媒体领域延伸的大势所趋.通过含山网络广播电视台建设,重点介绍了项目的方案以及实现方法.详细地分析了网络台建设过程中的安全防范措施和技术特点,同时对网络台未来的发展也进行了探讨.     

基于MODTRAN的光波大气透射率模型设计

由于红外辐射等光波在地球大气中传输会受到大气吸收、散射等作用的影响,因此研究光波在大气中的传输特性成为了一项重要的课题。本文主要通过对可见光和红外波段光波在大气中传输机理的研究,建立透射率模型来反映大气对光波传输的衰减作用。通过仿真计算出各个波段的光波在大气中传输的衰减结果,并利用MODTRAN软件计算结果对透射率模型进行比较分析。研究结果表明：透射率模型和MODTRAN软件仿真所得光波的透射率都在40%~100%之间变化,且变化曲线趋势一致性较好。所得结果真实有效,对工程实际有一定的作用。     

基层供电企业电网运行风险评估分析

电网的安全运行不但对基层供电企业的发展有着非常重大的影响,还会直接关系着社会的安全稳定。因此提高对县域电网安全运行的重视程度,对可能出现的风险进行合理准确的评估以找出电网中潜在风险是非常必要。本文对基层供电企业电网运行过程中的风险进行分析评估。     

网络环境下英语广告翻译的思考

广告英语有别于普通英语,它的词汇简洁别致又富于创新。力图用最简洁、最准确的文字,为商品提供丰富的信息,使读者一目了然、过目不忘。由于商品市场竞争特别激烈,为了保证商品的广告可以最大限度的吸引人的眼球,广告撰写者总是选择新颖别致的词汇、简洁的语句和生动的修辞,以赢得消费者的喜爱。     

含梯度折射率缺陷的一维光子晶体滤波性能研究

为实现一维光子晶体更优越的滤波特性,引入渐变折射率缺陷层,可以抑制某些特定频率的电磁波,产生光子禁带。利用时域有限差分（FDTD）法,严格求解麦克斯韦方程组。研究了缺陷层的折射率变化为抛物线型时对应的透射率谱线,并分析了周期介质层的折射率比、厚度比及周期数,对滤波性能的影响。研究表明,增加折射率比,含梯度折射率缺陷层的一维光子晶体可以实现更大的滤波带宽;改变厚度比,可以影响透射峰位置;改变周期数,则可以影响透射率。这一研究结果对提高光子晶体滤波器性能具有一定参考价值。