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41.
王振宇 《原子与分子物理学报》2024,41(2):022005
珠光体是十分重要的组织结构,因此本文构建了含铁素体-渗碳体相界面的模型,并采用分子动力学模拟方法模拟纳米压入的过程。通过对模拟结果的力学性能和组织结构分析,探究了铁素体-渗碳体相界面效应。研究发现,距铁素体-渗碳体晶界不同距离(位置压入),在压入最初阶段,压头载荷随着压头与晶界距离的增大而增大,当压入深度达到一定深度后,载荷随着距离的增大而减小。杨氏模量和最大剪切模量受压头尖端下方原子结构的直接影响,硬度受到结构完整性和类型的共同影响。铁素体-渗碳体相界面影响了纳米压入过程中位错形核、增殖和扩展,宏观表现为在相同压入深度下,不同压入位置压头载荷的差异。 相似文献
42.
43.
To solve the problem of organic-inorganic light conductive composite interface features, transparent resin and cement matrix were used as carriers to further study features of the organic-inorganic interface formed by transparent resin and cement matrix and the interface modification of the coupling agent. The bond strength, micro-hardness, microstructure and surface morphology of a resin light conductive cementitious materials (RLCCM) interface were evaluated by tests of tensile and oblique shear, micro-hardness, environmental scanning electron microscopy, and atomic force microscope. The results show that the silane A-151 and aluminate coupling agent could significantly improve interface bond properties of RLCCM. At 7 d, the interface tensile bond strength of the silane A-151 and aluminate coupling agent increased by 117 and 105%, respectively. At 28 d, strength on average increased by 73%. At 7 d, interface shear strength the silane A-151 and aluminate coupling agent of 45° increased by 43 and 53%, respectively, At 28 d, strength on average increased by 40%. The transparent resin performance weakened region thickness up to 100 μm; the hardness of the transparent resin in the transition region was increased by 19.6 and 39.9%, respectively. Silane coupling agent A-151 and cement hydration products formed flat spherical particles with diameter of approximately 78 nm, and these particles mosaicked and fused in the surface of the hydrate; therefore, the surface became denser and smoother. 相似文献
44.
C. Blanc M. Kléman 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,10(1):53-60
In the quasi-ternary CPCl/brine/hexanol lyotropic system, the interface of the lamellar and L3 sponge phases displays a phenomenon of epitaxy: the layers of the lamellar phase tend to make a constant non-trivial angle
with the interface. Thin samples of lamellar phase embedded in the sponge phase are thus submitted to oblique anchoring conditions
and defects are created in the lamellar phase in order to satisfy the bulk lamellar ordering and the boundary conditions.
We have studied small droplets of lamellar phase in the sponge phase. They do not exhibit the classic defects (focal conic domains) but wall defects, which appear in order to satisfy the smectic elasticity and the boundary
conditions. Moreover we show through experiments in controlled geometry that, even in the presence of focal conic domains,
wall defects control the size and periodicity of the textures which are observed at the interface.
Received 4 November 1998 相似文献
45.
We report on the free diffusion of single molecule near an interface studied using fluorescence correlation spectroscopy.
In particular, we show that the chemical nature of the substrate may modify the free diffusion of a widely used molecule (rhodamine
6G), thus inducing unexpected effects in fluorescence correlation spectroscopy measurements. Our results show a strong influence,
up to a few micrometer from the interface, of the surface polarity. This effect is assessed through the relative weight of
the two dimensions diffusion process observed close to the surface. Our results are discussed in terms of competition between
surface-solvent, solvent-molecule and molecule-surface specific interactions. 相似文献
46.
Extensive experimental results are presented to reveal the relaxations of polystyrene surface deformed by rubbing with a velvet
cloth. We found that surface topographic features, such as ditches and ridges created by rubbing, relax at temperatures at
about 20°
C below the bulk glass transition temperature of the polystyrene for a molecular weight of 442 kg/mol, even though we estimate
the Laplace Pressure driving the relaxation to be 1/500 of the yield limit. The relaxation is independent of the thermal history
before the rubbing process, and post rubbing thermal history below 55°
C . In other words, physical-aging processes at 23°
C for up to 7 days and at 50°
C for 2 days, which would have drastic effects on the relaxations of bulk polymers, have little effects on the relaxations
of rubbed surfaces. This is consistent with the mobility enhancement in the surface layer previously reported in the literature. 相似文献
47.
Imran Hussain Syed Anastasia Braer Frank Fleck Jorge Lacayo-Pineda 《Soft Materials》2018,16(4):275-288
In the present study, a specific type of reinforcing resin behavior is investigated using various mechanical approaches as well as microscopic techniques such as transmission electron microscopy and atomic force microscopy. Based on these observations, it could be concluded that the reinforcing resin introduces a synergistic effect with carbon black in order to strengthen the system. This is implied since the percolation threshold is significantly reduced and the morphology of the filler aggregates changes toward higher compactness, i.e., an increase of volume-to-size ratio with the addition of resin. 相似文献
48.
49.
There have been rapid advances in the development of new materials for use in electrode–tissue interfacing. The development of conducting polymers, conducting hydrogels, carbon nanotubes, graphene and other conducting materials has provided a rich landscape for controlling charge transfer at the electrode–tissue interface and hence to monitor and manipulate cell behaviour. These materials have been used in tissue-engineered constructs to direct and control cell proliferation, growth and differentiation. However, their translation to clinical devices has been less successful. In this review, the use of electroanalytical techniques to develop an understanding of charge transfer at the electrode–tissue interface is discussed. In particular, the impact of solution and electrode conditions on charge injection capacity is demonstrated. The importance of standardised testing methods and the correlation of electrochemical and electrophysiological performance show the limitations of empirical studies and help define key electrode properties for clinical devices. The development of a sound theoretical basis for charge transfer at this increasingly important interface is being advocated to improve clinical outcomes and device lifetime and reduce power usage. 相似文献
50.
Marie-Claude Viallon 《国际流体数值方法杂志》2020,92(5):391-421
The heat equation is solved by using a finite volume discretization in a domain that consists of a two-dimensional central node and several one-dimensional outgoing branches. Several interface connection options to match the submodels set on the node and on the branches, with or without continuity, are looked at. For each of them, a monolithic scheme is defined, and existence and uniqueness of the solution is proved. New schemes are deduced, which are obtained through domain decomposition methods in the form of interface systems, with one or two unknowns per interface. A comparative systematic study is carried out from an algebraic and numerical point of view according to the interface conditions: Dirichlet, Neumann, or Robin. An efficient diagonal preconditioning is proposed. 相似文献