Surface modification of soft-glass capillaries for gas chromatography by treatment with water vapour

“Leaching” or “etching” by strong mineral acids seems to be a necessary pretreatment step for the most commonly used deactivation procedures of glass capillaries by reaction with either polyethylene glycol or silylation reagents. The acidic sites which are formed on the surface during this acid treatment cannot be completely removed by the subsequent deactivation process. This drawback can be overcome by performing the leaching with water vapour, resulting in an accumulation of cations at the surface and a decrease in the number of silanol groups. Capillaries of this type show excellent properties for the chromatography of strongly basic compounds. After the wash-out of the alkaline surface layer, the acidity of the support is suited for the chromatography of strongly basic as well as strongly acidic compounds. Due to a lack of reactive acidic sites, special deactivation procedures have to be applied to capillaries produced in this way.     

离子交换-双氧水氧化法制备纳米CeO2晶体

以99.995% Ce(NO₃)₃和强碱性阴离子交换树脂为原料，采用离子交换-双氧水氧化法合成制备出纳米CeO₂晶体。并就离子交换反应中的Ce³⁺浓度、树脂加入速度和离子交换温度及H₂O₂加入速度等条件对CeO₂粒径的影响进行了探讨，得出了离子交换-双氧水氧化法制备纳米CeO₂晶体的最佳工艺条件。FTIR、TEM分析表明，离子交换法无需对合成的Ce(OH)₃溶胶进行洗涤即可去除NO₃^-、CO₃^2-等阴离子杂质，并用H₂O₂将该溶胶氧化，经真空干燥可制得粒径分布均匀，平均晶粒尺寸约3 nm，高纯度的CeO₂粉体。     

呋喃-乙酸分子间相互作用的量子化学研究

用密度泛函理论B3LYP方法选取6-311＋＋G(d,p)基组对呋喃-乙酸复合物进行了量子化学计算研究, 通过在相同水平下的频率振动分析发现了该势能面上6个极小值点, 其最稳定构型对应一强O…H—O型氢键, 其结合能在消除基组重叠误差后为－20.87 kJ•mol^－1. 通过自然键轨道(NBO)分析, 研究了电荷转移及轨道相互作用. 通过自洽反应场(SCRF)理论中的Onsager 溶剂模型在介电常数分别为1.0, 2.247, 4.9, 7.58, 10.36, 20.7, 32.63, 38.2, 46.7, 78.39的不同溶剂环境下重新优化呋喃与乙酸势能面上最稳定构型A, 研究了溶剂对呋喃-乙酸复合物几何构型、电荷分布、偶极矩以及结合能的影响. 发现溶剂化作用增大了呋喃与乙酸分子间的结合能, 导致O…H距离减小, H—O振动频率红移. 当溶液介电常数在1.0～32.63范围时, 溶剂效应十分显著, 当介电常数大于32.63后, 溶剂化作用几乎达到了极限.     

6-氨基青霉烷酸在弱碱性阴离子树脂IRA67上的吸附研究

用静态法研究了6-氨基青霉烷酸在弱碱性阴离子交换树脂IRA67上的吸附行为．在溶液pH为8．0，6-APA起始浓度介子3.00mg／m1-20．00mg／ml条件下，测定了25℃时IRA67树脂的静态交换动力学曲线、吸附等温线，并求得了IRA67树脂的平衡速率常数及吸附等温线方程．分别用Langmuir型和Frendlich型方程对IRA67树脂吸附等温线进行线性回归拟合，结果表明，6-APA在IRA67树脂上的吸附更符合Langmuir型吸附．     

q-Hypergeometric Series and Macdonald Functions

We derive a duality formula for two-row Macdonald functions by studying their relation with basic hypergeometric functions. We introduce two parameter vertex operators to construct a family of symmetric functions generalizing Hall-Littlewood functions. Their relation with Macdonald functions is governed by a very well-poised q-hypergeometric functions of type ₄₃, for which we obtain linear transformation formulas in terms of the Jacobi theta function and the q-Gamma function. The transformation formulas are then used to give the duality formula and a new formula for two-row Macdonald functions in terms of the vertex operators. The Jack polynomials are also treated accordingly.     

