定量磁化率成像重建方法及其应用

磁共振成像(MRI)中,相位图像包含丰富的组织磁化率变化信息,获取相位图像不需要额外的扫描时间．组织中的顺磁性物质会影响组织磁化率差异,从而导致局部磁场不均匀．对组织内顺磁性物质的定量有利于许多脑血管疾病和神经系统疾病的诊断,但利用局部相位信息重建组织磁化率分布是一个不适定逆问题,目前仍然有许多问题亟待解决．该文着重介绍定量磁化率成像(QSM)的原理、重建方法及其在MRI 中的应用．     

Small target detection using main directional suppression high pass filter

Small target detection in deep space background with a complex background is one of the most important tasks in space technology. Undulant background and stars have a great influence on the target detection for low signal to noise ratio targets of imagery. In this paper, a main directional suppression high pass filter is proposed for background suppression, furthermore applied in small target detection. First, target and background models are created. Second, the problems and the necessity of the deep space background suppression are proposed. Then, the main directional suppression high pass filter is presented for background suppression. Experimental results prove that the presented algorithm is efficient and adaptable to small and dim target detection under undulant background with star lines.     

EASY: A simple tool for simultaneously removing background,deadtime and acoustic ringing in quantitative NMR spectroscopy—Part I: Basic principle and applications

Elimination of Artifacts in NMR SpectroscopY (EASY) is a simple but very effective tool to remove simultaneously any real NMR probe background signal, any spectral distortions due to deadtime ringdown effects and -specifically- severe acoustic ringing artifacts in NMR spectra of low-gamma nuclei. EASY enables and maintains quantitative NMR (qNMR) as only a single pulse (preferably 90°) is used for data acquisition. After the acquisition of the first scan (it contains the wanted NMR signal and the background/deadtime/ringing artifacts) the same experiment is repeated immediately afterwards before the T1 waiting delay. This second scan contains only the background/deadtime/ringing parts. Hence, the simple difference of both yields clean NMR line shapes free of artefacts.In this Part I various examples for complete ¹H, ¹¹B, ¹³C, ¹⁹F probe background removal due to construction parts of the NMR probes are presented. Furthermore, ²⁵Mg EASY of Mg(OH)₂ is presented and this example shows how extremely strong acoustic ringing can be suppressed (more than a factor of 200) such that phase and baseline correction for spectra acquired with a single pulse is no longer a problem. EASY is also a step towards deadtime-free data acquisition as these effects are also canceled completely. EASY can be combined with any other NMR experiment, including 2D NMR, if baseline distortions are a big problem.     

Results of spectral monitoring of environmental gamma background in a fault zone of the Western Caucasus for seismological application

Results of continuous spectral monitoring of indoor gamma background are reported for seismological application in one fault zone of the Western Caucasus. Background count rates were recorded every 5 min since 2004. Two detectors (a scintillation crystal CsI(Tl), 200 mm × 150 mm in a low background metal screen and a NaI(Tl) detector, 90 mm × 90 mm outside of the screen) were used. Various intervals of energy of gamma rays, for example, (2.50–3.40) MeV, (1.70–2.00) MeV, (1.35–1.55) MeV and others were analyzed. Averages for all measurements as well as seasonal and hourly changes of count rate of detectors were obtained. As an example, for the interval (1.70–2.00) MeV a minimal monthly count rate of detector CsI(Tl) was observed in June, and the maximal monthly count rate of detector NaI(Tl) was observed in July. Factors of correlation between different intervals of energy of gamma rays were also investigated. Strong changes of annual, monthly and daily factors were obtained.In each daily curve of all intervals of energy of gamma rays, the first Fourier harmonic was calculated. The deviations from 3σ (“splash”), which are upward or downward from the first harmonic, were compared with the seismological data. It was possible to correlate the low background dates of “splashes” with the dates of regional earthquakes through 9 ± 1 days.Change of ratio of count rate in different intervals of energy of gamma rays can be used to study processes of preparation of earthquakes.The factor of correlations between intervals (2.50–3.40) MeV and (1.70–2.00) MeV increased to almost 1.00 close to earthquakes. This effect was obtained in low background screen.Connection of the gamma data with the meteorological data was not obtained.     

