新工科视阈下石油化工类高校应用化学专业课程体系重构

Taking a typical local and industry-orientated applied chemistry major as an example with focusing on the major changes in the form and content of the petrochemical industry, the way to reform the core curriculum system and teaching contents is presented. Based on the changing tendency of refinement of the petrochemical industry, a complete curriculum system with distinctive industry characteristics is set up according to the principles of the emerging engineering education (3E) with several reasonable suggestions. A new model for the construction of a 3E major in chemistry-related majors is suggested. It is a good reference for the construction of curriculum systems for other local and industry-orientated colleges who want to make 3E reform.     

乙基苯基二氯化锡与2－羟基萘醛缩对甲氧基苯胺Schiff碱1∶1配合物的合成和晶体结构

乙基苯基二氯化锡与２－羟基萘醛缩对甲氧基苯胺Ｓｃｈｉｆｆ碱１∶１配合物的合成和晶体结构刘宝殿，包明，孙振刚，贺庆林，邢彦，贾恒庆，林永华（东北师范大学化学系，长春，１３００２４）（中国科学院长春应用化学研究所，长春）关键词乙基苯基二氯化锡，Ｓｃｈｉｆ...     

Crystal Structure and Characterization of 2-N-(2-Hydroxy-benzylidene) Furanmethanoamine Nickel(II) Complex

1 INTRODUCTION Recently, the low-spin square-planar nickel(II) complexes and high-spin octahedral nickel(II) complexes with Schiff base ligands have received much attention in optical materials[1～3]. Some nic- kel(II) complexes are widely used as lubricating oil, rubber industry additives, a fire-resistant additive and fungicide for leather[4～7]. Also, their adducts with nitrogen have attracted broad attention due to their potential applications as organic conductors and magnetic mate…     

Fluid phase equilibria of binary and ternary mixtures of supercritical carbon dioxide with tetradecanoic acid and docosane up to 43 MPa and 393 K: cosolvency effect and miscibility windows

Isothermal pressure (p)-mass fraction (w) phase diagrams were measured for CO₂ + tetradecanoic acid at six temperatures from 328.2 K to 373.2 K and for CO₂ + docosane at four temperatures from 343.2 K to 393.2 K as well as isobaric temperature (T)-mass fraction (w) phase diagrams for both systems at 34.5 MPa. In addition the isothermal and isobaric Gibbs phase prisms at 373.2 K and 34.5 MPa respectively were determined for the ternary system CO₂ + tetradecanoic acid + docosane, and and isobaric miscibility window was found between 333 K and 385 K at 34.5 MPa.     

Synthesis of nanostructures based on 1,4- and 1,3,5-phenylethynyl units with π-extended conjugation. Carbon networks dendrimer base units

A convenient and efficient synthesis of 3,5-di(silylethynyl)phenylacetylene and p-[3,5-di(silylethynyl)phenylethynyl]phenylacetylene has been carried out. These compounds serve to prepare nanometer-sized conjugated 1,4- and 1,3,5-phenylethynyl oligomers, by means of cross-coupling with a convenient haloaryl derivative, catalysed by palladium(II), in excellent yields. The phenylethynyl homologues show fluorescence emission, the wavelength of which is displaced by approximately 20 nm by each phenylethynyl unit increasing the conjugate chain.     

Shape of the proton potential in an intramolecular hydrogen-bonded system. Part II

The crystals of 5,5′-dibromo-3-diethylaminomethyl-2,2′-biphenol N-oxide were studied by X-ray and FT-IR spectroscopy. Within this molecule two short OHO intramolecular hydrogen bonds are formed. The NO?H⁺?O⁻ bond between the OH and the N-oxide groups is very strong, of 2.419(7) Å between the oxygen atoms. The proton potential of this hydrogen bond is flat, broad and has probably no barrier—consequently it could not be located from X-ray diffraction data. The other hydrogen bond formed between two hydroxyl groups appears asymmetrical from FT-IR spectra, and shows also relatively limited proton polarizability. The molecular conformation is non-planar, due to strong overcrowding effect between the oxygen atoms involved in the hydrogen bonds.     

Tröger's base scaffold in racemic and chiral fashion as a spacer for bisdistamycin formation. Synthesis and DNA binding study

‘Head-to-head’ oligo-N-methylpyrrole peptide dimers linked by a methano[1,5]diazocin scaffold are presented in racemic as well as chiral fashion. Their DNA binding activities were assayed on calf thymus DNA, poly(dA-dT)₂, and poly(dC-dG)₂ by NMR and ECD spectroscopies, and fluorescence probe displacement assay. The presented dimers prefer AT sequences, but show higher affinity to poly(dC-dG)₂ than distamycin A. The (4R,9R) configuration of methanodiazocin bridge was found to be better suited for interaction with ct-DNA and poly(dA-dT)₂ than (4S,9S) configuration.     

H3PW12O40 and its cesium salts as pentane isomerization catalysts at ambient temperature

The activity of Mg−Al basic heterogeneous catalysts in the reactions of alcohols with ethylene oxide was studied. The kinetics of alcohol oxyethylation was examined. The kinetic equation of the reaction was determined and the structure of products was studied. The distribution coefficients of the oxyethylation reaction products were calculated. A comparison of the catalytic activity of Mg−Al hydroxides and products of their thermal treatment was made.     

Synthesis of Tetra—Schiff Base Macrocyclic Compound Containing Benzo—12—crown—4

Tetra-Schiff base macrocyclic compound containing benzo-12-crown-4 was synthesized via condensation of 2,6-diformyl-4-methyl-phenol with 4′，5′-diaminobenzo-12-C-4 promoted by proton. The compound was characterized by MS,IR ^1HNMR spectroscopy and elemental analysis.     

Synthesis and Antibacterial Activities of 4-Amino-3-(1-aryl-5-methyl-1,2,3-triazol-4-yl)-5-mercapto-1,2,4-triazoles/2-Amino-5-(1-aryl-5-methyl-1,2,3-triazol-4-yl)-1,3,4-thiadiazoles and Their Derivatives

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