带有前置EDFA卫星相干激光通信终端的信噪比分析

卫星激光通信链路是一项实现卫星大规模星座组网的关键技术。相干激光链路灵敏度高、抗背景干扰、速率升级空间大,在星间激光链路中应用广泛。文章建立了带有前置掺铒光纤放大器(EDFA)的卫星相干激光通信终端的信噪比分析模型,仿真分析了EDFA功率增益、EDFA噪声系数、本振光功率、信号光功率、光放后端光带宽、基带前端电带宽对终端输出信噪比的影响以及各种输出噪声功率占比的情况,得到了带有前置EDFA卫星相干激光通信终端的信噪比参数特性。     

一种高增益的宽带低噪声放大器的设计

采用SANAN公司的0.25μm E-Mode pHEMT工艺,基于ADS仿真,设计了一款工作频率为2.0～4.2 GHz的两级级联的宽带LNA芯片。芯片采用电阻偏压的方式,实现了3.3 V单电源供电。同时,设计了一种改进型的RLC并联负反馈结构,实现了宽带匹配。仿真结果表明,该LNA在2.0～4.2 GHz频段内,最大增益为30.9 dB,增益平坦度为±0.6 dB左右,输入回波损耗小于-9 dB,输出回波损耗小于-12 dB;噪声系数为(1.2±0.14) dB;系统稳定性因子K在全频带内大于2.8;芯片面积为0.78 mm×2.2 mm。     

采用辅助转动装置的MIMO 系统双目标DPD 实验研究

文中介绍了一种双目标数字预失真(DPD)方案,并进行了实验研究。不增加系统复杂度的情况下, 可以有效地扩展MIMO 系统的线性化波束宽度。在发射机附近增设一个发射低功率信号的线性辅助转动装置,该 架构实现了MIMO 系统主波束线性化。实验平台由发射机系统和一个辅助转动装置组成,发射机天线阵列为1×4。 输入信号采用两个20 MHz 带宽峰均比分别为5. 7 dB 和5. 6 dB 的正交频分复用(OFDM)信号。实验研究结果表明, 采用了辅助转动装置的双目标DPD 方法后,邻信道功率比(ACPR)达到-50 dBc 以下的主波束线性化宽度可以扩展 到22°,同时信号归一化均方误差(NMSE)平均数值为-40 dB。该方案有效地拓宽了MIMO 系统线性化波束宽度。     

On the design considerations of solid-state power amplifiers for satellite communications: A systems perspective

Conventional solid-state power amplifier (SSPA) design approach isolates radio frequency (RF) design from communication theory. In this paper, a unified SSPA design approach is proposed, which optimizes SSPA parameters (bias voltage and input RF signal power) to minimize total DC power consumption while satisfying received SNR constraint specified by the link budget. The effect of SSPA nonlinearity is quantified by the error vector magnitude measured at its output and the corresponding received SNR degradation is analyzed. Using the quantitative metrics for received SNR, it is possible to evaluate highly nonlinear SSPA classes such as Class-B or deep-Class AB, which are normally not considered in conventional SSPA design approach to be used in satellite communication applications.     

基于40 nm CMOS工艺的高效率功率放大器设计

针对硅基毫米波功率放大器存在的饱和输出功率较低、增益不足和效率不高的问题,基于TSMC 40nm CMOS工艺,设计了一款工作在28GHz的高效率和高增益连续F类功率放大器。提出的功率放大器由驱动级和功率级组成。针对功率级设计了一款基于变压器的谐波控制网络来实现功率合成和谐波控制,有效地提高了功率放大器的饱和输出功率和功率附加效率。采用PMOS管电容抵消功率级的栅源电容,进一步提高线性度和增益。电路后仿真结果表明,设计的功率放大器在饱和输出功率为20.5dBm处的峰值功率附加效率54%,1dB压缩点为19dBm,功率增益为27dB,在24GHz~32GHz频率处的功率附加效率大于40%。