Determination of Chloride by Flame molecular Absorption Spectrometry with Continuum Source and Self-Reversal Background Correction

The use of continuum source and self-reversal background correction were investigated for flame molecular absorption spectrometry (MAS). Chloride was determined by MAS using the aluminum monochloride molecule in a conventional flame atomic absorption spectrometer. Absorbance of this molecule was monitored in a lean nitrous oxide/acetylene flame at 261.4 nm using a lead hollow cathode lamp as the excitation source. Characteristic masses of 210, 260, and 820 mg/L were observed for no background correction, continuum source correction, and self-reversal correction, respectively. The ability of the techniques to correct for interferences caused by high concentrations of fluoride and sodium was investigated. The self-reversal technique was shown to remove interferences at concentration levels up to 10,000 mg/L. Chloride was determined in chloroacetic acid using calibration with chloride standards; continuum source correction had the best recovery value. These results suggest that both correction methods should be investigated for practical applications of flame MAS to obtain optimum analytical performance.     

Computation of consistent initial values for properly stated index 3 DAEs

The computation of consistent initial values is one of the basic problems when solving initial or boundary value problems of DAEs. For a given DAE it is, in fact, not obvious how to formulate the initial conditions that lead to a uniquely solvable IVP. The existing algorithms for the solution of this problem are either designed for fixed index, or they require a special structure of the DAE or they need more than the given data (e.g. additional differentiations). In this paper, combining the results concerning the solvability of DAEs with properly stated leading terms with an appropriate method for the approximation of the derivative, we propose an algorithm that provides the necessary data to formulate the initial conditions and which works at least for nonlinear DAEs up to index 3. Illustrative examples are given.      

Atmospheric pressure photoionization for coupling liquid-chromatography to mass spectrometry: A review

This review presents the state-of-the-art techniques that couple liquid chromatography (LC) and mass spectrometry (MS) via atmospheric pressure photoionization (APPI). The different ionization mechanisms are discussed as well as the influence of the mobile phase composition, the nature of the dopant, etc. A comparison with other ionization sources, such as electrospray ionization (ESI) and atmospheric pressure chemical ionization (APCI), is reported, and the combination of APPI with these sources is also discussed. Several applications, covering the time period of 2005-2008, for the analysis of drugs, lipids, natural compounds, pesticides, synthetic organics, petroleum derivatives, and other substances are presented.     

Heavy-tailed limits for medium size jobs and comparison scheduling

We study the conditional sojourn time distributions of processor sharing (PS), foreground background processor sharing (FBPS) and shortest remaining processing time first (SRPT) scheduling disciplines on an event where the job size of a customer arriving in stationarity is smaller than exactly k≥0 out of the preceding m≥k arrivals. Then, conditioning on the preceding event, the sojourn time distribution of this newly arriving customer behaves asymptotically the same as if the customer were served in isolation with a server of rate (1−ρ)/(k+1) for PS/FBPS, and (1−ρ) for SRPT, respectively, where ρ is the traffic intensity. Hence, the introduced notion of conditional limits allows us to distinguish the asymptotic performance of the studied schedulers by showing that SRPT exhibits considerably better asymptotic behavior for relatively smaller jobs than PS/FBPS. Inspired by the preceding results, we propose an approximation to the SRPT discipline based on a novel adaptive job grouping mechanism that uses relative size comparison of a newly arriving job to the preceding m arrivals. Specifically, if the newly arriving job is smaller than k and larger than m−k of the previous m jobs, it is routed into class k. Then, the classes of smaller jobs are served with higher priorities using the static priority scheduling. The good performance of this mechanism, even for a small number of classes m+1, is demonstrated using the asymptotic queueing analysis under the heavy-tailed job requirements. We also discuss refinements of the comparison grouping mechanism that improve the accuracy of job classification at the expense of a small additional complexity. This work is supported by NSF Grant 0615126.     

植物样品中Zn的双背景峰背比测定法

本文介绍了一种用双背景峰背比法测定植物样品中金属元素的方法。利用此法我们成功地测定了茶叶(84501)和茶树叶(84501)标样中的Zn,其结果与鉴定值吻合良好。